Lanthanide Complexes for Oligomerization of Phenyl Isocyanate

IntroductionThestudyonthereactivitiesoflanthanidecomplexesto wardisocyanateshasattractedmuchattention .Ithasbeenre portedthatlanthanidealkoxides,1anddivalentdiaza pentadi enyllanthanidecomplexes2 canbeusedasthesinglecompo nentinitiatorsforisocyanatespolymerization .Recentlyourre searchgrouphasalsofoundthatlanthanoceneamide ,3diva lentaryloxideofsamarium4 ,5anddivalentsamarocene6 areallactivefortheoligomerizationofphenylisocyanate,andtheactivespeciesforthesethreesystemswereallsuccessfullyisolat…     

Strong limit-point classification of singular Hamiltonian expressions

Strong limit-point criteria for singular Hamiltonian differential expressions with complex coefficients are obtained. The main results are extensions of the previous results due to Everitt, Giertz, and Weidmann for scalar differential expressions.

     

对英语专业八级口语口译考试评分的探讨

本文通过对英语专业八级口语口译考试的评分标准的考察，指出八级口语口译考试评分中两个突出的特点，即突出口语考试和口译考试评分“信息单元化”，从而影响口译质量评估的有效性。适当改变评分比例和口译评分标准的改进将有助于改善测评效果。     

Classical Limit of Expectation Values in a Wave Packet Involving Few Stationary States

Expectation values of physical quantities in a wave packet involving few stationary states in an infinite square well are calculated. Explicit results show that the expectation values in the classical limit go over to the corresponding classical quantity in the form of the arithmetic mean (in mathematical term, the Fejér's average) of the partial Fourier series converging to the classical quantity. The number of the stationary states is that of the partial Fourer series in the Fejér's average. The quantum uncertainty is then demonstrated to have a classical counterpart.     

音乐心理学在儿童音乐教育中的研究与应用

音乐心理是人脑的特殊机能,是大脑对客观音乐现实的主观反应.黑格尔曾说过:"音乐是进入更高的知识世界的唯一的、非物质的方法."说明了音乐心理学在音乐再教育中具有更科学的作用和更崇高的地位.     

Nonparametric estimation of distributions with categorical and continuous data

In this paper we consider the problem of estimating an unknown joint distribution which is defined over mixed discrete and continuous variables. A nonparametric kernel approach is proposed with smoothing parameters obtained from the cross-validated minimization of the estimator's integrated squared error. We derive the rate of convergence of the cross-validated smoothing parameters to their ‘benchmark’ optimal values, and we also establish the asymptotic normality of the resulting nonparametric kernel density estimator. Monte Carlo simulations illustrate that the proposed estimator performs substantially better than the conventional nonparametric frequency estimator in a range of settings. The simulations also demonstrate that the proposed approach does not suffer from known limitations of the likelihood cross-validation method which breaks down with commonly used kernels when the continuous variables are drawn from fat-tailed distributions. An empirical application demonstrates that the proposed method can yield superior predictions relative to commonly used parametric models.     

Synthesis and transition temperatures of liquid crystals incorporating a 1,4-tetrafluorophenylene unit

Two homologous series of mesogenic materials which incorporate a 1,4-tetrafluorophenylene moiety and a terminal cyano- or nitro-substituent have been synthesized by using palladiumcatalysed coupling procedures. The compounds exhibit nematic and/or smectic A phases.     

Robinson-Trautman equations and Chandrasekhar's special perturbation of the Schwarzschild metric

A perturbation wave solution of the Robinson-Trautman equations is proved to be a perturbation of the Schwarzschild black hole which describes an outgoing axial gravitational wave and corresponds to a special case of Chandrasekhar's algebraically special perturbation of the Schwarzschild metric.     

A problem in extremal quasiconformal extensions

A constantK ₀ ^(m) (h) is introduced for every quasisymmetric mappingh of the unit circle and every integerm≥4 which contains the constantK ₀(h) (indicated by the change in module of the quadrilaterals with vertices on the circle) as a special case. A necessary and sufficient condition is established forK ₀ ^(m) (h) =K ₁(h). It is shown that there are infinitely many quasisymmetric mappings of the unit circle having the property thatK ₀ ^(m) (h)<K ₁(h), wherek ₁(h) is the maximal dilatation ofh.