Optimization of the locations of the loudspeaker and absorption material in a small room

The sound field both in the loudspeaker box and in the room is calculated by an analytical solution of three-dimensional wave equation. It is shown in theory that the amplitude response in small rooms is affected by the following positions: driver position on the front panel of the box, box position in the room, absorption material position in the box and absorption material position on the interior walls of the room. Both our computer prediction and experiments prove that the optimum positions are beneficial to the amplitude response.     

可调谐液晶法-珀滤光片的研究

提出了一种可用于密集波分复用系统中的新型可调谐滤光片的设计方法,该设计利用了液晶的双折射现象,以及液晶盒内法-珀效应,从理论上分析了器件的光谱特性,计算了液晶分子的折射率调制和其分子转动角度的关系.并对器件进行了性能测试.实验结果与理论吻合较好.     

Synthesis, Spectroscopy, and Electrochemistry of Metallophthalocyanines Substituted by Propylenedithiotetrathiafulvalene Derivatives

Zinc(II) and magnesium(II) phthalocyanines bearing four substituted propylenedithiotetrathiafulvalene (PDT-TTF) units were synthesized and characterized by NMR, MS, EA, and UV/VIS spectra. The absorption peaks of two target molecules were hypsochromically shifted compared with the phthalocyanine parent compound. Studies using cyclic voltammetry indicated that introduction of Zn and Mg as central metals enhanced the electronwithdrawing between the phthalocyanine core and the PDT-TTF unit, thus losing one electron to form (PDT-TTF)⁺ becomes more difficult.     

The magnetization behavior of nanocrystalline permanent magnets based on the Stoner–Wohlfarth Model

The magnetization behavior in nanocrystalline permanent magnets has been investigated using mean field Stoner–Wohlfarth model. The model is comparatively simple but allows the numerical treatment of extended nanostructures. The predominant intergrain exchange coupling is expressed by a mean field constant N_m in spite of no explicit relationship between N_m and the microstructure. By this model, the experimental phenomena, such as the remanence enhancement, the shape of demagnetization curve, the irreversible magnetization, the exchange bias field and their respective temperature dependence, can be well explained. The N_m dependence of magnetic properties has been extensively discussed in the present paper.     

Transition‐metal‐catalyzed reactions of 5‐methylene‐2‐oxazolidinone and 5‐methylene‐1,3‐thiazolidine‐2‐thione with isocyanates

5‐Methylene‐2‐oxazolidinone (1) and 5‐methylene‐1,3‐thiazolidine‐2‐thione (4) react with various isocyanates to give the corresponding urethanes 3 and 5 in high yields in the presence of palladium(0) or palladium(II) catalyst under mild reaction conditions. A mechanism is proposed. Copyright © 2003 John Wiley & Sons, Ltd.     

Spectral and Pseudospectral Approximations Using Hermite Functions: Application to the Dirac Equation

We consider in this paper spectral and pseudospectral approximations using Hermite functions for PDEs on the whole line. We first develop some basic approximation results associated with the projections and interpolations in the spaces spanned by Hermite functions. These results play important roles in the analysis of the related spectral and pseudospectral methods. We then consider, as an example of applications, spectral and pseudospectral approximations of the Dirac equation using Hermite functions. In particular, these schemes preserve the essential conservation property of the Dirac equation. We also present some numerical results which illustrate the effectiveness of these methods.     

Investigation of the Li1+xV3O8 electrode–organic electrolyte interface by scanning photoelectron microscopy

To investigate the formation of a solid electrolyte interface (SEI) on the Li_1+xV₃O₈ electrode surface in the thermodynamic stability range of the organic electrolyte, we applied scanning photoelectron microscopy (SPEM) to a pristine electrode and to an electrode after ten cycles. The F K-edge absorption spectrum of the cycled electrode showed that LiF forms on the electrode surface during the lithium insertion–extraction process in the Li_1+xV₃O₈/Li cell. The photoelectron spectrum for the cycled electrode showed intense spectral features corresponding to Li 1s, F 2s, F 2p, and P 2p electron signals, whereas these spectral features were of negligible intensity for the pristine electrode. The above results give strong support for the formation of an SEI that consists of LiF and compounds containing phosphorus during operation of the battery. The SPEM images also revealed that the fluorine distribution on the surface of the cycled electrode was inhomogeneous.     

加快农业科技成果转化促进农村经济发展--记太原市农业科学研究所

太原市农业科学研究所成立于1979年11月，隶属太原市农业局，属全民所有制事业单位。该所在职人员52人，下设5个科室，其中科技人员41人(高级职称10人，中级职称16人，初级15人)，是太原市唯一集果树、蔬菜科研、推广、服务为一体的农业科研机构。     

苯并18-冠-6配合物[K(B18-C-6)]SCN的合成与结构分析

苯并 18 -冠 - 6 (B18- C- 6 )与 K2 [Cd(SCN) 4 ]反应 ,得到了 [K(B18- C- 6 ) ]SCN配合物。通过元素分析、红外光谱、单晶 X射线衍射进行了结构分析。该配合物为单斜晶系 ,空间群 P2 (1) / c,晶体学数据 :a=0 .996 0(3) nm,b=2 .5 0 97(7) nm,c=0 .8374 (2 ) nm,β=10 6 .5 19(5 )°,V=2 .0 0 6 7(10 ) nm3 ,Z=4 ,F(0 0 0 ) =86 4,R1=0 .0 4 2 9,w R2 =0 .0 5 75。结构分析表明 ,该配合物由一个 [K(B18- C- 6 ) ]配阳离子和一个 SCN阴离子组成 ,配合物的两个分子通过 K+ - π相互作用形成一维链状结构