短柄泥蜂属一新种记述(膜翅目:泥蜂总科:短柄泥蜂科)

本文记述了泥蜂总科Sphecoidea短柄泥蜂科Pemphredonidae短柄泥蜂属Pemphredon Latreille一新种:赵氏短柄泥蜂Pemphredon chaoi Li et He,sp. nov. 模式标本保存在中国科学院动物研究所。     

钻井液在致密砂岩中裂缝的侵入深度模型

克深井区储层的孔隙结构与裂缝特征造成钻井过程中钻井液大量漏失,其中的固相颗粒会堵塞裂缝,使得部分生产井在完井后产量偏低甚至无产量,现场主要是通过酸压来解决这类问题。对于裂缝性气藏的酸压而言,需要知道钻井液在裂缝中的侵入深度变化,以便于设计施工参数,评价酸压效果。针对这一问题,根据牛顿流体在裂缝中的流动机理,裂缝宽度的变化以及裂缝壁面的滤失等,建立了钻井液在单一裂缝中的漏失动力模型,根据裂缝内钻井液压力的分布来定量描述钻井液的侵入深度,考虑并分析了该模型的侵入深度与侵入时间,压差和裂缝宽度之间的相互关系。最后,利用该模型计算了克深井区获得增产效果的酸压井中钻井液的侵入深度和酸液的侵入深度,通过增产井中二者之间的关系,从而间接证明了该模型。     

Enantioselective Hydrogenation of Endocyclic Enones:the Solution to a Historical Problem

The enantioselective hydrogenation of endocyclic enones has been a historical problem for homogeneous catalysis.We herein report an efficient method to reduce e...     

一种新型的CPU故障检测方法及其应用

本文根据国产新型单路数字新闻传真系统的特点,采用一种新颖而有效的 CPU 故障诊断算法.此方法的故障覆盖率较高,在程序运行后,得到令人满意的效果.     

CaO/MgO和CaO/Ca9Al6O18吸收CO2的循环反应特性研究

钙基吸收剂是CO2捕集技术中常用的吸收剂,但随着循环次数的增加,天然钙基吸收剂循环反应特性下降明显.采用葡萄糖酸钙(Ca(C6H11O7)2)与葡萄糖酸镁(C12H22MgO14)及L-乳酸铝([CH3CH(OH)COO]3Al)作为前驱物,通过湿法混合的方法处理,制得了5种新型钙基吸收剂,试验研究了其吸收CO2的循环吸收能力及循环稳定性,分析了吸收剂组分、煅烧温度、煅烧气氛等条件对新型吸收剂循环反应特性的影响规律.研究结果表明,选用此前驱物制备的吸收剂,其循环反应特性明显高于传统的钙基吸收剂;其中,CaO/MgO(75wt%/25wt%)吸收剂具有最好的循环吸收能力,CaO/Ca9Al6O18(75wt%/wt25%)吸收剂具有最好的循环稳定性.通过研究煅烧条件对这两种吸收剂循环反应特性的影响,得到:850℃时,吸收剂表现出最佳的反应特性,而随着温度的升高,吸收剂的循环吸收能力有所下降;煅烧气氛对吸收剂循环吸收特性的影响与煅烧温度有显著的关系.     

基于MVC的通用型模式的设计与实现

针对单机、C/S和B/S这3种主流结构在MVC模式层次结构上的异同点,提出了对3层MVC模式的表现层进行拓展,加入Model,构建通用型MVC模式的设计方法,解决了在系统开发中这3种结构间转换的难题,提高了系统的可扩展性、可维护性和可复用性,并以大学物理仿真实验为例实现了通用型MVC模式的设计.     

Butterfly and Nest-Shaped Tp*-W-Cu-S Cluster Monomers and Dimers with Hexamethylenetetramine as Ligand: Anion-Dependent Structures and Nonlinear Optical Properties

The assembly of[Et4N][Tp*WS3](1) with CuX (Tp* =hydridotris(3,5-dimethylpyrazol-1-yl)borate;X =Cl,Br,and I) or[Cu(MeCN)4][PF6]in the presence of tetratopic liga...     

Insights into the Allosteric Effect of SENP1 Q597A Mutation on the Hydrolytic Reaction of SUMO1 via an Integrated Computational Study

Small ubiquitin-related modifier (SUMO)-specific protease 1 (SENP1) is a cysteine protease that catalyzes the cleavage of the C-terminus of SUMO1 for the processing of SUMO precursors and deSUMOylation of target proteins. SENP1 is considered to be a promising target for the treatment of hepatocellular carcinoma (HCC) and prostate cancer. SENP1 Gln597 is located at the unstructured loop connecting the helices α4 to α5. The Q597A mutation of SENP1 allosterically disrupts the hydrolytic reaction of SUMO1 through an unknown mechanism. Here, extensive multiple replicates of microsecond molecular dynamics (MD) simulations, coupled with principal component analysis, dynamic cross-correlation analysis, community network analysis, and binding free energy calculations, were performed to elucidate the detailed mechanism. Our MD simulations showed that the Q597A mutation induced marked dynamic conformational changes in SENP1, especially in the unstructured loop connecting the helices α4 to α5 which the mutation site occupies. Moreover, the Q597A mutation caused conformational changes to catalytic Cys603 and His533 at the active site, which might impair the catalytic activity of SENP1 in processing SUMO1. Moreover, binding free energy calculations revealed that the Q597A mutation had a minor effect on the binding affinity of SUMO1 to SENP1. Together, these results may broaden our understanding of the allosteric modulation of the SENP1−SUMO1 complex.     

Steam-assisted crystallization of highly dispersed nanosized hierarchical zeolites from solid raw materials and their catalytic performance in lactide production

A solvent-free route based on solid raw materials affords higher product yield and lower waste production compared to the traditional hydrothermal synthesis. However, the as-made zeolites usually present blocky aggregation states, limiting their mass transfer and exposure of active sites in catalytic applications. Herein, highly dispersed nanosized hierarchical Beta zeolites with varied Si/Al ratios were prepared via steam-assisted crystallization from ball-milled solid raw materials. Thanks to the sufficient mixing of solid raw materials and favorable migration of solid mixture, nanosized Beta zeolites are obtained that are assembled from nanoparticles (∼15 nm) and possess abundant interconnected intraparticle mesopores. The strategy can also be extended to synthesize nanosized hierarchical ZSM-5 zeolites. The as-prepared Beta zeolite (Si/Al = 10) exhibits outstanding catalytic performance in conversion of lactic acid to lactide (as high as 77.5% in yield). This work provides avenues for simple and cost-efficient synthesis of highly dispersed nanosized hierarchical zeolites, promising their important catalytic applications.

A cost-effective synthesis strategy based on steam-assisted crystallization from ball-milled solid raw materials is developed to prepare a highly dispersed nanosized hierarchical Beta zeolite for conversion of lactic acid (LA) to lactide (LT).