Single-molecule single crystals

Various approaches to the preparation and verification of single-molecule single crystals are discussed for polyethylene and poly (oxyethylene). Analytic tools are electron microscopy, electron diffraction, and differential scanning calorimetry. The main difficulty in producing a single-molecule single crystal is to keep crystals from joining during growth.     

显微组织对NdFeB磁体β（iHc）的影响

研究了显微组织对ＮｄＦｅＢ磁体ｉＨｃ及β（ｉＨｃ）的影响，对ＮｄｘＦｅ９３－ｘＢ７磁体，ｘ从１６增加到２８时，Ｈｃ增加了５５％，β（ｉＨｃ）降低了约１１％；进一步优化显微组织，增加富Ｎｄ晶间相，减弱晶粒间的磁耦合作用及消除晶粒表面的高退磁场区域，不仅可提高磁体的矫顽力，亦可显著改善其矫顽力温度系数。     

MFRG-DPIR FOR THE DISORDERED TRANSVERSE ISING MODEL

A new approximate scheme which is combined by the mean-field renormalization group theory (MFRG) with the discretized path-integral renormalization (DPIR) is employed in the study of the disordered tranverse Ising model (TIM). The critical properties of random-bonds Ising systems on a d-dimensional lattice are calculated with this new approximate scheme.     

学习毛泽东的思想政治工作艺术

毛泽东的思想政治工作艺术其本质是对思想政治工作的一种艺术掌握方式,是目的性和工具性的统一。毛泽东丰富多彩的思想政治工作艺术在当今时代仍然具有生命力,它是新形势下思想政治工作改进和创新的重要方法借鉴。     

中国西南武陵山区跳蛛新种记述（蜘蛛目：跳蛛科）

本文记述跳蛛科13个新种,采自西南武陵山地区。暗跳蛛Asemonea、列锡蛛Lycidas和法老蛛Pharacocerus 3属为我国新记录属。     

反应条件及添加惰性物质对三聚甲醛合成反应的影响

研究了三聚甲醛合成过程进料浓度、催化剂用量等对副产物（特别是甲酸）生成行为的影响。结果表明，该体系副产物的生成强烈地依赖于反应时间和催化剂硫酸的用量，而与原料浓度的波动无关。在反应－精馏过程的反应器中添加惰性高沸有机物，可有效地缩短反应物的停留时间，提高三聚甲酸的选择性，大大降低快速反应－精馏过程对反应器的设计要求。     

HPM合成及其在苯乙烯阳离子聚合体系中作用

通过利用与金属多氧络合物的相互作用,合成了具有特殊结构与功能的金属多氧络合物催化剂。经过红外表征,说明新合成的催化剂具有典型的金属多氧络合物晶体结构,同时其活性质子也得到了很好的稳定化保护。经过在苯乙烯体系中的聚合实验,发现合成的新型催化剂在引发聚合的同时,也能很好地实现聚合反应的稳定化,便于聚合操作的进行。     

Competitive influence of atactic polystyrene and supercritical carbon dioxide on the conformation of syndiotactic polystyrene

The crystallization behavior of miscible syndiotactic polystyrene (sPS) and atactic polystyrene (aPS) blends with different sPS/aPS weight ratios was investigated in supercritical CO₂ by using Fourier‐transform infrared spectroscopy, differential scanning calorimetry, and wide‐angle X‐ray diffraction. Supercritical CO₂ and aPS exhibited different effects on the conformational change of sPS and competed with each other. Increasing the content of amorphous aPS in the blends made its effect on the conformational change of sPS gradually surpass that of supercritical CO₂. Supercritical CO₂ favored the formation of the helical conformation of sPS in lower temperature range and the all trans planar conformation in higher temperature range, instead of forming the latter one only in higher temperature range in ambient atmosphere. However, increasing aPS content in the blends pushed the range for forming the helical conformation to lower temperature and made the all trans planar conformation dominant in aPS/sPS 25/75 blend after treating in supercritical CO₂ above 60 °C. The all trans planar zigzag conformation was more favorable than the helical conformation after mixing aPS in sPS in supercritical CO₂. © 2007 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 45: 1755–1764, 2007     

Nonlinear rheological behavior of silica filled solution‐polymerized styrene butadiene rubber

The reinforcement and nonlinear viscoelastic behavior have been investigated for silica (SiO₂) filled solution‐polymerized styrene butadiene rubber (SSBR). Experimental results reveal that the nonlinear viscoelastic behavior of the filled rubber is similar to that of unfilled SSBR, which is inconsistent with the general concept that this characteristic comes from the breakdown and reformation of the filler network. It is interesting that the curves of either dynamic storage modulus (G′) or loss tangent (tan δ) versus strain amplitude (γ) for the filled rubber can be superposed, respectively, on those for the unfilled one, suggesting that the primary mechanism for the Payne effect is mainly involved in the nature of the entanglement network in rubbery matrix. It is believed there exists a cooperation between the breakdown and reformation of the filler network and the molecular disentanglement, resulting in enhancing the Payne effect and improving the mechanical hysteresis at high strain amplitudes. Moreover, the vertical and the horizontal shift factors for constructing the master curves could be well understood on the basis of the reinforcement factor f(φ) and the strain amplification factor A(φ), respectively. The surface modification of SiO₂ causes a decrease in f(φ), which is ascribed to weakeness of the filler–filler interaction and improvement of the filler dispersion. However, the surface nature of SiO₂ hardly affects A(φ). © 2007 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 45: 2594‐2602, 2007