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61.
在相对碰撞平动能为 0 .0 5eV的分子束实验条件下 ,研究了亚稳态CO(a) +NO(X)的E E传能通道 .通过测量和分析交碰区的传能发射光谱 ,在 780和 860nm处观测到了NO(b -a)跃迁Ogawa带的△v =+ 4和△v =+ 3序的发射光谱 .从而首次在实验上直接证实了传能过程中第四通道的存在 (CO (a) +NO(X)→CO (X) +NO(b) ) .这一通道的发现解释了前人测量到的在CO(a)与NO(X)碰撞传能过程中CO(a)的猝灭速率远大于NO(A ,B)生成速率的实验结果 ,并进一步证实了这一“经典”E E传能体系为电子交换机理的传能观点 相似文献
62.
Transmission fluctuation spectrometry (TFS) is a method for the analysis of particle size distributions based on the statistical fluctuations of a transmission signal. Complete information on the PSD and particle concentration can be retrieved by a special transformation of the transmission signal, whereby the expectancy of the transmission square (ETS) is determined after the signal has been subjected to a procedure of spatial and temporal averaging. By varying the averaging parameters over a wide range, a spectrum of ETSs is obtained and introduced into a linear equation system, which yields the PSD. In the experimental realization presented here, variable temporal averaging is realized in the frequency domain with a series of low pass filters at different cutoff frequencies while spatial averaging inevitably occurs as the particles pass through a focused Gaussian beam of finite cross section. Experimental results on spherical particles (glass beads) and non‐spherical particles (SiC) are presented. The PSDs are resolved in 30 intervals within a particle size range from 1–1000 μm, employing a modified Chahine inversion algorithm. So far, the measurements are limited to moderate particle concentrations. Some influences affecting the measurements, especially for higher particle concentrations, are discussed in detail. 相似文献
63.
Lanthanide Complexes for Oligomerization of Phenyl Isocyanate 总被引:1,自引:0,他引:1
IntroductionThestudyonthereactivitiesoflanthanidecomplexesto wardisocyanateshasattractedmuchattention .Ithasbeenre portedthatlanthanidealkoxides,1anddivalentdiaza pentadi enyllanthanidecomplexes2 canbeusedasthesinglecompo nentinitiatorsforisocyanatespolymerization .Recentlyourre searchgrouphasalsofoundthatlanthanoceneamide ,3diva lentaryloxideofsamarium4 ,5anddivalentsamarocene6 areallactivefortheoligomerizationofphenylisocyanate,andtheactivespeciesforthesethreesystemswereallsuccessfullyisolat… 相似文献
64.
引入v-支持向量机,通过构造和求解一个凸优化问题,同时实现了对边际电价的预测和对置信区间的估计,且无需假定预测偏差的概率分布.在v-支持向量回归中,当ε〉0时,v是错误样本的个数占总样本个数份额的上界.利用该性质,边际电价预测的置信度和置信区间可以很自然地用参数1-v和变量ε来表示,这为发电公司进行竞价方案的风险分析打下了很好的基础.算例仿真表明,该方法具有较好的泛化性能和较高的预测精度. 相似文献
65.
ChujiangCai ZhigangShen MingzhuWang ShulinMa YushanXing 《中国颗粒学报》2003,1(4):156-161
This paper reports the use of a colloidal Pd^0 catalysis system to metallize the surface of precipitators separated from coal fly-ash, and metals such as Cu, Ni etc. are deposited on the precipitators surface. Alternatively, according to the characteristic surface of cenospheres, an Ag coating catalysis system is adopted to first deposit Ag on the cenospheres surface, followed, if necessary, by the deposition of other metals such as Cu, Ni, etc. on the Ag coating to produce monolayer and multilayer metal-coated cenospheres. The surface characteristics and the morphologies of the metal coatings are examined in detail with scanning electron microscopy (SEM), energy dispersive spectroscopy (EDX) and X-ray photoelectron spectroscopy (XPS) techniques. It can be shown that the quality of metal coatings derived from the Aa coatina catalysis system, is better than that of the colloidal Pd^0 catalysis system. 相似文献
66.
67.
提出了一种用于修正光学神经网络硬件系统误差的虚拟神经网络模型,光学实验结果表明该网络能够有效地消除硬件系统误差对实验结果的影响。 相似文献
68.
Angular momentum effect in prescission particle multiplicities for a light system by diffusion model
W. Ye W. Q. Shen Z. D. Lu J. Feng Y. G. Ma J. S. Wang K. Yuasa-Nakagawa T. Nakagawa 《Zeitschrift für Physik A Hadrons and Nuclei》1997,359(4):385-389
The effect of angular momentum on the competition between fission and particle emission during light system fission process was studied via fission diffusion model. The prescission particle multiplicities were found to increase with decreasing angular momentum. The experimental prescission proton and α particle multiplicities can be fitted for 10.6 MeV/nucleon 84Kr(27Al,binary fission) reaction with this model. Entrance channel effect found in [1] is proved to be angular momentum effect. 相似文献
69.
C.J. Lu H.M. Shen S.B. Ren Y.N. Wang 《Applied Physics A: Materials Science & Processing》1997,65(4-5):395-401
3 thin films is systematically studied by using X-ray diffraction (XRD). The PbTiO3 thin films with different average grain sizes were prepared on various substrates by a sol-gel process. The films on NaCl
and fused glass are randomly grain-oriented, while those on (111)Pt/Ti/SiO2/Si are highly {100} cubic index grain-oriented . It is found from the XRD patterns of the films on NaCl that with decreasing
average grain size from 230 to 80 nm, the intensities of high h index (h>l) peaks (hkl), such as (100), (110), (200), (201),
(210), (211), etc., decrease rapidly and ultimately disappear, whereas another set of peaks (lkh), including (001), (002),
(102), (112), etc., are still intense. This interesting result suggests that at grain size below a certain critical size an
increasing number of grains no longer show 90°-domains, which is confirmed by TEM observations. Meanwhile, X-ray evidence
of such a grain-size-related absence of 90°-domains is also found for PbTiO3 films on Pt(111) and fused-glass substrates. The volume fractions of single-domain grains (without 90°-domains) in the films
are estimated from their XRD patterns. By combining SEM and TEM investigations, the critical grain size for the formation
of 90°-domains is further determined to be near 200 nm.
Received: 19 December 1996/Accepted: 24 March 1997 相似文献
70.
为改善横向水力载荷对控制棒导向筒的作用,对靠近上腔室出口管嘴附近的控制棒导向筒(对称的4组:02-26,03-25,11-29,12-28)加设了保护套.在秦山核电站压水堆上腔室14的可视化模拟体中,以水为介质进行了实验研究,把结果与未加设保护套的实验结果作了分析比较,得到了对靠近上腔室出口管嘴附近的控制棒导向筒加设保护套有助于改善流场对控制棒导向筒的水力载荷作用和确保控制棒能按指令在导向筒中自由升降和快速下插的结论. 相似文献