超分子化合物{[8-hydroxyquinolineH]44+·[SiW12O40]4-·2H2O}的水热合成、晶体结构及热稳定性

A supermolecular compound, {[8-hydroxyquinolineH]₄⁴⁺·[SiW₁₂O₄₀]^4-·2H₂O} was synthesized by hydrothermal reaction with silico-tungstic acid and 8-hydroxyquinoline. The crystal of the compound belongs to monoclinic system, space group P2₁/n, with a=1.282 6(6) nm, b=2.292 7(4) nm, c=2.092 0(6) nm, β=95.495(2)°, Z=4, V=6.124 1(7) nm³, D_c=3.791 g·cm^-3, μ=22.568 mm^-1, F(000)=6 200, R₁=0.029 3, wR₂=0.069 3, GOF=1.079. Su-permolecular compound is composed of one SiW₁₂O₄₀^4- with Keggin structure, four protonated cations of 8-hydroxyquinoline, two hydrones. Thermal analysis results showed that the anionic skeleton construction of heteropoly acid in compound decomposed approximately at 349.0 ℃. CCDC: 622142.     

CO2 responsive wormlike micelles based on sodium oleate,potassium chloride and N,N-dimethylethanolamine

The anionic surfactant sodium oleate (NaOA) can self-assemble in aqueous solution in the presence of counter-ion inorganic salts to form wormlike micelles (WLMs), which exhibited viscoelastic behavior. In this paper, KCl was used to induce the formation of wormlike micelles with sodium oleate. In this process, we found that the addition of N, N-dimethylethanolamine (DMEA) can destroy the structure of WLMs leading significant decrease of viscosity. However, after introducing CO₂ into the ternary solution (KCl-NaOA-DMEA), the WLMs can be regenerated due to the electrostatic interaction between the protonated DMEA and the anionic surfactants. The addition of sodium hydroxide (NaOH) causes the electrostatic interaction between OA^- and DMEAH⁺ be destroyed, which results in the wormlike micelles becoming spherical micelles of lower viscosity. The transition of WLMs with high viscosity and low viscosity spherical micelles can be repeated several times by using CO₂ and NaOH.     

中国北方某河流水质现状调查及分析

为调查A河、B河下游水体的水质现状,于2014年丰水期（8月）和枯水期（12月）,选取A、B河下游各8个采样点,对水体的溶解氧、氨氮等6项理化指标,以及Hg、Pb等7项重金属指标进行检测,采用单项参数评价法和综合水质标识指数法对2条河流的水质现状进行分析及评价,并采用对数型幂函数普适指数公式对水体的富营养程度进行评价。结果发现,A、B河下游水质以劣V类为主,水体中各类重金属不超标,主要超标污染物为总氮、总磷、氨氮等。A河水质好于B河,2条河流丰水期水质好于枯水期。A、B河下游水体处于重富和极富营养化状态,应加强整治2条河流流域的农业面污染源,降低河流的富营养化风险。     

More Than 12 % Polarization and 20 Minute Lifetime of 15N in a Choline Derivative Utilizing Parahydrogen and a Rhodium Nanocatalyst in Water

Hyperpolarization techniques are key to extending the capabilities of MRI for the investigation of structural, functional and metabolic processes in vivo. Recent heterogeneous catalyst development has produced high polarization in water using parahydrogen with biologically relevant contrast agents. A heterogeneous ligand‐stabilized Rh catalyst is introduced that is capable of achieving ¹⁵N polarization of 12.2±2.7 % by hydrogenation of neurine into a choline derivative. This is the highest ¹⁵N polarization of any parahydrogen method in water to date. Notably, this was performed using a deuterated quaternary amine with an exceptionally long spin‐lattice relaxation time (T₁) of 21.0±0.4 min. These results open the door to the possibility of ¹⁵N in vivo imaging using nontoxic similar model systems because of the biocompatibility of the production media and the stability of the heterogeneous catalyst using parahydrogen‐induced polarization (PHIP) as the hyperpolarization method.     

耐盐碱刺槐离体再生快繁体系的建立与优化

为提高耐盐碱刺槐的快繁效率,满足沿海及滨海盐碱地区绿化要求,以耐盐碱刺槐无性系"W009"和"W038"为试材,研究不同条件对耐盐碱刺槐试管苗分化和生根的影响.结果表明:两刺槐茎尖初代接种不定芽萌发率均好于茎段,"W009"离体茎尖不定芽萌发的最适培养基为MS+6-BA 0.5 mg·L~(-1)+NAA 0.05mg·L~(-1),茎段不定芽萌发的最适培养基为MS+6-BA 1.0mg·L~(-1)+NAA 0.1mg·L~(-1);而适合"W038"离体茎尖和茎段不定芽萌发的最适培养基则为MS+6-BA 1.0mg·L~(-1)+NAA 0.1 mg·L~(-1);适合"W009"不定芽增殖的培养基为MS+6-BA 1.0mg·L~(-1)+NAA 0.05mg·L~(-1),"W038"不定芽增殖的培养基为MS+6-BA 2.0mg·L~(-1)+NAA 0.1 mg·L~(-1);"W009"最适生根培养基为:1/2 MS+0.1 mg·L~(-1) IBA+0.2mg·L~(-1) NAA+1.0g·L~(-1)活性炭;"W038"最适生根培养基为:1/2 MS+0.3 mg·L~(-1) IBA+0.2 mg·L~(-1) NAA+1.0g·L~(-1)活性炭.     

量子信息革命引领未来科技革命

作为全球瞩目的新兴战略技术焦点,量子信息技术已经在量子计算与量子通信等领域取得了突破性进展。从科学史的角度来看,量子信息革命与发生在20世纪的第1次量子革命在原理和内涵等方面存在着显著区别,对未来的科技发展战略也有着直接影响。梳理了量子纠缠与量子信息技术的演变历程,分析了量子信息技术在科学、技术、哲学等多个层面的革命性特征,总结了量子信息革命对未来科技战略及科学发展模式的意义与启示。     

CL256型MOS图象传感器的研制

CL256型MOS图象传感器是一种新型的固体图象传感器,国外又称为自扫描光电二极管列阵(Self Scanned Photodiode Array,简称SSPD器件)。该器件采用了硅栅P-MOS工艺,而作为扫描电路的移位寄存器是采用的一种带变容管自举电路的三管动态无比电路。这是一种高速度低功耗电路,对研制高位数的SSPD器件尤为重要。 文中叙述了CL256型MOS图象传感器的电路工作原理,工艺实验及实验结果。     

低温下聚合物的树枝状放电

针对低温电工绝缘的实际应用和低温电老化机理的探讨，通过针尖电极试验，着重研究了超高分子量聚乙烯的特性；并将它与交联聚乙烯、低密度聚乙烯做了对比。结果表明，机械应力下疲劳强度的劣化是低温电树枝化的重要因素。超高分子量聚乙烯具有低温性能好。不会开裂，适用于低温电工绝缘的特点。     

Synthesis and Crystal Structure of 7-Nitro-5-sulfo-napthalene-1,4-dicarboxylate Acid

1 INTRODUCTION Napthalene-1,4-dicarboxylate acid (1,4-NDC) has rigidity and stability because of the aryl ring and flexibility due to the carboxyl group, so it can be designed to assemble many novel microporous me- tal-organic coordinate polymer materials (MOCP) with transition metal[1～5]. In order to design and syn- thesize MOCP with specific framework structure for potential applications as functional materials, the ligand was decorated by bringing more substitutes to the aryl ring[…