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21.
用电化学金属阳极氧化法在非水溶剂中合成了苯甲醛缩氨基硫脲(HL)与Cu(I)、Zn(Ⅱ)配合物,通过元素分析、红外光谱、紫外光谱、磁矩、摩尔电导等对配合物进行了表征。 相似文献
22.
Jianguo Ren Xianbin Wang Jianfa Chen Chunyuan Li Hui Yang Ziyuan Ouyang 《科学通报(英文版)》1998,43(9):761-761
The isotopic cumpositions of helium have been investigated in hot spring gases sampled from the Liaodong Peninsula. China.
The3He/4He ratios range from 0.14 Ra (0.14 times the atmospheric3He/4He ratio of 1.40 × 10-6 to 0.72 Ra.3He/4He versus4He/20Ne ratios and He contents suggest that a small amount of mantle-derived helium reaches the earth’s surface. Helium iwtope
ratios of the hot spring gases show a distribution pattern similar to the regional heat flow values, indicating that the positive
thermal anomaly occurring in the rtrea is closely associated with the presence of mantle-derived helium. The observations
described above provide some significant evidence that the molten magma originating from partial melting of the upper mantle
may have intruded into the continental crust along the activity fault. The coupling of the presence of mantle He and heat
flow anomalies to seismic activity in studied region seem to imply that there is an internal relationship between mantle degassing
and seismic activity. 相似文献
23.
The range and the nonextinction property of a supercritical superdiffusion and solutions of its corresponding differential
equation are studied. It is pruved that under a suitable condition, the conditioned superprocess of the supercritical superdiffusion
is a subcritical superdiffusion. 相似文献
24.
Cytosine deaminase gene ofEscherichia coli strain H-30 was cloned, and its initiation codon of ‘GTG’ was mutated to ‘ATG’ by PCR. Prokaryotic recombinant expression
vector pBV220-CD was constructed. Clone with high enzyme activity were selected by detecting their specific activity of cytosine
deaminase. 5-FC(5-FC, 5-fluorocytosine) could induce the lethal toxicity to cells containing active CD gene. DNA sequence
analysis indicated that there were 16 altered bases and 5 of them resulted in the alteration of amino acids in predicted peptide
by comparing DNA sequence of the clone H-30-CD-11 with high enzyme activity with CD gene reported in Gene Bank. 相似文献
25.
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27.
The equilibrium geometries, electronic structures, as well as one- and two-photon absorption cross sections of a series of octupolar chromophores with Zn(2+) or Cu(+) as coordinate centers and 4,4'-bis(dibutylaminostyryl)-[2,2']-bis(bipyridyl) as ligands have been determined by using B3LYP/6-31G and ZINDO methods. These molecules are designed by controlled combination of two or three bipyridyl ligands with the metal centers. The results show that Zn(2+) is an effective template for the design of octupolar structures which enable it to form tetrahedral and octahedral coordinated complexes; while Cu(+) only exists in a tetrahedral coordinated complex, comparing the tetrahedral complex with Zn(2+) as the center with that of Cu(+) as the center, it is found that the complex with the Cu(+) center is a better two-photon absorption material than the former as far as the transparency/nonlinearity is concerned. Furthermore, for the same metal center of Zn(2+), both one- and two-photon absorptions of the tetrahedral complex are redshifted relative to those of the octahedral complex, is attributed to the spiroconjugation effect in the tetrahedral complex. Our theoretical findings are consistent with recent experimental observations and provide an important foundation for the design of improved transparency-nonlinearity two-photon absorption materials. 相似文献
28.
Zi-Zhong Li Qing-Xiang Guo Tan Ren Xiao-Qing Zhu You-Cheng Liu 《Journal of inclusion phenomena and macrocyclic chemistry》1993,15(1):37-42
Tetramethylsilane (TMS) can be included by -cyclodextrin (-CD), and sodium 2,2-dimethylsilapentane-5-sulphonate (DSS) can form inclusion complexes with - and -CD. The NMR chemical shifts are changed considerably as a result of the strong interaction between CD and the guest compound in the inclusion complexes. A downfield shift of as much as 0.63 ppm shift downfield has been observed for the protons of external TMS in CD aqueous solution. In view of this, the question arises of whether TMS and DSS can be used as internal references. DSS in D2O is suggested as an external reference for aqueous cyclodextrin solution in NMR measurements. 相似文献
29.
A new series of MR-IPN polyacrylamide—poly(vinyl-ethylenediamine)chelatesorbents were prepared by the reaction of ethylenediamine with MR-IPN matrixes.The newchelate sorbent showed good sorption properties for auric and platinic ions. 相似文献
30.
Metathesis reactions between Ru(2)(DMBA)(4)Cl(2) (DMBA = N,N'-dimethylbenzamidinate) and MX (M = Na and K) yielded bis-adduct derivatives Ru(2)(DMBA)(4)X(2) (X = CN (1), N(3) (2), N(CN)(2) (3)). Metathesis reactions between Ru(2)(DMBA)(4)(NO(3))(2) and KI resulted in Ru(2)(DMBA)(4)I(2) (4). Compound 1 is diamagnetic, while compounds 2-4 are paramagnetic (S = 1). Both compounds 1 and 2 undergo two reversible one-electron processes, an oxidation and a reduction, while compound 3 features a quasireversible reduction. Single-crystal X-ray diffraction studies revealed that the Ru-Ru bond lengths are 2.4508(9), 2.3166(7), 2.304[1], and 2.328(1) A for compounds 1-4, respectively. Structural and electrochemical data clearly indicate that the axial ligands impart a significant influence on the electronic structures of diruthenium species. 相似文献