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11.
Joshua Lee Yuheng Bu Prasanna Sattigeri Rameswar Panda Gregory W. Wornell Leonid Karlinsky Rogerio Schmidt Feris 《Entropy (Basel, Switzerland)》2022,24(4)
As machine learning algorithms grow in popularity and diversify to many industries, ethical and legal concerns regarding their fairness have become increasingly relevant. We explore the problem of algorithmic fairness, taking an information–theoretic view. The maximal correlation framework is introduced for expressing fairness constraints and is shown to be capable of being used to derive regularizers that enforce independence and separation-based fairness criteria, which admit optimization algorithms for both discrete and continuous variables that are more computationally efficient than existing algorithms. We show that these algorithms provide smooth performance–fairness tradeoff curves and perform competitively with state-of-the-art methods on both discrete datasets (COMPAS, Adult) and continuous datasets (Communities and Crimes). 相似文献
12.
Margarita A. Epishina Alexander S. Kulikov Leonid L. Fershtat 《Molecules (Basel, Switzerland)》2022,27(8)
A series of novel 1,4-dihydrobenzo[1,2,4][e]triazines bearing an acetyl or ester moiety as a functional group at the C(3) atom of the 1,2,4-triazine ring were synthesized. The synthetic protocol is based on an oxidative cyclization of functionally substituted amidrazones in the presence of DBU and Pd/C. It was found that the developed approach is suitable for the preparation of 1,4-dihydrobenzo[e][1,2,4]triazines, but the corresponding Blatter radicals were isolated only in few cases. In addition, a previously unknown dihydrobenzo[e][1,2,4]triazolo[3,4-c][1,2,4]triazine tricyclic open-shell derivative was prepared. Studies of thermal behavior of the synthesized 1,4-dihydrobenzo[1,2,4][e]triazines revealed their high thermal stability (up to 240–250 °C), which enables their application potential as components of functional organic materials. 相似文献
13.
Oleksandr Kramar Yuriy Skorenkyy Leonid Didukh Yuriy Dovhopyaty 《Molecular Crystals and Liquid Crystals》2018,671(1):55-66
AbstractPhenomenon of ferromagnetic ordering was for a long time associated exclusively with transition metal and rare-earth compounds. Nowadays this view is challenged by growing evidence that in molecular carbon-based systems the ferromagnetic alignment of spins can be observed as well. We have developed a microscopical model of a fulleride electronic subsystem taking into account triple orbital degeneracy of energy states within the configurational-operator approach. Using the Green function method the energy spectrum of the model has been calculated. Conditions for the ferromagnetic state stabilization have been determined. Static electrical conductivity and effective masses of current carriers in the system with orbitally degenerated energy band have been obtained. In the ground state and for low temperatures at different forms of unperturbed density of electronic states the concentration dependences of transport characteristics for less-then-half-filled lower quasiparticle subband have been calculated. 相似文献
14.
Jonathan Lee Anupama Yadav Michael Antia Valentina Zaffino Leonid Chernyak 《辐射效应与固体损伤》2017,172(3-4):250-256
The impact of internal irradiation with secondary Compton electrons, generated by gamma-photons, on the characteristics of III-N/GaN-based devices was explored. N-channel AlGaN/GaN high-electron-mobility transistors (HEMTs) were exposed to gamma-radiation from a 60Co source for doses up to 600?Gy. Temperature-dependent electron beam-induced current (EBIC) was employed to measure minority carrier transport properties. For low doses below ~250?Gy, the minority carrier diffusion length in AlGaN/GaN HEMTs is shown to increase by about 40%. This increase is likely due to longer minority carrier lifetime induced by internal Compton electron irradiation. An associated decrease in activation energy, extracted from temperature-dependent EBIC, was also found. The obtained increase in transconductance and decrease in gate leakage current indicate an improvement in performance of the devices after low doses of irradiation. For high doses of gamma-irradiation, above ~300?Gy, the performance of HEMTs showed a deterioration. The deterioration results from the onset of increased carrier scattering due to additional radiation-induced defects, as is translated in a decrease of minority carrier diffusion length. 相似文献
15.
Bushmeleva A. S. Tafeenko V. A. Zakharov V. N. Lobova A. A. Aslanov Leonid A. 《Structural chemistry》2019,30(2):425-434
Structural Chemistry - Contradictory literature on the alkali-assisted exfoliation of the melon and searching for the best precursors for different heptazine derivative synthesis led us to the... 相似文献
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Taking the m-power of an entry is a well-defined operation on the unimodular vectors in An modulo addition operations, if n is at least 3, for an arbitrary commutative ring A and any integer m. 相似文献
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The vibronic and spin-orbit-induced interactions among the (3)Sigma(-), (1)Delta, and (1)Sigma(+) electronic states arising from a half-filled pi orbital of a linear triatomic molecule are considered, employing the microscopic (Breit-Pauli) spin-orbit coupling operator. The 6 x 6 Hamiltonian matrix is derived in a diabatic spin-orbital electronic basis set, including terms up to fourth order in the expansion of the molecular Hamiltonian in the bending normal coordinate about the linear geometry. The symmetry properties of the Hamiltonian are analyzed. Aside from the nonrelativistic fourth-order Renner-Teller vibronic coupling within the (1)Delta state and the second-order nonrelativistic vibronic coupling between the (1)Sigma(+) and (1)Delta states, there exist zeroth-order, first-order, as well as third-order vibronic coupling terms of spin-orbit origin. The latter are absent when the phenomenological expression for the spin-orbit coupling operator is used instead of the microscopic form. The effects of the nonrelativistic and spin-orbit-induced vibronic coupling mechanisms on the (3)Sigma(-), (1)Delta, and (1)Sigma(+) adiabatic potential energy surfaces as well as on the spin-vibronic energy levels are discussed for selected parameter values. 相似文献
20.
Kuznetsov Vitaly V. Pavlov Leonid N. Filatova Elena A. Vinokurov Eugeny G. 《Journal of Solid State Electrochemistry》2018,22(1):217-225
Journal of Solid State Electrochemistry - Electrodeposition of chromium from both CrCl2- and CrCl3-containing dimethylformamide (DMF)–water solutions is studied. It is found that the process... 相似文献