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11.
12.
七轴五联动螺旋桨加工机床控制系统关键技术 总被引:1,自引:0,他引:1
为解决大型螺旋桨加工车铣复合机床的控制问题,提出了基于运动控制器和以太网的开放式数控系统体系结构,其上位机采用通用的工业计算机,下位机采用高性能运动控制器.进而提出了基于坐标映射的插补算法,通过将真实的3旋转2直线坐标系和虚拟的3直线2旋转的标准坐标系的双向映射和通用的插补算法的集成,完成了4旋转2直线的特殊机床结构的插补算法;采用双电机同步耦合驱动技术,消除大型回转工作台传动间隙,确保工作台精确跟踪插补结果,控制两台电机分别驱动工作台的两个方向运动,同时通过其产生的反向张力使得两台电机的传动链按照规定方向绷紧,可以有效地消除机械间隙. 相似文献
13.
Tonghui Yang Xiaolan Liu Yanli Ding Shihua Zhao Naiqiang Yin 《Journal of nanoparticle research》2018,20(8):207
In this work, ZnO nanorod/Cu2O composite nanostructure solar cells were prepared using hydrothermal growth and electrodeposition. The CdS layer was added between ZnO and Cu2O to suppress carrier reverse recombination. Nondestructive interface deposition methods were employed to prepare CdS and Cu2O functional layers. The CdS layers were unconventionally deposited in non-alkaline solution, which can inhibit etching on the ZnO surface, and Cu2O layers were electrodeposited in ZnO-buffered alkaline solution which can also inhibit etching on the ZnO surface. Finally, the performance of solar cells was improved by adding a highly resistive CdS intermediate layer between ZnO and Cu2O layers. This work demonstrated the nondestructive interface approach of chemical solution deposition of functional layers on ZnO and possibilities for further improvements to the performance of Cu2O-based nanostructure solar cells with the addition of an intermediated layer. 相似文献
14.
Seventeen flavonoids isolated from the extracts of the stem of Entada phaseoloides were investigated for their anticomplement (both classic and alternative pathways) and antimicrobial activities against Gram-positive bacteria (MRSA, MSSA, Standard Enterococcus and Bacillus subtilis), Gram-negative bacteria (Escherichia coli, Pseudomonas aeuroginosa) and the yeast-like pathogenic fungus Candida albicans. The anticomplement studies revealed a dose-dependent activity among isolated quercetin, luteolin, apigenin, galangin, 5,2',5'-trihydroxy-3,7,4'-trimethoxyflavone-2'-O-beta-D-glucoside (+)-3,3',5',5,7-pentahydroflavanone, (+)-dihydrokaempferol, (-)-epicatechin, (+)-catechin, naringenin, and 5,7,3',5'-tetrahydroxyflavanone, and the antimicrobial results indicated that quercetin, 5,7,4'-trihydroxy-3'-methoxyflavonol and galangin produced the inhibitory activities against MRSA, MSSA, and Standard Enterococcus, while luteolin and rhamnocitrin displayed inhibition against only MRSA and MSSA. To the best of our knowledge, this is the first report that describes the anticomplement and antimicrobial activities of the stem of E. phaseoloides. 相似文献
15.
A carbon paste electrode modified with chelating resin (ammino-isopropylmercaptan-type cross-linked chelating resins) for the voltammetric determination of gold(III) was characterized by cyclic voltammetry. The gold(III) ion is accumulated on the surface of the modified electrode only by the chelating effect of the modifier in the carbon paste, without application of a potential. After exchange of the medium the accumulated amount of gold(III) is determined by voltammetry in a blank electrolyte solution. The response depends on both the concentration of gold and the accumulation time. For a 5-min preconcentration time, a linear calibration graph was obtained in the range 3 × 10?8-1 × 10?6 M and the detection limit was about 1 × 10?8 M. A combination of chemical and electrochemical renewal allows the use of a single modified electrode in multiple analytical determinations over several days. For ten preconcentration—determination—renewal cycles [2 × 10?7 M Au(III)], the response could be reproduced with 4.7% relative standard deviation. Many parameters such as the composition of the paste and pH influence the response of the measurement. Many other metal ions have no or little effect on the determination of gold. The procedure was applied to the determination of gold in minerals, copper and anode mud, with good results. 相似文献
16.
本文提出了使用ICP-AES直接测试天然矿泉水中硫酸根的方法,样品经过盐酸酸化,加热处理后直接上仪器测试测试。方法检出限达到0.05mg/L,加标回收率达到95%-103%,重复性实验RSD%低至1.01%,对比实验RD小于5%。 相似文献
17.
HUANG Wei-Ping ZHANG Xin-Jie WU Shi-HuaMA Shu-Yin ZHANG Shu-Ji ZHAO Wei-Jun 《天然气化学杂志》1997,6(3):252-257
IntroductionIn1962,N.V.Kutepow'SgroupfirstusedcomplexesofFe,CoandNiascatalyststocatalyzecarboXylationofethanoltopreparepropanoicacidanditsderivants.Thereactionpressurewashighandtheyieldwaslow.LateronPaulalsandhiscolleagueusedabC13andiodineascatalyst,which… 相似文献
18.
Jing Zhou Shihua Song Feng Jiang Chunling Fu Prof. Shengming Ma 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(42):9948-9958
Herein, we report the total synthesis of traumatic lactone and rhizobialide by utilizing allenoic acid to construct the lactone ring. The key starting materials, allenoic acids, could be prepared by the ATA (allenation of terminal alkynes) of a terminal alkyne with an aldehyde that contained a protected hydroxyl group followed by hydrolysis. Importantly, the asymmetric synthesis could be realized just by replacing racemic diphenylprinol with (R)- or (S)-diphenylprinol to deliver the optically active allenoate. 相似文献
19.
Summary: Silica supported chromium oxide catalysts have been used for many years to manufacture polyethylene and they still account for more than 50% of world production of high‐density polyethylene. Along with its commercial success, the catalytic mechanism and polymerization kinetics of silica supported chromium oxide catalysts have been the subject of intense research. However, there is a lack of modeling effort for the quantitative prediction of polymerization rate and polymer molecular weight properties. The chromium oxide catalyzed ethylene polymerization is often characterized by the presence of an induction period followed by a steady increase in polymerization rate. The molecular weight distribution is also quite broad. In this paper, a two‐site kinetic model is developed for the modeling of ethylene polymerization over supported chromium oxide catalyst. To model the induction period, it is proposed that divalent chromium sites are deactivated by catalyst poison and the reactivation of the deactivated chromium sites is slow and rate controlling. To model the molecular weight distribution broadening, each active chromium site is assumed to have different monomer chain transfer ability. The experimental data of semibatch liquid slurry polymerization of ethylene is compared with the model simulations and a quite satisfactory agreement has been obtained for the polymerization conditions employed.
20.