Nonlinear rheological behavior of silica filled solution‐polymerized styrene butadiene rubber

The reinforcement and nonlinear viscoelastic behavior have been investigated for silica (SiO₂) filled solution‐polymerized styrene butadiene rubber (SSBR). Experimental results reveal that the nonlinear viscoelastic behavior of the filled rubber is similar to that of unfilled SSBR, which is inconsistent with the general concept that this characteristic comes from the breakdown and reformation of the filler network. It is interesting that the curves of either dynamic storage modulus (G′) or loss tangent (tan δ) versus strain amplitude (γ) for the filled rubber can be superposed, respectively, on those for the unfilled one, suggesting that the primary mechanism for the Payne effect is mainly involved in the nature of the entanglement network in rubbery matrix. It is believed there exists a cooperation between the breakdown and reformation of the filler network and the molecular disentanglement, resulting in enhancing the Payne effect and improving the mechanical hysteresis at high strain amplitudes. Moreover, the vertical and the horizontal shift factors for constructing the master curves could be well understood on the basis of the reinforcement factor f(φ) and the strain amplification factor A(φ), respectively. The surface modification of SiO₂ causes a decrease in f(φ), which is ascribed to weakeness of the filler–filler interaction and improvement of the filler dispersion. However, the surface nature of SiO₂ hardly affects A(φ). © 2007 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 45: 2594‐2602, 2007     

升巨散对实验性血小板减少症的治疗作用研究

采用水提醇沉法将升巨散制成冲剂,对实验性血小板减少症的治疗,表明升巨散具有升高外周血小板数量之功效,差异显著(P<0.15).相继在出血时问、凝血时间和24h 血块收缩实验中,也间接证实本品有升高外周血小板数量之作用。又在骨髓象检查中,发现升巨散能提高骨髓之巨核细胞及血小板数量,差异显著。本品 LD_(50)及95%可信限为70.88±2.62g/kg。     

钻石型等级晶格上Gauss模型的临界性质

在Gauss模型中 ,假设Gauss分布常数依赖于晶格格点的配位数 ,并且满足关系bqi/bqj=qi/ qj( qi是格点i的配位数 ,bqi是格点i上的Gauss分布常数 ) .利用重整化群变换和自旋重标相结合的方法 ,研究了一族钻石型等级晶格上Gauss模型的临界行为 .结果发现 :这些晶格的铁磁相变性质属于同一普适类 ,其临界点和临界指数分别为K =b_qi/ q_i 和ν=1 / 2 .     

中国六种管巢蛛记述（蜘蛛目：管巢蛛科）

本文记述我国管巢蛛6种,即白马管巢蛛Clubiona baimaensis sp. nov.、朝鲜管巢蛛C. corena Paik 金氏管巢蛛C. kimyongkii Paik、琴形管巢蛛C. lyriformis sp. nov.、臼齿管巢蛛C. moralis sp. nov.和江原管巢蛛C. wolchongsensis Paik。其中3种为新种,3种为我国新纪录。文中并提出,乌苏里管巢蛛C. ussurica Michailov(♀)可能与金氏管巢蛛(♂)为同种,因而乌苏里管巢蛛的拉丁字名应为后一种的同物异名。     

磁场中载流线圈力和力矩的公式

本文给出计算载流线圈在外磁场中所受力和力矩的普遍公式.     

Synthesis and characterization of novel perfluorinated polyimides with 3D‐controlled structures for photonic applications

We have designed and synthesized novel perfluorinated polyimides with 3D controlled structure. At first, we successfully developed the new synthetic routes to diamines with pendant bulky perfluorinated aromatic units in a multi‐step synthetic procedure. Novel perfluorinated polyimides were prepared in a two‐step reaction in N‐methyl‐2‐pyrrolidinone (NMP) solution: The first step was for the synthesis of polyamic acids (PAAs) and the second reaction was for the imidization of PAA. The polymer yield was over 89% and the inherent viscosity of PAAs was in the range of 0.24–0.36 dL/g. The thin films were prepared by spin‐coating the PAA solution in NMP onto various substrates such as a Si wafer or a KBr pellet, dried at 80 °C and further cured at 230 °C. The resultant polyimides are thermally stable over 400 °C. The refractive index and birefringence of the resultant polyimides are 1.5858–1.6452 and 0.01–0.005, respectively. The refractive index of polyimide decreases with increasing the fluorine content. The copolymerization and the ether linkages into the backbone reduce the birefringence of polyimides. Surprisingly, the pendant ether linkage is not a crucial factor in reducing the polyimide birefringence. Their birefringence is comparatively very low, compared with that of previous polyimides. © 2005 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 1326–1342, 2006     

Synthesis and luminescence characteristics of conjugated dendrimers with 2,4,6‐triaryl‐1,3,5‐triazine periphery

We have synthesized conjugated dendrimer with triazine peripheries, and their luminescence properties were investigated. The dendrimers consist of dendritic triazine wedges for electron transport, distyrylbenzene core as an emitting moiety, and t‐butyl peripheral groups for good processing properties. The dendrimers have LUMO values of about ?2.7 eV possibly because of the triazine moiety with high electron affinity. Photoluminescence study indicates that energy transfer occurs from the triazine wedges to the stilbene bridge, and finally to the core chromophore units due to a cascade decrease of bandgap from the peripheral wedge to core moiety. Therefore, the emission wavelength was determined by the structure of the core unit. The energy transfer efficiency of distyrylbenzene‐cored dendrimers was about 75 and 55% for Trz‐1GD‐DSB and Trz‐2GD‐DSB, respectively. A preliminary electroluminescence property also was investigated. © 2005 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 254–263, 2006     

非晶态Te_（81）Ge_（15）Sb_4薄膜材料的电学性能

对用熔体淬火再真空蒸发所制备的非晶态Ｔｅ＿（８ｌ）Ｇｅ＿（１５）Ｓｂ＿４薄膜的伏－安特性，直流电导率及玻璃转变温度等性能进行了研究。结果表明，这种材料具有较好的开关效应及较高的热稳定性，可用作开关器件等。     

有机化学中的弯曲键

该文根据弯键理论，讨论了σ－π型双键与弯曲键的等价性，并对多种键性规律进行了园满的解释。     

关于单花莸的二型花的补记

陈介(1964)在四棱草属(Schuabelia)中发现了二型花,即开花授粉型的花(chasmoga-mous)和闭花授粉型的花(cleistogs)。本文作者于1985年指出单花莸(Caryopteris nepetoefolia(Benth.)Maxim.)也有二型花。自从K.J Maximowicz在1876年将Tenn nepetaefolia从香科属(Teucrnm)转隶到莸属(Caryopteris)以来,有关它的这一特征一直无人知晓。单花莸与四棱草属的二型花不仅有相同的结构,而且也都是发生在同一植株上;就花期而言,开花授粉型花的花期在先,闭花授粉型花的花期在后;从花的着生位置看,两种类型的花各自生在其聚伞花序上。迄今,几乎所有已出版的植物志均未提到单花莸有二型花。为此,本文对其作了补充描述,并简略讨论了二型花在植物进化上的意义。