基于压力拱理论的深埋节理岩体隧道围岩压力研究

为研究节理岩体隧道围岩压力计算方法,以隧道压力拱理论为基础,通过离散元数值模拟分析了岩体的坚硬程度、完整程度和结构面的抗剪强度对隧道压力拱的影响,应用多元线性回归拟合了多因素围岩压力公式,并结合依托工程对拟合公式进行了适用性分析。结果表明：节理岩体隧道压力拱范围为拱顶到最大主应力方向的偏转点,隧道压力拱高度随着节理间距和结构面的抗剪强度的增大而减小,岩体力学参数对压力拱高度的影响较小;与现场实测的围岩压力相比,计算误差在15％以内。所提围岩压力公式适用性良好,为节理岩体的围岩压力计算提供了新的思路。     

尖晶石型LiMn2O4的低温制备

锂锰氧化物;溶胶凝胶法;尖晶石型LiMn2O4的低温制备     

Coral reef-like polyanaline nanotubes prepared by a reactive template of manganese oxide for supercapacitor electrode

Coral reef-like PANI nanotubes composed of nanopaticles were successfully synthesized by a reactive template of manganese oxide.The structure was characterized by using SEM,TEM,and FT-IR,and the supercapacitive behaviors of these nanotubes were investigated with cyclic voltammetry（CV）,and charge-discharge tests,respectively.A maximum specific capacitance of 533 F/g could be achieved in 1mol/L aqueous H₂SO₄ with the potential range of -0.2 to 0.8 V（vs.the saturated calomel electrode） in a half-cell setup configuration for PANI electrode,suggesting its potential application in the electrode material for electrochemical capacitors.     

Polymeric ytterbium(ii) complex with pyridyl amido ligands

The reaction of potassium pyridyl amido ligand {L = [N(R)(2-C5H3N-6-Me)]–, R = CH2But} with YbI2(thf)2 afforded the linear polymeric complex [K0.5(L)3YbiiK0.5]n, which was characterized by X-ray structure analysis.     

Development of a test strip based on DNA-functionalized gold nanoparticles for rapid detection of mercury(II) ions

A rapid,sensitive,selective and reliable strip assay based on DNA-functionalized gold nanoparticles for Hg²⁺ detection has been developed,with a detection limit 5 nmol/L.The measurement principle was based on thymine-Hg²⁺-thymine(T-Hg²⁺-T) coordination chemistry and streptavidin-biotin interaction.The major advantages of this assay are that results can be read visually without any instrument in less than 10 min and that it does not require any sample pretreatment.     

Corrosion inhibition of ammonium molybdate for AA6061 alloy in NaCl solution and its synergistic effect with calcium gluconate

The corrosion inhibition of ammonium heltamolybdate (AH) and calcium gluconate (CG) for AA6061 alloy in 3% NaCl solution was investigated by the electrochemical measurements. It indicates that AH inhibits the corrosion of AA6061 alloy and acts as an anodic inhibitor. Maximum inhibition efficiency reaches 74.3% at the concentration of 1 × 10^?4 mol.l^?1 AH. The results of the electrochemical studies reveal AH is physically adsorbed on the AA6061 alloy surface and the adsorption follows Langmuir isotherm. The combination of AH and CG enhances the inhibition efficiency to 95.9%. The enhanced inhibition is attributed to the promotion of AH adsorption by CG. The mixture of AH and CG is a mixed‐type inhibitor and renders the corrosion potential to more positive values. Copyright © 2011 John Wiley & Sons, Ltd.     

Sorption equilibria of CO2 on silica-gels in the presence of water

The sorption equilibria of carbon dioxide on three types of silica gel (SG) with different pore size distributions in the presence of water were studied experimentally using a volumetric method at 275?K with pressures from 0 to 3.7?MPa. Both the pore size distribution of the silica gel and the quantity of pre-sorbed water impact the formation of the CO₂ hydrates. For wet silicon gel A(SG-A) with water loading ratio of 0.75, the highest CO₂ sorption was about 2.5?mmol of CO₂ per gram of dry sorbent at 275?K. Similarly, the highest sorption was about 2.7?mmol for wet SG-B with R _w =0.81. However, CO₂ hydrate did not form on the wet surface of SG-C due to its large pore sizes.     

一种新型的多址接入中继协作方案

现有多址中继协作方案的编码增益有限且用户之间不能相互辅助,为此,文中提出了一种结合网络与信道编码的多址中继协作方案:在中继端利用网络编码将不同用户的编码冗余同时转发,目的端通过对某个用户信息的正确译码恢复出其他用户的编码冗余.通过对译码错误事件概率的分析,推导了该方案的中断率与误码率近似值表达式.仿真结果表明,随着信噪比的提升,文中方案可获得比编码协作更好的中断率和误码率性能,同时信噪比较高的用户还可辅助提升信噪比较低的用户的性能.