内壳层光电离机制物理现象的实验观测

内壳层光电离机制是产生粒子数反转的途径之一，如何在中等功率的激光器上产生接近“水窗”波段的Ｘ光激光输出是人们关注的一个焦点。本文介绍在双靶耦合条件下利用内壳层光电离原理产生粒子数反转的实验研究，包括：实验原理、靶型选择、泵浦靶Ｘ光源强度测量及工作靶线谱诊断等，最后对实验结果进行了讨论，认为在国内目前条件和我们已采取的措施下，双靶耦合光电离机制只能产生微弱的粒子数反转。     

氯嘧磺隆标准品的合成、纯化与表征

利用 2 -乙氧羰基苯磺酰胺与草酰氯反应 ,得到 2 -乙氧羰基苯磺酰基异氰酸酯 ,再与 2 -氨基 -4-氯 -6 -甲氧基嘧啶进一步反应 ,合成氯嘧磺隆 .采用柱层析法对合成的氯嘧磺隆粗品进行纯化 ,所得标准品经元素分析 ,1H NMR,MS,IR确定为目标化合物 ,HPLC检测纯度为 99%以上 .     

MCM-41中孔SiO2分子筛合成新方法

以溴代十六烷基吡啶（CPBr）为模板剂，正硅酸乙酯（TEOS）为硅源，在优化的操作条件下通过S＋X-I 路径合成了高结晶度的MCM－41中孔SiO2分子筛，并提高了其收率；以TG－DTA结果为基础，对分子筛脱模板剂的过程进行了优化，同时以XRD对合成物系中CPBr；TEOSHCl，H2O相对含量对MCM－41分子筛晶相结构的影响以及该结构的形成过程进行了分析，发现MCM－41结构沿S＋X-I 路径的形成经过了Lamellar→Hexagonal相转移历程.     

Superior performance of nano-Au supported over Co3O4 catalyst in direct N2O decomposition

Au nanoparticles supported over Co3O4 lead to a highly active and stable catalyst for N2O decomposition even in the presence of excess oxygen and steam.     

Cipadonoid A, a novel limonoid with an unprecedented skeleton, from Cipadessa cinerasecns

Cipadonoid A ( 1), a novel limonoid with an unprecedented skeleton, was isolated from the leaves of Cipadessa cinerasecns. Its structure and relative configuration were determined by spectroscopic analysis and computer modeling. 1 represents a new type of limonoid, characterized by a rearranged tetrahydropyranyl ring B incorporating usually exocyclic C-30. A possible biosynthetic pathway of 1 was also proposed.     

算符(f(“非汉字符号”))~k正交归一本征态的非经典特性

证明了算符 (a^ f(n^) ) k(k≥ 3)的k个正交归一本征态的完备性 ,引入了反聚束效应和一种新的高阶压缩 ,研究了算符 (a^ f(n^) ) k 的k个本征态的反聚束效应和高阶压缩特性 .结果表明 ,这些态可以构成一个完备的希尔伯特(Hilbert)空间 ,它们均可呈现反聚束效应 ,且当k为偶数时它们可呈现M阶 [M =(n +1 2 )k ;n =0 ,1,2 ,… ]压缩效应     

主拟-Baer模

In this paper, we give the equivalent characterizations of principally quasi-Baer modules, and show that any direct summand of a principally quasi-Baer module inherits the property and any finite direct sum of mutually subisomorphic principally quasi-Baer modules is also principally quasi-Baer. Moreover, we prove that left principally quasi-Baer rings have Morita invariant property. Connections between Richart modules and principally quasi-Baer modules are investigated.     

Design,synthesis, and antilung adenocarcinoma activity research of novel paeonol Schiff base derivatives containing a 1,2,3-triazole moiety

A new series of paeonol Schiff base derivatives containing a 1,2,3-triazole moiety were synthesized using the copper(I) catalyzed azide-alkynecycloaddition (CuAAC) reaction and evaluated for their cytotoxicity in vitro against human cervical carcinoma HeLa cells, human lung cancer A549 cells, and human liver cancer HepG2 cells. Unfortunately, all the tested compounds showed poor activities toward the human cervical carcinoma HeLa cells and human liver cancer HepG2 cells. However, compounds (E)-2-(1-(((1-[2-fluorophenyl]-1H-1,2,3-triazol-4-yl)methyl)imino)ethyl)-5-methoxyphenol ( 4c ) and (E)-2-(1-(((1-[3- chlorophenyl]-1H-1,2,3-triazol-4-yl)methyl)imino)ethyl)-5-methoxyphenol ( 4i ) exhibited inhibitory activities toward human lung cancer A549 cells (IC₅₀ = 45.1 μM for 4c and 78.9 μM for 4i ) compared with that of paeonol, which indicated that such paeonol Schiff base derivatives containing a 1,2,3-triazole moiety could be further modified to obtain good cytotoxicity in vitro against human lung cancer A549 cells.     

Use of Capillary Electrophoresis in the Study of Interaction between dsDNA and Drug Molecules

The advantages of berberine such as the anticancer1, antiinflammatory2 and no side effects of camptothecin1, have promoted the research in the mechanism of berberine with macrobiomolecules. In general, three different points of view have been presented on…     

考虑边界条件的频率法测索力实用公式

通过两端固结梁和两端铰接梁的频率特征方程,在找出了二者的频率关系后,建立了一个形式简单、物理意义明确的索力计算公式.和同类方法的对比分析结果表明,该公式具有更好的计算精度和适用范围,使用该公式可以快速、准确地识别出不同长细比、抗弯刚度拉索的索力.分析了拉索边界条件对索力计算结果的影响,提出了考虑拉索端部转动约束刚度的索力计算公式.