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81.
82.
The adsorption of asymmetrical triblock copolymers from a non-selective solvent on solid surface has been studied by using Scheutjens-Fleer mean-field theory and Monte Carlo simulation method on lattice model. The main aim of this paper is to provide detailed computer simulation data, taking A8-kB20Ak as a key example, to study the influence of the structure of copolymer on adsorption behavior and make a comparison between MC and SF results. The simulated results show that the size distribution of various configurations and density-profile are dependent on molecular structure and adsorption energy. The molecular structure will lead to diversity of adsorption behavior. This discrepancy between different structures would be enlarged for the surface coverage and adsorption amount with increasing of the adsorption energy. The surface coverage and the adsorption amount as well as the bound fraction will become larger as symmetry of the molecular structure becomes gradually worse. The adsorption layer becomes thicker with increasing of symmetry of the molecule when adsorption energy is smaller but it becomes thinner when adsorption energy is higher. It is shown that SF theory can reproduce the adsorption behavior of asymmetrical triblock copolymers. However, systematic discrepancy between the theory and simulation still exists.The approximations inherited in the mean-filed theory such as random mixing and the allowance of direct back folding may be responsible for those deviations. 相似文献
83.
非负矩阵与有向图的谱半径 总被引:2,自引:0,他引:2
本文给出非负矩阵的谱半径的上界、下界,由此给出有向图的谱半径的界. 相似文献
84.
85.
The equivalent geometrical configurations of linear ordered orthogonal arrays are determined when their strengths are 3 and 4. Existence of such geometrical configurations is investigated. They are also useful in the study of (T, M, S)-nets. 相似文献
86.
87.
88.
The distortion theorem for biholomorphic convex mappings in bounded symmetric domains are considered. Especially the distortion theorem for biholomorphic convex mappings in classical domain of type IV and two exceptional domains are given. 相似文献
89.
本文对梯形水平折梁(0≤α<∏2)和矩形水平折架(α=∏2)用最小余能原理进行了内力分析,并导出了相应的计算公式,可在工程结构设计中采用 相似文献
90.
A method for determining accurate relative molecular masses and elemental compositions of several non-volatile and thermally labile organic compounds in the source cell was established. The experimental sequence included laser desorption/electron impact Fourier transform mass spectrometry and direct-mode observation over a narrow mass range. Perfluorotributylamine was used as internal calibrant. Errors were about 1 ppm. 相似文献