Sorption and desorption of neptunium(V) on calcareous soil and its solid components: A comparative study

The sorption and desorption isotherms of untreated calcareous soil and three treated soils to remove CaCO₃, organic matter (OM) and both CaCO₃ and OM were determined and analyzed with the Freundlich equation at pH 7.8, moderate concentrations of NpO₂ ⁺ (~10^-5mol/l), in the presence of 0.01 mol/l CaCl₂ and under ambient aerobic conditions. The relative contribution of CaCO₃ and OM to the neptunium(V) sorption on calcareous soil and the sorption/desorption hysteresis is discussed. The effects of adding fulvic acid (FA) and carbonate in to the solution on the sorption of neptunium(V) on the soils were also studied. The sorption and desorption characteristics of NpO₂ ⁺, Zn²⁺, Sr²⁺ and Cs⁺ on the soils are compared.     

VIB金属蝎型配合物(Scorpionate)的研究进展

综述了VIB金属(Mo、W)多吡唑硼配合物近年来的研究进展。详细地叙述了第二代多吡唑硼配体的合成与表征。     

A Substituted Tetraazaporphyrinogen as an Electroactive Component for a Polymeric Membrane Anion-Selective Electrode

A novel anion-selective electrode has been prepared by usingtetraazaporphyrinogen as the electroactive component and o-nitrophenyloctylether as the plasticizer. The electrode exhibits almost Nernstian responsecharacteristics for Pic^-, ReO ₄ ^- ,SCN^-, ClO ₄ ^- and TPB^-. The linearresponse ranges towards the above-mentioned anions are 10^-6 10^-2, 10^-5 10^-2,10^-5 10^-2, 10^-5 10^-1, and 10^-5 10^-2mol/Land the corresponding slopes are -56.8, -57.1, -56.3, -56.1, and -59.9mV/decade with correlation coefficients of -0.99978, -0.99987, -0.99999,-0.99998, and -0.99998, respectively. The electrode shows an anti-Hofmeisterselectivity sequence: Pic^- > SCN^- >ReO ₄ ^- > ClO ₄ ^- > I^- >Br^- > BF ₄ ^- > Sal^->NO ₃ ^- > Cl^-. The unusual responsemechanism of the novel anion-selective electrode was investigated byexperimental observations and calculation with the MNDO method. Theelectrode was used as a TPB^- and a Pic^-sensitiveelectrode, respectively, and applied to the assay of levamisolehydrochloride tablets by potentiometric titration and Gran's methods. Theresults obtained are in excellent agreement with that determined by thestandard pharmacopoeia method based on nonaqueous titration.     

On an inhomogeneous deformation of a generalized Neo-Hookean material

We study the inhomogeneous deformation of a wedge of an incompressible generalized power-law Neo-Hookean material. We find solutions which have a boundary layer structure, in the sense that adjacent to the boundary the solution is inhomogeneous, while in the core region the solution is homogeneous. It is found that such solutions have an associated pressure field that is bounded. Inhomogeneous solutions are also possible when the pressure varies logarithmically with the radial coordinate. We also establish explicit exact solutions for specific values of the parameter. The results reduce to the Neo-Hookean solution when the power law exponent is set to unity.     

Synthesis, Structure and Conductivity of the New Charge-transfer Salt (ET)_2(CH_2=CH-CH_2-SO_3)·H_2O

ET is one of the most famous electron-donor molecules, which forms charge-transfer complexes (abbr. CT-complexes) with various types of counterions. These complexes have received intense attention because a wide range of physical properties such as conductivity and superconductivity1, ferromagnetism2-4 and nonlinear optical properties5 was found in these materials. Although the majority of the ET-based CT-complexes were prepared by combining with inorganic counterions, CT-complexes with o…     

片状化石燃料的循环流化床燃烧(Ⅰ)--片状颗粒的形貌描述和流态化阻力特征描述

比较了不同球形度概念对片状化石燃料的描述效果,研究了片状化石燃料球形度变化对其流态化特征的影响.分析了Krumbein球形度为0.1～0.4的京西无烟煤在一台50MW循环流化床锅炉上表现出来的特殊现象,如运行床温和炉膛压力大幅度波动、依靠排放冷渣保持稳定运行,揭示了这些现象发生的原因.     

BaO-CaO-CaF2系渣用于钢液深脱磷能力

使用BaO-CaO-CaF2系渣在实验室中进行钢水深脱磷实验以获得超低磷钢水.实验结果表明,初始磷约为0.01%的条件下,获得了50%以上的脱磷率及0.005%以下最低0.002%的磷含量;脱磷效果受钢水氧化性影响显著.实验测得1 813～1 893K范围内该渣系的磷容量在1018～1019.35之间,并且随BaO含量增加,磷容量增大.