Utilizing the Space‐Charge Region of the FeNi‐LDH/CoP p‐n Junction to Promote Performance in Oxygen Evolution Electrocatalysis

The modulation of electron density is an effective option for efficient alternative electrocatalysts. Here, p‐n junctions are constructed in 3D free‐standing FeNi‐LDH/CoP/carbon cloth (CC) electrode (LDH=layered double hydroxide). The positively charged FeNi‐LDH in the space‐charge region can significantly boost oxygen evolution reaction. Therefore, the j at 1.485 V (vs. RHE) of FeNi‐LDH/CoP/CC achieves ca. 10‐fold and ca. 100‐fold increases compared to those of FeNi‐LDH/CC and CoP/CC, respectively. Density functional theory calculation reveals OH^? has a stronger trend to adsorb on the surface of FeNi‐LDH side in the p‐n junction compared to individual FeNi‐LDH further verifying the synergistic effect in the p‐n junction. Additionally, it represents excellent activity toward water splitting. The utilization of heterojunctions would open up an entirely new possibility to purposefully regulate the electronic structure of active sites and promote their catalytic activities.     

Investigation of mononuclear,dinuclear, and trinuclear transition metal (II) complexes derived from an asymmetric Salamo‐based ligand possessing three different coordination modes

A new asymmetric Salamo‐based ligand H₂L was synthesized using 3‐tert‐butyl‐salicylaldehyde and 6‐methoxy‐2‐[O‐(1‐ethyloxyamide)]‐oxime‐1‐phenol. By adjusting the ratio of the ligand H₂L and Cu (II), Co (II), and Ni (II) ions, mononuclear, dinuclear, and trinuclear transition metal (II) complexes, [Cu(L)], [{Co(L)}₂], and [{Ni(L)(CH₃COO)(CH₃CH₂OH)}₂Ni] with the ligand H₂L possessing completely different coordination modes were obtained, respectively. The optical spectra of ligand H₂L and its Cu (II), Co (II) and Ni (II) complexes were investigated. The Cu (II) complex is a mononuclear structure, and the Cu (II) atom is tetracoordinated to form a planar quadrilateral structure. The Co (II) complex is dinuclear, and the two Co (II) atoms are pentacoordinated and have coordination geometries of distorted triangular bipyramid. The Ni (II) complex is a trinuclear structure, and the terminal and central Ni (II) atoms are all hexacoordinated, forming distorted octahedral geometries. Furthermore, optical properties including UV–Vis, IR, and fluorescence of the Cu (II), Co (II), and Ni (II) complexes were investigated. Finally, the antibacterial activities of the Cu (II), Co (II), and Ni (II) complexes were explored. According to the experimental results, the inhibitory effect was found to be enhanced with increasing concentrations of the Cu (II), Co (II), and Ni (II) complexes.     

国家层面创新能力的评价

 综述了创新、创新监测与评价的研究进展，辨析了国家创新能力、创新型国家和科技强国的内涵特征，分析了中国创新能力在世界上的相对位置，探讨了建设科技强国的经验及启示。     

heory, controls parameter and application of the packed-bed electroosmotic pump

Theory and controls parameters affecting the output pressure and flow rate of the packed-bed electroosmotic pump (p-EOP), including zeta potential ζ, electric intensity E, length of the column L, cross-section area of the column A, dielectric constant ε and viscosity coefficient η of the liquid being pumped, are discussed concisely. And also, the fabrication and application of the p-EOP are introduced.     

语法术语再认知

关于语法术语在英语语言习得和英语教学中的作用认知，在过去的几十年里从未有过间断并倍受关注，通过分析学生接受、运用英语语法术语的状况，并结合我国的大学英语教学，指出正确认知语法术语对英语语言学习和语言教学的重要作用。     

"长三角"城际轨道交通概念规划

介绍了概念规划的概念,阐述了概念规划的特点.概念规划反映的是一种趋势、一种意向,其特征是创意与速度,强调内容简化、重点突出,强调多目标、多方案的比较,强调规划的灵活性,淡化时间期限,注重动态特征.初步探索了概念规划在“长三角”城际轨道交通规划中的运用.     

高校非计算机专业计算机基础课程改革之浅见

在全面调查现行高校计算机基础课程教学特点的基础上，按照知识形成的四个层次，结合学生的实际特点，制定了切实可行的教学改革方案，使学生根据自己的实际情况，选择灵活、可行的学习方法自主学习，体现了因材施教的思想，为高校计算机教学的改革做出了有益的探索。     

Permutation Analysis of Track and Column Braiding

Introduction Trackandcolumnbraidingisanavailable3D braidingmethod[1～3],whichperformsbraidingprocessbymovingbraidingcarriersalongroworcolumndirection alternatively.LiandDing[4]examinethebraidingmethod andconcentratetheirstudyonthemovementofbraiding carriersonthebraidingplatform,onwhichthebraiding tracksarelocated.Accordingtothebraidingprinciple,a studyofbraidingprocessisactuallyastudyofthemovingpatternofyarnendsonthebraidingplatform.Intheiranotherpaper[6],thepositionsofbraidingcarriersare r…     

图书馆数字资源整合浅谈

介绍了图书馆数字化资源的主要类型和资源整合的目标，针对数字资源的特点，提出了图书馆数字资源整合的必要性，并论述了推进数字资源整合的措施。