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831.
Yao‐Cheng Shi Su‐Hua Zhang Hong‐Jian Cheng Wei‐Ping Sun 《Acta Crystallographica. Section C, Structural Chemistry》2006,62(9):m407-m410
The title compounds, both [Fe(C5H5)(C15H14NO2)], crystallize with Z′ = 2 in the centrosymmetric space group P. In each compound, there is an intramolecular N—H⋯O=C hydrogen bond, and pairs of intermolecular O—H⋯O=C hydrogen bonds link the molecules into chains, parallel to [10] in the 3‐hydroxy compound and parallel to [10] in the 4‐hydroxy compound. 相似文献
832.
833.
Wang Y Liu Z Han B Huang Y Zhang J Sun D Du J 《The journal of physical chemistry. B》2005,109(25):12376-12379
We report a facile route to pattern polymer surfaces with the aid of compressed CO(2), termed the compressed-CO(2)-assisted imprint method. In this method, compressed CO(2) serves as a plasticizer for polymers (such as poly(methyl methylate) and polystyrene), which leads to a tremendous reduction in the glass transition temperature and viscosity of the polymers. Nylon fabrics and anode aluminum oxide porous membranes are used as molds, respectively, to pattern the softened polymers at relatively low temperatures, resulting in patterns at the scale of micrometers and nanometers on the surface of polymer films. The patterned structures can be tuned by changing CO(2) pressure and temperature in the imprinting process. This method is simple and environmentally benign. It also can be operated at low temperatures, for instance, ambient temperature. 相似文献
834.
The reaction of the rifle cyclic complex (1) with sodium amalgam in THF resulted in the expected cleavage of the Fe-Fe bond to afford his-sodium salt ( Me2SiSiMe2 ) [η^5-C5H4Fe(CO)2]2 (4). The latter was not isolated and was used directly to react with MeI, PhCH2Cl, CH3C(O)Cl, PhC(O)Cl,Cy3SnCl (Cy= cyclohexyl) or Ph3SnCl to afford corresponding ring-opened derivatives (Me2SiSiMe2) [η^5-C5H4Fe(CO)2]2 [5, R=Me; 6, R=PhCH2; 7, R=CH3C(O); 8, R=PhC(O); 9, R = Cy3Sn or 10, R = Ph3Sn ]. The crystal and molecular structures of 10 were determined by X-ray diffraction analysis. The molecule took the desired ant/ conformation around the Si-Si bond. The length of the Si--Si bond is 0.2343(3)nm, which is essentially identical to that in the cyclic structure of 1[0.2346(4) tun]. This result unambiguously demonstrates that the Si--Si bond in the cyclic structure of 1 is not subject to obvious strain. 相似文献
835.
Wei Y Guo X Shuang S Dong C Sun X Wong M 《Journal of photochemistry and photobiology. B, Biology》2005,81(3):190-194
Novel dimeric capsules are generated from the noncovalent assembly of 5, 10, 15, 20-tetrakis(4-N-ethylpyridiniurmyl)prophyrin (TEPyP) and tetracarboxyl-phenyl calix[4]arene. The self-assembly system was investigated based on UV-Vis absorption and fluorescent spectra. The factors affecting the interaction process including pH and concentration were examined in detail. The association constants between TEPyP and calix[4]arene were determined by the nonlinear least squares fit. The results showed that the basic medium is favourable to the interaction and electrostatic interaction was determinate in the processes of self-assembly process. The related mechanism was discussed. 相似文献
836.
Sun T Zhang L Wang Y Zhao S Peng B Li M Yu J 《Journal of colloid and interface science》2002,255(2):241-247
The influences of two commercial demulsifiers that have a straight chain and branch chain, respectively, on the dilational viscoelasticity of an oil-water interfacial film containing surface-active fractions from crude oil were investigated. The branch-chain demulsifier AE-121 could efficiently substitute surface-active fractions of different average molecular weights from the oil-water interface, while straight-chain SP-169 could only efficiently substitute those of large average molecular weight. It was apt to form a mix-adsorption layer with surface-active fractions of small average molecular weight. The results showed that the molecular size (or represented by average molecular weights) of the surface-active fractions was an important factor influencing the reciprocity of demulsifiers and surface-active fractions at the oil-water interface. This effect could be well explained by the difference between sizes of surface-active fraction molecules and vacancies between demulsifier molecules at the interface. The results of SDBS also proved this explanation. 相似文献
837.
A series of novel phenoxy-phosphinimine ligands (L): L = 2-(Ph2PNR), 4, 6-(CMe3)2-C6H2OH [2, R = SiMe3; 3, R = Ph] have been prepared in the yield of 65-71%. And bis(phenoxy-phosphinimide) group 4 complexes of the type L2MCl2 [4, M = Ti, R = SiMe3; 5, M = Zr, R = SiMe3; 6, M = Ti, R = Ph; 7, M = Zr, R = Ph] have been synthesized by the reaction of the ligands with TiCl4 and ZrCl4. The structure of complex 7 has been determined by X-ray crystallography. The complexes 4-7 showed inactive to ethylene polymerization in the presence of modified methylaluminoxane (MMAO) and i-Bu3Al/Ph3CB(C6 F5)4. These results should be caused by overdoing the steric congestion around central metal. 相似文献
838.
The structures, binding energies, and electronic properties of one oxygen atom (O) and two oxygen atoms (2O) adsorption on silicon clusters Si(n) with n ranging from 5 to 10 are studied systematically by ab initio calculations. Twelve stable structures are obtained, two of which are in agreement with those reported in previous literature and the others are new structures that have not been proposed before. Further investigations on the fragmentations of Si(n)O and Si(n)O2 (n = 5-10) clusters indicate that the pathways Si(n)O --> Si(n-1) + SiO and Si(n)O2 --> Si(n-2) + Si2O2 are most favorable from thermodynamic viewpoint. Among the studied silicon oxide clusters, Si8O, Si9O, Si5O2 and Si8O2 correspond to large adsorption energies of silicon clusters with respect to O or 2O, while Si8O, with the smallest dissociation energy, has a tendency to separate into Si7 + SiO. Using the recently developed quasi-atomic minimal-basis-orbital method, we have also calculated the unsaturated valences of the neutral Si(n) clusters. Our calculation results show that the Si atoms which have the largest unsaturated valences are more attractive to O atom. Placing O atom right around the Si atoms with the largest unsaturated valences usually leads to stable structures of the silicon oxide clusters. 相似文献
839.
A series of new complexes {2,6-bis[1-((2-methyl-4-methoxyphenyl)imino)ethyl]pyridine}Cl2 [M=Fe(II) (2), Co(II) (3), Ni(II) (4), Cu(II) (5), Zn(II) (6)] have been synthesized. At 25°C, using 500 equiv of methylaluminoxane (MAO), the activities of Fe(II), Co(II) catalysts can reach 4.02 ×106 g/mol-Fehatm for ethylene polymerization and 3.98×105 g/mol-Cohatm for ethylene oligomerization. The effects of polymerization conditions such as reaction temperature, Al/M molar ratio and time on the activity of catalyst have been explored. 相似文献
840.
Hydrolyses of phosphorus halides, (RO)(2)POX where R = H or Me and X = F or Cl, in the gas phase and in the reaction field have been investigated theoretically with ab initio and the density functional theory (DFT). The free energy of activation in the reaction field was also estimated using the Onsager method with a correction of entropy change and basis set superposition error (BSSE). The reaction of (MeO)(2)POF proceeds through a path with bifunctional catalysis regardless of the medium, but the reaction of (MeO)(2)POCl proceeds through bifunctional and general base catalysis in the gas phase and in water, respectively. The estimated free energy barrier of 23 kcal/mol for the hydrolysis of (MeO)(2)POF is in good agreement with the experimental values of 24 kcal/mol, and relative barrier of 3 kcal/mol to the (MeO)(2)POCl is also in good agreement with the experimental values of 5 kcal/mol of diisopropyl phosphorus halides ((Pr(i)O)(2)POX, X = F and Cl). 相似文献