高阶有限元-边界积分法在二维介质体散射中的运用

以2阶、3阶基函数为例,应用高阶有限元-边界积分法分析了二维介质体电磁散射特性。计算了2种介质材料不同,电尺寸不同的二维介质方柱的雷达散射截面,结果与矩量法一致。对3种数值结果进行了误差分析,结果表明,高阶有限元-边界积分法比1阶有更高的计算精度、收敛速度和计算效率。     

基于摆线滚轮阴模基体的步长伸缩双圆弧插补算法

阴模基体加工精度是影响摆线金刚石滚轮制造精度的关键因素。为了提高摆线滚轮阴模基体在数控机床上的加工精度,首先求解出摆线滚轮阴模基体形面曲线方程,然后基于双圆弧插补法,建立摆线滚轮阴模基体步长伸缩双圆弧插补数学模型,利用数值分析方法求解插补节点数据,控制步长伸缩以调整插补误差。通过计算实例验证了算法的可行性,结果表明：双圆弧插补误差小于0.01μm,比直线插补误差降低75%;控制步长伸缩,在相同允差下拟合圆弧段数减少55%,提高了加工效率;插补数据拟合的加工仿真曲线光滑平整,刀具路径具备G1连续性。     

散货自动化装船策略设计及算法优化

为实现大宗散货自动化装船,设计一种以平衡装载原则、货物堆积平整度和船舶安全性为基础,利用散货物料堆积特性建立理想锥体模型近似模拟物料平整堆积装船效果,建立散货装船物料堆点布置及对应装载量的自动规划策略,提出一种具有自我影响因子的改进型黄金分割法,快速构建理想平整堆积模型,优化自动规划算法效率,最后通过实验验证自动装船策...     

Na-K liquid alloy:A review on wettability enhancement and ionic carrier selection mechanism

The intrinsic liquid interface of Na-K alloy allays concerns about dendrite growth on metal anodes that are thermodynamically within the room temperature(20-22℃).Nevertheless,it hinders the formation of a stable electrode structure due to the inferior wettability induced by considerable liquid tension.In addition,the dominant ionic carrier in the Na-K alloy is subject to multiple factors,which is not conducive to customized battery design.This review,based on recently reported frontier achievements on Na-K liquid anodes,summarizes practical strategies for promoting the wettability by hightemperature induction,capillary effect,vacuum infiltration,and solid interface protection.Furthermo re,four selection mechanisms of the dominant ionic carrier are presented:(1) ion property dominated,(2)cathode dominated,(3) separator dominated,and(4) solid electrolyte interface dominated.Notably,initial electrolytes in energy storage systems have been unable to play a decisive role in ionic selection.Utilizing a superior wettability strategy and simultaneously identifying the dominant ionic carrier can facilitate the tailored application of dendrite-free Na-K liquid anodes.     

快速提升小波变换在介质体散射中的运用

推导一种用于求解介质体散射问题的面积分方程,它克服了内谐振现象,且同体积分方程相比,获得了更小的阻抗矩阵维数。一种新的基于提升法的类小波变换预处理算子的使用,降低了矩阵向量积的计算复杂度和求逆过程中的迭代次数。数值结果表明,与传统方法相比,提升法消减了预处理矩阵的多余内存,并且节省了约1倍的计算时间。     

Simultaneous Determination of Seven Lipophilic and Hydrophilic Components in Salvia miltiorrhiza Bunge by LC-MS/MS Method and Its Application to a Transport Study in a Blood-Brain-Barrier Cell Model

Salvia miltiorrhiza Bunge (SM) has been extensively used in Alzheimer’s disease treatment, the permeability through the blood-brain barrier (BBB) determining its efficacy. However, the transport mechanism of SM components across the BBB remains to be clarified. A simple, precise, and sensitive method using LC-MS/MS was developed for simultaneous quantification of tanshinone I (TS I), dihydrotanshinone I (DTS I), tanshinone IIA (TS IIA), cryptotanshinone (CTS), protocatechuic aldehyde (PAL), protocatechuic acid (PCTA), and caffeic acid (CFA) in transport samples. The analytes were separated on a C18 column by gradient elution. Multiple reaction monitoring mode via electrospray ionization source was used to quantify the analytes in positive mode for TS I, DTS I, TS IIA, CTS, and negative mode for PAL, PCTA, and CFA. The linearity ranges were 0.1–8 ng/mL for TS I and DTS I, 0.2–8 ng/mL for TS IIA, 1–80 ng/mL for CTS, 20–800 ng/mL for PAL and CFA, and 10–4000 ng/mL for PCTA. The developed method was accurate and precise for the compounds. The relative matrix effect was less than 15%, and the analytes were stable for analysis. The established method was successfully applied for transport experiments on a BBB cell model to evaluate the apparent permeability of the seven components.     

Fixed-time SOSM controller design with output constraint

Nonlinear Dynamics - In this paper, a novel fixed-time second-order sliding mode (SOSM) controller has been developed for a class of nonlinear systems with output constraints. Based on the output...     

精确模型下斜齿轮接触应力的有限元分析

探讨了基于Pro/Engineer的复杂模型的建模方法,介绍了建立斜齿轮精确模型的方法和步骤,将斜齿轮装配后导入已经嵌入到建模系统的有限元环境内,利用有限元软件对已经建立的斜齿轮模型施加约束、划分网格、建立接触对,对接触应力进行精确的计算,并把分析的结果与传统方法计算得到的数据对比,为以斜齿轮为零部件的产品设计提供了可靠的依据和精确的数据,为工程设计中发挥专业软件和计算机的优势提供了新的思路.     

超高效液相色谱-四极杆/静电场轨道阱高分辨质谱对粮谷产品中20种真菌毒素的快速筛查和确证

建立了超高效液相色谱-四极杆/静电场轨道阱高分辨质谱快速筛查和确证粮谷产品中20种真菌毒素的方法。样品经乙腈（含2%（体积分数）甲酸）提取,用Captiva EMR-Lipid小柱净化,采用Thermo Hypersil Gold C₁₈柱（100 mm×2.1 mm,1.9 μm）分离,用四极杆/静电场轨道阱高分辨质谱进行分析。在全扫描模式下以分析物的保留时间和一级母离子信息实现快速筛查,以自动触发采集的二级碎片离子信息进行确证。结果显示,目标分析物在各自的质量浓度范围内线性关系良好（相关系数r²>0.99）,方法检出限为0.25~20 μg/kg,回收率为72.9%~117.8%,相对标准偏差为2.9%~15.2%（n=6）。该方法灵敏度高,结果准确、可靠,适用于粮谷产品中20种真菌毒素的快速筛查和确证。     

Metal–Organic Framework Membrane Nanopores as Biomimetic Photoresponsive Ion Channels and Photodriven Ion Pumps

Biological ion channels and ion pumps with sub‐nanometer sizes modulate ion transport in response to external stimuli. Realizing such functions with sub‐nanometer solid‐state nanopores has been an important topic with wide practical applications. Herein, we demonstrate a biomimetic photoresponsive ion channel and photodriven ion pump using a porphyrin‐based metal–organic framework membrane with pore sizes comparable to hydrated ions. We show that the molecular‐size pores enable precise and robust optoelectronic ion transport modulation in a broad range of concentrations, unparalleled with conventional solid‐state nanopores. Upon decoration with platinum nanoparticles to form a Schottky barrier photodiode, photovoltage across the membrane is generated with “uphill” ion transport from low concentration to high concentration. These results may spark applications in energy conversion, ion sieving, and artificial photosynthesis.