First-principles study of structural stability and elastic property of pre-perovskite PbTiO3

The structural stability and the elastic properties of a novel structure of lead titanate,which is named preperovskite PbTiO₃ （PP-PTO） and is constructed with TiO₆ octahedral columns arranged in a one-dimensional manner,are investigated by using first-principles calculations.PP-PTO is energetically unstable compared with conventional perovskite phases,however it is mechanically stable.The equilibrium transition pressures for changing from preperovskite to cubic and tetragonal phases are 0.5 GPa and 1.4 GPa,respectively,with first-order characteristics.Further,the differences in elastic properties between pre-perovskite and conventional perovskite phases are discussed for the covalent bonding network,which shows a highly anisotropic character in PP-PTO.This study provides a crucial insight into the structural stabilities of PP-PTO and conventional perovskite.     

Synthesis and characterization of eumelanin‐inspired poly(indoylenearylenevinylene)s and poly(indoylenearyleneethynylene)s

Four novel conjugated polymers containing the eumelanin‐inspired indole core have been successfully synthesized using common cross coupling reactions. These polymers differed by the arylene and the carbon–carbon bond linkage. Optoelectronic experiments of these polymers suggest that the ethynylene linkage contributed to the red‐shifted absorption spectra and blue‐shifted emission spectra when compared to the vinylene linkage polymers. Furthermore, the optical bandgaps of the poly(indoylenearyleneethynylene)s (PIAEs) were smaller compared to the poly(indoylenearylenevinylene)s (PIAVs). Surprisingly, the HOMOs of these polymers were less affected by the nature of the carbon–carbon linkage. However, the LUMOs of the PIAEs were lower in comparison to the PIAVs. These eumelanin‐inspired PIAEs and PIAVs are good fluorophores with fluorescence quantum yields ranging from 0.12 to 0.67 and have good thermal stability for applications such as in organic light‐emitting diodes. © 2016 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2017 , 55, 457–463     

电子商务环境下RBAC模型的扩展

随着电子商务系统规模的膨胀,基于角色的访问控制模型面临着角色庞大、管理复杂等问题.在提出用户组角色的概念和规则的基础上,扩展了RBAC访问控制模型,给出其在XACML框架下的描述与设计,最后用Java语言实现了扩展的RBAC模型.     

Semiparametric Preference Learning

Unlike traditional supervised learning problems,preference learning learns from data available in the form of pairwise preference relations between instances.Existing preference learning methods are either parametric or nonparametric in nature.We propose in this paper a semiparametric preference learning model,abbreviated as SPPL,with the aim of combining the strengths of the parametric and nonparametric approaches.SPPL uses multiple Gaussian processes which are linearly coupled to determine the preference relations between instances.SPPL is more powerful than previous models while keeping the computational complexity low （linear in the number of distinct instances）.We devise an efficient algorithm for model learning.Empirical studies have been conducted on two real-world data sets showing that SPPL outperforms related preference learning methods.     

高校科技查新工作存在的主要问题及对策分析

简要介绍了我国高校科技查新工作的现状,针对目前查新工作中存在的服务内容上缺乏完善的查新报告质量保障机制,服务手段上没有针对查新员建立科学有效的激励机制,服务对象上缺少针对中小企业用户的个性化服务机制等问题,提出了有效提升高校科技查新工作质量的对策。     

A study on the evaluation of cesium removal performance in soil washing process using flocculating agent

Journal of Radioanalytical and Nuclear Chemistry - As a result of nuclear power plant accidents such as Chernobyl and Fukushima, and even their maintenance, the soil is contaminated due to the...     

冷轧带钢板形翘曲变形过程及规律的解析

针对冷轧带钢生产现场常见的板形翘曲缺陷,应用辛弹性力学方法对因材料纵向延伸在厚度方向上出现不均匀而导致带钢翘曲变形的现象及过程进行了解析研究,通过建立和求解带钢翘曲变形力学模型,推导获得带钢翘曲度大小和不均匀纵向延伸的关系.在选择通用有限元软件验证了基于辛弹性力学方法的带钢翘曲变形力学模型及计算结果的正确性的基础上,计算得到了各个影响因素对翘曲变形的影响规律.计算结果表明,带钢翘曲度大小随着带钢上下表面纵向延伸差和横向与纵向延伸差比值的增大而线性地增大,随着带钢厚度增大而减小,随着带钢宽度增大而呈二次关系增大.最后,应用辛弹性力学方法带钢翘曲变形模型,研究了C翘向L翘的转化现象,建立了C翘转化为L翘的力学模型,获得其转化关系公式,并通过现场实验验证了转化公式的准确性.