光催化甲苯衍生物、环烷烃与无机亚磺酸盐的位点选择性C(sp3)-H砜基化

烃类是最基础的有机分子之一,具有品种丰富、来源广泛、价格低廉等优势,其多样性、选择性转化一直备受合成化学家关注.然而,这些化合物中通常存在多个键能高、极性低、相互间差异性小的C(sp3)-H键,因此,实现高效、选择性C-H官能化极具挑战性.近年来,可见光催化广泛应用于有机合成中,与氢转移催化相结合所发展的可见光氢转移光...     

Ge132合成方法的改进及其产品的鉴定

对文献介绍的Ge132的合成方法进行改进，简化操作过程，提高了收率，并用质谱、红外光谱及元素分析等方法对其产品进行鉴定。     

东部沿海要素西移与中西部改革发展的相互关系

沿海企业因成本全面上升和资源分布格局的变化开始向西转移扩张，这对于缺乏投资而改革与发展滞后的内陆地区有促进发展和改革的双重意义。沿海由此为新产业发展让出空间，调整自己的产业结构；中西部则因要素注入而得以加速企业改革和发展，缩小中国区域发展差距。     

Simultaneous determination of phthalates and adipates in human serum using gas chromatography–mass spectrometry with solid‐phase extraction

A gas chromatography–mass spectrometry assay was developed and validated for the simultaneous determination of phthalates and adipates in human serum. The phthalates and adipates studied were dimethyl phthalate, diethyl phthalate, dibutyl phthalate, benzylbutyl phthalate, di‐2‐ethylhexyl phthalate, di‐n‐octyl phthalate, diethyl adipate, dibutyl adipate, diisobutyl adipate, bis(2‐butoxyethyl) adipate and di‐2‐ethylhexyl adipate, with diisooctyl phthalate as internal standard. The extraction and cleaning up procedure was carried out with solid‐phase extraction cartridges containing dimethyl butylamine groups, which showed extraction efficiencies over 88% for each analyte and the internal standard. The calibration curves obtained were linear with correlation coefficients greater than 0.98. For all analytes, the assay gave CV% values for intra‐day precision from 4.9 to 13.3% and mean accuracy values from 91.4 to 108.4%, while inter‐day precision was 5.2–13.4% and mean accuracy 91.0–110.2%. The limits of detection for the assay of phthalates and adipates were in the range 0.7–4.5 ng/mL. The method is simple, sensitive and accurate, and allows for simultaneous determination of nanogram levels of phthalates and adipates in human serum. It was successfully applied to an investigation on the level of phthalates and adipates in a non‐occupationally exposed population.     

语调、语气在演绎歌曲《松花江上》中的重要作用

汉语是声调语言,其语调、语气对歌唱的行腔和润色具有重要作用,通过对语调、语气与旋律、节拍、节奏、旋法特征结合的分析,试图找出在演唱过程中运用怎样的语调和语气才能恰如其分地表达出作曲家的创作意图,才能达到完美的二度创作、三度创作的效果。     

分数维环式单向耦合Lorenz系统的同步

主要采用分数维方法,基于Lalace变换,对环式单向耦合的3个Lorenz混沌系统的同步进行了研究,并对取得的结果作了相关数值模拟,模拟结果证实我们取得的成果的正确性和有效性.     

光学非球面面形拟合方法研究

作者在研制一台高精度检测非球面仪器的过程中,探讨了二次和高次非球面面形方程参数的拟合方法。计算实例表明,线性化拟合法和非线性拟合法较圆满地达到了各种非球面面形拟合精度和实时处理的要求。     

基于微立体光刻技术的组织支架的制备

介绍了基于微立体光刻技术制造的三维支架初步模型.由微立体光刻设备制备出了μm级的圆柱阵列式支架和三角孔式支架,整体结构很微小,结构上端为原生代细胞附着区域,下端是细胞培养液的贮液池.支架结构精度较高,可以达到传统快速成型技术不能具备的等级,其微孔之间的孔隙结构达到200μm左右,同时,微孔的数量、大小、分布及形状可人工影响或控制.姜姜