金属有机导体、半导体和超导体

本文综述了三类金属有机固体化合物的合成、结构与导电性能。这三类化合物是金属有机电荷转移盐,金属酞菁和会属卟啉络合物,以及金属有机夹层化合物。     

Knoevenagel缩合反应研究的新进展

综述了近年来Knoevenagel缩合反应研究的新进展, 包括微波、超声波、固相合成、离子液体等新技术新试剂在该反应中的应用.     

基于自注意力机制的新生儿胆道闭锁识别

新生儿胆道闭锁是新生儿常见的致命疾病之一,并且该病在亚洲的发病率高于世界其他地区.新生儿胆道闭锁需要及时发现及时治疗,然而由于缺少专业的儿科医生和辅助诊疗手段,新生儿父母往往不能及时发现而错过了最佳治疗时间.因此,本文开发了一个具有实际应用价值的预诊算法,通过新生儿粪便图片预测新生儿是否患有新生儿胆道闭锁,并提醒新生儿父母及时就诊.为了让算法在应用场景下识别率更高,本文的算法基于一个真实场景下拍摄的新生儿粪图片数据集开发.首先我们设计了一个自注意力网络模型BANet(Biliary Atresia Network),将图片的浅层特征和深层特征相结合,可以得到更好的分类效果.由于拍摄自应用场景下的图片存在过暗和过曝等问题.通过分析数据集的亮度分布,我们设计了一个自动亮度调节算法解决.此外,图片中的阴影也会对识别结果造成干扰,因此我们在训练阶段增加了一种阴影数据增强方式来缓解这一问题.为验证本文提出算法的有效性,本文设计了一个和医生的对比试验.结果证明BANet在四分类的识别率、二分类的识别率、特异性和敏感性等客观评价指标上占有明显优势.本文提出的BANet能够有效利用图片中的颜色、异常点...     

一些稀疏图的强边染色（英文）

图G的强边染色是指对图G进行正常边染色使得任意长度为3的路的三条边染不同的颜色.图G的强边色数,记为χ’_s(G),是使得图G是强k边着色的最小正整数kk.2015年,Zang [arXiv:1510.00785]证明了:最大度△(G)=5的图G,χ’_s(G)≤37.本文证明了:最大度△(G)=5且最大平均度小于8/3(或者14/5)的图G,χ’_s(G)≤13 (或者14).另外,本文证明了:最大度△(G)≥3的不含K_2,3-图子式的图G,χ’_s(G)≤4△(G)-6,这个界是紧的.     

智能网联车辆节能自适应巡航控制研究

现有车辆自适应巡航控制多专注于单一的轨迹跟踪目标,而决定控制技术实际应用效益的关键是系统的节能性能.为了能够同时保证跟踪误差收敛性与燃油经济性,研究了一种车辆节能自适应巡航控制器设计方法：首先以轨迹跟踪为目标,设计了具有时变反馈增益的状态反馈控制律;其次,以反馈增益为优化变量,以整个预测时域内各采样时刻自身车辆单位位移燃油消耗量的累加为代价函数,基于经济模型预测控制方法设计了节能控制算法,并通过构建共同Lyapunov函数,给出了保证跟踪误差以指数速度收敛的反馈增益选取范围;最后,通过数值仿真验证了控制器设计的有效性,定量展示了本文所提出的方法在降低燃油消耗量方面的有效性.     

超声场"聚能效应"的研究--超声场对氢键缔合的负载固定相解吸平衡的影响

以NKA-Ⅱ树脂/TBP/50%乙醇和CL-TBP树脂/苯酚/水为实验对象,测定了超声场条件下树脂吸附物解吸过程的动力学曲线,讨论了超声功率密度和温度对平衡条件下解吸物浓度的影响.结果表明,随着温度的升高和超声功率密度的增大,平衡解吸物浓度呈上升趋势.超声场作用下的平衡解吸物浓度比无超声场同温度下的一般解吸过程的平衡解吸物浓度高.这反映了超声场"聚能效应"的强化作用.     

Distribution of δD in 25-cm Surface Snow Along Trans-Antarctic Route (Ⅱ)——The “1990 International Trans-Antarctic Expedition” Glaciological Research

On the way of the "1990 International Trans-Antarctic Expedition", the first author of this paper, the Chinese member of the expedition, collected 104 snow samples in 25-cm surface snow along a 5986-km route on Antarctic ice sheet from west to east. The geographical distribution of δD across the Antarctica by the longest route is obtained from stable isotope analysis for the first time. After discussing regional differences of physical geographic conditions, maritime-continental influence, altitudes and latitudes at sampling sites, the distribution of δD is considered to have a close relation to latitudes, but the topographic effect is prominent in some particular regions. The mean annual temperature at sampling site and its relationship with δD in surface snow covering Antarctica from west to east are discussed also. The δD-temperature gradient from the south end of Antarctic Peninsula to Vostok obtained in this paper is very close to that in Terre Adelie Land obtained by predecessors. The snow-dri     

Synthesis and In Vitro Antiviral Activities of Some New 2-Arylthiomethyl-4-tertiaryaminomethylsubstituted Derivatives of 6-Bromo-3-ethoxycarbonyl-5-hydroxyindoles

Some new derivatives of 3-ethoxycarbonyl-6-bromo-5-hydroxyindoles were designedand prepared, their antiviral activity were determined in cell culture with virus cytopathic effect assay. The results showed compound Ⅶ b, Ⅶ h exhibited potential antiviral activity.     

Dioxygen Affinities and Catalytic Oxidation Performance of Cobalt (II)Complexes with N-Aryl Hydroxamic Acid

It is well known that the study on biomimetic oxygen carriers not only has important theoretic significance to discover the mechanism of reversible bonding, activating oxygen as well as the oxidation reaction in organism, but also has potential application in separating oxygen from air and realizing the high efficiency and selectivity of catalytic oxidation reaction under a mild condition1. Metal- porphyrin and metal- phthalol- gaunine have been extensively used as biomimetic oxygen carriers u…     

脱色阴离子交换剂的再生研究

提出一种新的离子交换剂再生理论，即吸附物的脱附依靠离子交换和络合的协同效应完成．以二价钙离子为再生剂，对糖液脱色用的阴离子交换树脂和阴离子交换纤维进行再生，并与传统的碱性钠盐相比较，研究证明钙离子为再生剂的工艺，具有低成本、无污染的特点．