Design, Synthesis of Chiral Ketone and Application in Asymmetric Epoxidation

A class of chiral ketone was synthesized for asymmetric epoxidation. High ee values have been obtained for a number of cis olefin and trans olefin. The epoxidation was stereospecific with no isomerizatiom observed in the epoxidation of acyclic system. Encourageingly high ee value has also been obtained for a number of terminal olefins. Mechanistic studies show that electronic interactions play an important role in the stereodifferentiation. O O O O O O NBoc O O t-BuO2CH2CN O O O …     

Three Novel Eremophilanolides from Ligularia virgaurea spp. oligocephala

From the alcoholic extract of the whole plant of Ligularia virgaurea spp. oligocephala, three novel eremophilane sesquiterpene lactones, 6α, 10α-dihydroxy- 1-oxoeremophila-7(11), 8(9)-dien-8, 12-olide, 613, 10α-dihydroxy-1-oxoeremophila-7 (ll), 8 (9)-dien-8, 12-olide and 10α-hydroxy-1-oxoeremophila-7(l 1), 8(9)-dien-8, 12-olide were isolated. Their structures were elucidated by various spectroscopic methods including intensive 2D NMR techniques (COSY,HMQC, HMBC and ^1H-^1H NOESY) and HR-MS.     

Crystal Structures of Two Potential Tumor Imaging Agents and Therapeutic Agents Copper（Ⅱ） Ternary Complexes with Salicylidene-tyrosinato Schiff Base and Nitrogen-donor Chelating Lewis Base

The crystal structures of two potential tumor imaging agents and therapeutic agents -copper(Ⅱ) complexes with salicylidene-tyrosinato Schiff base and nitrogen-donor chelating Lewis base, [Cu(sal-tyr)(bipy)] 1 and [Cu(sal-tyr)(phen)]2CH3OH 2 are presented. Our work is helpful to get deep understanding of novel 64Cu tumor imaging agents and therapeutic agents.     

初-边值问题驻波解的渐近稳定性

本文考虑一带有人工粘性的二维定常等熵无旋平面流方程组的初-边值问题. 在一定的假设下,我们证明其驻波解是渐近稳定的.     

KDP晶体三倍频实验和分析

报道了ＫＤＰ晶体中的三倍频产生的实验研究，计算了比较了直接三倍频过程和级联过程对ＫＤＰ晶体三阶有效非线性系数的贡献，并探讨了ＫＤＰ作为非线性晶体材料三阶非线性系数测量基准的可行性。     

一种漂移室定位子性能反常现象的研究

研究了一种漂移室定位子性能的反常现象,它关系到定位子的使用寿命．着重测量了暗电流和随机噪声与时间、高压及温度的关系.     

耐火砖模具设计中空间平面尺寸的合理标注

分析空间四边平面加工过程中产生不共面的原因，提出了合理标注空间平面尺寸的方法并阐述了其理论根据。     

非线性系统两变量控制下的分枝特性

采用分枝理论推导非线性系统两变量P和PI控制下的分枝特性,所导得的几个定理阐明了简单分枝点和Hopf分枝点的位置和性质。一个简化精馏塔模型用于演示这一过程,展示出精馏塔系统在闭环时,可能出现多态和极限环。     

距离数字显示在脉冲超声多普勒血流检测中的应用

1 工作原理及电路组成图给出电路原理框图.以工作发射频率为时钟脉冲,调制脉冲作为闸门开启时间,将调制脉冲予以延迟作为接收信号的选通脉冲来关闭闸门,这个时间就是声脉冲从换能器发射到采样点,再回到接收换能器所经过的时间,用这个时间来控制时钟脉冲予以汁数、寄存、译码,以数字形