Synthesis and characterization of liquid crystalline side‐chain block copolymers containing luminescent 4,4′‐bis(biphenyl)fluorene pendants

A series of new liquid crystalline homopolymers, copolymers, and block copolymers were polymerized from styrene‐macroinitiator ( SMi ) and methacrylates with pendent 4,4′‐bis(biphenyl)fluorene ( M1 ) and biphenyl‐4‐ylfluorene ( M2 ) groups through atom transfer radical polymerization (ATRP). The number‐average molecular weights (Mn) of polymers P1 ‐ P4 were 10,007, 14,852, 6,275, and 10,463 g mol^?1 with polydispersity indices values of 1.21, 1.15, 1.31, and 1.22, respectively. All polymers exhibit the nematic phase. The thermal, mesogenic, and photoluminescent properties of all polymers were investigated. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 4564–4572, 2007     

Synthesis and characterization of wholly aromatic poly(azomethine)s containing donor–acceptor triphenylamine moieties

N‐(4‐nitrophenyl)‐4′,4″‐bisformyl‐diphenylamine was synthesized from N‐(4‐nitrophenyl)‐diphenylamine by the Vilsmeier‐Haack reaction. Soluble aromatic poly(azomethine)s (PAMs) were prepared by the solution polycondensation of N‐(4‐nitrophenyl)‐4′,4″‐bisformyl‐diphenylamine and aromatic diamine in N‐methyl‐2‐pyrrolidone (NMP) at room temperature under reduced pressure. All the PAMs are highly soluble in various organic solvents, such as N,N‐dimethylacetamide (DMAc), chloroform (CHCl₃), and tetrahydrofuran (THF). Differential scanning calorimetry (DSC) indicated that these PAMs had glass‐transition temperatures (T_gs) in the range of 170–230 °C, and a 10% weight‐loss temperatures in excess of 490 °C with char yield at 800 °C in nitrogen higher than 60%. These PAMs in NMP solution showed UV‐Vis charge‐transfer (CT) absorption at 405–421 nm and photoluminescence peaks around 462–466 nm with fluorescence quantum efficiency (Φ_F) 0.10–0.99%. The highest occupied molecular orbital (HOMO) and lowest unoccupied molecular orbital (LUMO) energy levels of these PAMs can be determined from cyclic voltammograms as 4.86–5.43 and 3.31–3.34 eV, respectively. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 4921–4932, 2007     

Multiple MIPS 4Kc cores based interrupt controller design and its implementation on HDTV SoC platform

A multiple MIPS 4Kc processor cores based interrupt processing system is introduced. The interrupt controller plays a key role in the high definition television （HDTV） system-on-a-chip （SoC） platform, especially when it is a multiple processor system. Based on a general introduction to the whole HDTV SoC platform, a layered interrupt controller and its implementation are discussed in detail. The proposed scheme was implemented in our FPGA verification board. The results indicate that our scheme is reliable and efficient. Meanwhile, as a functional intellectual property （IP）, the interrupt controller has reusability and expandability with the layered structure.     

数控机床伺服系统故障的维修

列举了数据机床故障实例,介绍了数控机床伺服系统故障的维修。     

NiAl金属间化合物熔体旋转法制备工艺参数研究

研究了金属间化合物快速凝固薄带的成型过程和影响薄带质量的工艺参数。提出了熔体在喷嘴处进行层流流动的经验关系式，给出了金属间化合物快速凝固薄带制备的最佳工艺参数。     

内含热薄透镜CW色心激光腔的振荡光束特性

运用像镜原理分析三镜折迭腔、四镜折迭腔和四镜8字型环形腔等光学谐振腔的振荡光束特性及其热行为。讨论热效应对谐振腔振荡光束特性的影响规律以及像镜分析方法的精确性,给出谐振腔的热不灵敏条件。     

饲育条件下Semisulcospiens decipiens的生长

在饲育温度条件下研究了Ｓ．ｄｅｃｉｐｉｅｎｓ的生长和产仔数及与饲育水温的关系。结果表明水温在上升期和下降期，新生贝和稚贝的生长速度较快，产仔数也较多．成体贝在水温１１℃～２９℃时，都可产出新生贝，以１８℃～２４℃时产出较多．在高温饲育条件下，成体贝的生长速度缓慢。     

城市规划辅助审批系统中的相似度研究

城市规划的审批是一件难于量化的工作，它受政治经济等多方面因素影响，是城市规划领域关注的一大焦点．本文尝试将CBR技术用于城市规划辅助审批，让政府的审批依据达到历史与现实的统一．实现CBR的一个关键是相似度的设计，本文结合城市规划辅助审批领域的特点，设计了可行的方案，并应用于实际的办公系统中．     

低温电解渗硫及其应用研究

本文研究了１８ＣｒＭｎＴｉ钢渗碳＋低温电解渗硫工艺及硬质合金刀具低温电解渗硫工艺．考核了刀具的耐用度。试验结果表明．低温电解渗硫提高了切削刀具的使用寿命。