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21.
Galtchouk Leonid I. Pergamenshchikov Serge M. 《Statistical Inference for Stochastic Processes》2022,25(1):127-158
Statistical Inference for Stochastic Processes - We consider drift estimation problems for high dimension ergodic diffusion processes in nonparametric setting based on observations at discrete... 相似文献
22.
Arcadiy V. Krasheninnikov Konstantin E. Kon’kov Leonid A. Openov Vladimir F. Elesin 《Czechoslovak Journal of Physics》1996,46(3):1197-1198
The effect of ion irradiation on the superconducting transition temperatureT c and resistivityρ ab (T) of YBa2Cu3O7-x films with different oxygen content (initial temperatureT c0≈90 K and 60 K) is studied experimentally. The dependenciesT c /T c0 on residual resistivityρ o are obtained in very wide range 0.2<T c /T c0 <1 andρ o μΩ·cm. The critical values ofρ o , corresponding to the vanishing of superconductivity, are found to be an order of magnitude larger then those predicted by theory ford-wave pairing. At 0.5÷0.6<T c /T c0<1 the experimental data are in close agreement with theoretical dependencies, obtained for the anisotropics-wave superconductor within the BCS-framework. 相似文献
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24.
We show that an ε-approximate solution of the cost-constrainedK-commodity flow problem on anN-nodeM-arc network,G can be computed by sequentially solving O(K(? ?2+logGK) logGM log (G? ?1 GK)) single-commodity minimum-cost flow problems on the same network. In particular, an approximate minimum-cost multicommodity flow can be computed in $\tilde O$ (G? ?2 GKNM) running time, where the notation Õ(·) means “up to logarithmic factors”. This result improves the time bound mentioned by Grigoriadis and Khachiyan [4] by a factor ofM/N and that developed more recently by Karger and Plotkin [8] by a factor of? ?1. We also provide a simple $\tilde O$ (NM)-time algorithm for single-commodity budget-constrained minimum-cost flows which is $\tilde O$ (? ?3) times faster than the algorithm developed in the latter paper. 相似文献
25.
Han J Kaledin LA Goncharov V Komissarov AV Heaven MC 《Journal of the American Chemical Society》2003,125(24):7176-7177
Accurate ionization potential (IP) measurements provide essential thermodynamic information and benchmark data that can be used to evaluate the validity of electronic structure models. Calculations of the first IP of UO2 using relativistic methods consistently predict values that are approximately 0.7 eV higher than the accepted experimental value. The present measurements validate the theoretical calculations and show that the previous determinations corresponded to the ionization of thermally excited molecules. Similarly, new measurements of the IP for UO show that the currently accepted value is too low by 0.4 eV. 相似文献
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27.
Close DM Crespo-Hernández CE Gorb L Leszczynski J 《The journal of physical chemistry. A》2005,109(41):9279-9283
In the present study the ionization energy thresholds (IET's) of uracil and thymine have been calculated (with the B3LYP, PMP2, and P3 levels of theory using the standard 6-31++G(d,p) basis set) with one to three water molecules placed in the first hydration shell. Then (B3LYP) polarizable continuum model (PCM) calculations were performed with one to three waters of the hydration shell included. Calculations show there is a distinct effect of microhydration on uracil and thymine. For uracil, one added water results in a decrease in the IET of about 0.15 eV. The second and third water molecules cause a further decrease by about 0.07 eV each. For thymine, the first water molecule is seen to decrease the IET by about 0.1 eV, while the second and third water molecules cause a further decrease of less than 0.1 eV each. The changes in IET calculated here for thymine with one to three waters of hydration are smaller than the experimental values determined by Kim et al. (Kim, S. K.; Lee, W.; Herschbach, D. R. J. Phys. Chem. 1996, 100, 7933). Preliminary results presented here indicate that the experimental results may involve keto-enol tautomers of thymine. The results of placing the microhydrated structures of uracil and thymine in a PCM cavity was seen to make very little difference in the IET when compared to the IET of ordinary uracil or thymine in a PCM cavity. The implications are that accurate calculations of the IET's of uracil and thymine can be obtained by simply considering long-range solvation effects. 相似文献
28.
Tanskanen H Khriachtchev L Räsänen M Feldman VI Sukhov FF Orlov AY Tyurin DA 《The Journal of chemical physics》2005,123(6):64318
Vinyl radicals produced by annealing-induced reaction of mobilized hydrogen atoms with acetylene molecules in solid noble-gas matrices (Ar, Kr, and Xe) were characterized by Fourier transform infrared and electron paramagnetic resonance (EPR) spectroscopies. The hydrogen atoms were generated from acetylene by UV photolysis or fast electron irradiation. Two vibrational modes of the vinyl radical (nu7 and nu5) were assigned in IR absorption studies. The assignment is based on data for various isotopic substitutions (D and 13C) and confirmed by comparison with the EPR measurements and density-functional theory calculations. The data on the nu7 mode is in agreement with previous experimental and theoretical results whereas the nu5 frequency agrees well with the computational data but conflicts with the gas-phase IR emission results. 相似文献
29.
The concentration sensitivity of a thermal conductivity detector (TCD) depends, among other factors, on the amount of sample mixture in the detector's sensing cell. Since the cell volume has to be appropriately matched with column diameter, it makes the concentration sensitivity of a TCD dependent on column diameter and, therefore, on the speed of gas chromatography. Through reduction of column diameter, higher speed tends to lead to a reduction in the concentration sensitivity of the cell. The factor which the most directly affects the concentration sensitivity of a TCD cell is the heat power conducted through the cell. The higher the power, the greater the sensitivity. The limit of detection of a TCD depends on the concentration-sensitivity of its cell and on the level of statistical errors in the measurement. The errors increase with increasing analysis speed. As the column diameter is reduced, the errors cause additional worsening (on top of the decrease in concentration sensitivity) of the detection limit, dynamic range, and other performance characteristics of the TCD. 相似文献
30.
Nemukhin AV Grigorenko BL Khriachtchev L Tanskanen H Pettersson M Räsänen M 《Journal of the American Chemical Society》2002,124(36):10706-10711
Theoretical and matrix-isolation studies of intermolecular complexes of HXeOH with water molecules are presented. The structures and possible decomposition routes of the HXeOH-(H(2)O)(n)(n = 0, 1, 2, 3) complexes are analyzed theoretically. It is concluded that the decay of these metastable species may proceed through the bent transition states (TSs), leading to the global minima on the respective potential energy surfaces, Xe + (H(2)O)(n+1). The respective barrier heights are 39.6, 26.6, 11.2, and 0.4 kcal/mol for n = 0, 1, 2, and 3. HXeOH in larger water clusters is computationally unstable with respect to the bending coordinate, representing the destabilization effect. Another decomposition channel of HXeOH-(H(2)O)(n), via a linear TS, leads to a direct break of the H-Xe bond of HXeOH. In this case, the attached water molecules stabilize HXeOH by strengthening the H-Xe bond. Due to the stabilization, a large blue shift of the H-Xe stretching mode upon complexation of HXeOH with water molecules is featured in calculations. On the basis of this computational result, the IR absorption bands at 1681 and 1742 cm(-1) observed after UV photolysis and annealing of multimeric H(2)O/Xe matrixes are assigned to the HXeOH-H(2)O and HXeOH-(H(2)O)(2) complexes. These bands are blue-shifted by 103 and 164 cm(-1) from the known monomeric HXeOH absorption. 相似文献