Chiral separation of synthetic vicinal diol compounds by capillary zone electrophoresis with borate buffer and beta-cyclodextrin as buffer additive.

The investigation on capillary electrophoretic enantioseparation of six synthetic compounds containing vicinal diol groups has been undertaken to acquire the optimum conditions using native beta-cyclodextrin (beta-CD) as chiral selector and borate as a background electrolyte. The separation was carried out in an uncoated capillary (58.5 cm x 75 microm i.d., effective length 48.5 cm) and the effects of several important factors were investigated in detail. The results showed that beta-CD as a chiral selector exhibited good enantioselectivity and that the enantioseparation was greatly influenced by the structure of the diols, the borate concentration and the buffer pH. The optimum performance was obtained for the chiral vicinal diols under the conditions of 200 mM borate buffer of pH 9.8 containing 1.7% beta-CD at an applied voltage of 15 kV and a capillary temperature of 20 degrees C. Under the conditions, four diols were baseline separated with fast analysis time and the good theoretical plate numbers (above 10 x 10(4)) and favorable migration-time reproducibilities (RSDs below 3.0%) were obtained. The separation results were satisfactory.     

短肢剪力墙结构简化计算模型

根据短肢剪力墙结构的受力特点,建立了短肢剪力墙结构有限元分析的简化模型--考虑剪切变形的梁模型,并采用这种模型应用有限元分析软件ADINA对一算例进行抗侧刚度分析,与实验结果进行比较,结果表明该模型力学概念清晰,计算简单,而且具有较高的计算精度.     

化学教学中文献探究教学模式初探

文章对文献探究教学模式的概念、特点、功能、评价以及适用范围进行了介绍;设计出文献探究教学模式在中学化学教学中的使用程序,并且指出了运用文献探究模式教学时需要注意的事项.     

浅析加强英语听说能力的培养--从CET改革谈起

交际是学习语言的最终目的.大学英语四、六级考试改革突出了英语听说能力,其目的是促进学生重视英语交际能力.要提高学生英语交际能力,在英语教学中教师应正确处理好几对关系:听与说的关系;交际文化与语言文化的关系;教师与学生的关系;准确与流利的关系等,把握教学原则,从而加强学生的听说能力培养.     

Formation of long range ordered arrangement of quantum dots with the help of lateral centripetal flow

A simple “chimney” method was used to eliminate the voids in an arrangement of quantum dots sized 2 nm on a solid substrate, which resulted in a large well ordered superlattice of area in the order more than 1 μm². Based on the principle of speeding up the interparticle interaction of nanoparticles to overcome the particle-substrate one, a lateral centripetal force originated from a glass tube acting as a chimney in a simple evaporation device is imposed. This method allows the packing process to be controlled in a mechanical force field, that is, with the same nanogold dispersion different patterns on a substrate—from separate dots to an ordered compact monolayer or even a multilayer structure—could be easily obtained.     

半导体反型层中的电子关联和多体波函数

本文运用CBF(correlation basis function) 理论, 由电子间的有效势V_eff_(R) 和电子气的集体振荡行为, 给出准二维电子体系— 半导体反型层中的电子的关联因予U (R), 得到该体系的对关联函数、关联能和多体波函数. 关键词：     

环形线电荷的电场分布

给出了圆环形线电荷电场分布的理论公式，并利用计算机计算出其具体分布规律。     

双折射双频激光器偏振特性的分析

用激光原理和晶体光学原理分析了腔内加旋光晶体的激光器输出光的偏振特性，实验和分析表明，激光器输出两束不同频率的垂直线偏振光，激光器两端输出光的偏振面有一夹角ａ，且此夹角与晶轴和传光方向的夹角θ有关。理论计算结果在双折射双频激光器的实验结果符合很好。     

Some existence results on periodic and generalized periodic solutions for singular hamiltonian systems

In this paper, we use the variational method to study the existence of periodic and generalized periodic solutions of planar second order Hamiltonian systems when a singular potential is present. The results obtained are applied to the study of generalized periodic solutions of the Restricted Three-Body Problem and the Planarn-Body Problem.     

LF λ-subgroup Generated by LF Subset

In this paper .an important property layer-preserving of LF group and an concept LF λ-subgroup generated by LF subset will be introduced. On the height of LF group theory ,we recognize the concept generated subgroup more clearly.