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51.
Jacobi BG Laitar DS Pu L Wargocki MF DiPasquale AG Fortner KC Schuck SM Brown SN 《Inorganic chemistry》2002,41(18):4815-4823
Trimesityliridium(III) (mesityl = 2,4,6-trimethylphenyl) reacts with O(2) to form oxotrimesityliridium(V), (mes)(3)Ir=O, in a reaction that is cleanly second order in iridium. In contrast to initial reports by Wilkinson, there is no evidence for substantial accumulation of an intermediate in this reaction. The oxo complex (mes)(3)Ir=O oxidizes triphenylphosphine to triphenylphosphine oxide in a second-order reaction with DeltaH++ = 10.04 +/- 0.16 kcal/mol and DeltaS++ = -21.6 +/- 0.5 cal/(mol.K) in 1,2-dichloroethane. Triphenylarsine is also oxidized, though over an order of magnitude more slowly. Ir(mes)(3) binds PPh(3) reversibly (K(assoc) = 84 +/- 3 M(-1) in toluene at 20 degrees C) to form an unsymmetrical, sawhorse-shaped four-coordinate complex, whose temperature-dependent NMR spectra reveal a variety of dynamic processes. Oxygen atom transfer from (mes)(3)Ir=O and dioxygen activation by (mes)(3)Ir can be combined to allow catalytic aerobic oxidations of triphenylphosphine at room temperature and atmospheric pressure with overall activity (approximately 60 turnovers/h) comparable to the fastest reported catalysts. A kinetic model that uses the rates measured for dioxygen activation, atom transfer, and phosphine binding describes the observed catalytic behavior well. Oxotrimesityliridium does not react with sulfides, sulfoxides, alcohols, or alkenes, apparently for kinetic reasons. 相似文献
52.
53.
投料顺序对动态硫化PP/EPDM性能影响及其机理的研究 总被引:12,自引:0,他引:12
针对PP降解在PP/EPDM动态硫化中对体系产生的不利影响。考察了四种不同投料顺序对PP/EPDM动态硫化物的冲击韧性,加工流动性,交联程度和断面形貌等宏观和微观性能,并进行了不同EPDM含量的动态硫化和非硫化PP/EPDM的性能比较。结果表明,优化投料顺序能实现对动态硫化体系中化学反应对象和化学反应程度的有效干预。 相似文献
54.
Czechoslovak Mathematical Journal - Let L(n, d) denote the minimum possible number of leaves in a tree of order n and diameter d. Lesniak (1975) gave the lower bound B(n,d) = ⌈2(n −... 相似文献
55.
论非构造油气藏综合勘探方法 总被引:3,自引:1,他引:2
通过研究构造演化和生烃与油气运聚散的关系,总结成功的地震相和基准面旋回高分辨率层序地层学方法在寻找岩性地层油气藏中的应用,分析了各种特殊地震处理和油气检测方法的适用性和可靠性,提出了3个层次、5类方法的非构造油气藏勘探思路。3个层次及有关方法是:在盆地规模上进行整体、动态、综合研究,寻找有利油气聚集带;在有利油气聚集带规模上,开展高分辨率层序地震地层学研究,寻找各类有效尖灭体和圈闭;在可能的圈闭基础上,利用地震烃类检测和化探技术进行圈闭评价。3个层次5类方法的全面研究和有机结合是减小非构造油气藏勘探风险,提高勘探成功率的有效途径。 相似文献
56.
对甘薯的开花规律作了观察.结果表明,一个植株的花序有30-75个,开花顺序有先后.在一个植株上,花是从下而上开放的;在一个花序上,花由内向外开放,它的开花情况符合两种模式图.从每一个植株纵向开花来看,花是从下而上呈螺旋报开放. 相似文献
57.
Two problems for task schedules in a multiprocessor parallel system are discussed in this paper:
- Given a partially ordered set of tasks represented by the vertices of an acyclic directed graph with their corresponding processing times, derive the lower bound on the minimum time(LBMT) needed to process the task graph for a given number of processors.
- Determine the lower bound on minimum number of processors(LBMP) needed to complete those tasks in minimum time. It is shown that the proposed LBMT is sharper than previously known values and the computational aspects of these bounds are also discussed.
58.
59.
Highly dispersed α-Fe_2O_3/NaY,NiO/NaY,and CuO/NaY catalyst systems were pre-pared by impregnation method.Dispersion thresholds of the transition metal oxides on NaY" zeolitewere determined by XRD phase analysis.The dispersion capacities of the transition metal oxides on NaYzeolite are much lower than that estimated on the basis of a closed packed monolayer in the micropores.The catalytic activity and selectivity of the highly dispersed oxide catalyst systems for ethylben-zene and cyclohexane dehydrogenation reactions were reported. 相似文献
60.
The polymer bound Schiff‐base ligand (PS‐SalGlu) has been prepared from polystyrene bound salicylaldehyde and glutamic acid, and its complex (PS‐SalGlu‐Co) has also been synthesized. The polymer ligand and its complex were characterized by infrared spectroscopy, small area X‐ray photoelectron spectroscopy, and inductively coupled plasma‐atomic emission spectro (ICP‐AFS). In the presence of the complex, cyclohexene can be effectively oxidized by molecular oxygen without reductant. The long‐chain linear aliphatic olefins, such as 1‐octene, 1‐decene, 1‐dodecene and 1‐tetradecene, can be directly oxidized by molecular oxygen catalyzed by PS‐SalGlu‐Co, which affords the 1,2‐epoxy alkane. Copyright © 2001 John Wiley & Sons, Ltd. 相似文献