首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   33988篇
  免费   3650篇
  国内免费   4056篇
化学   14662篇
晶体学   285篇
力学   996篇
综合类   284篇
数学   2170篇
物理学   6903篇
综合类   16394篇
  2024年   97篇
  2023年   406篇
  2022年   805篇
  2021年   916篇
  2020年   919篇
  2019年   965篇
  2018年   759篇
  2017年   888篇
  2016年   1090篇
  2015年   1346篇
  2014年   1696篇
  2013年   2234篇
  2012年   2415篇
  2011年   2683篇
  2010年   2269篇
  2009年   2277篇
  2008年   2572篇
  2007年   2412篇
  2006年   2201篇
  2005年   1724篇
  2004年   1501篇
  2003年   1300篇
  2002年   1320篇
  2001年   1108篇
  2000年   923篇
  1999年   791篇
  1998年   548篇
  1997年   505篇
  1996年   485篇
  1995年   434篇
  1994年   386篇
  1993年   313篇
  1992年   273篇
  1991年   229篇
  1990年   192篇
  1989年   191篇
  1988年   145篇
  1987年   115篇
  1986年   75篇
  1985年   66篇
  1984年   26篇
  1983年   28篇
  1982年   13篇
  1981年   12篇
  1980年   7篇
  1977年   7篇
  1973年   3篇
  1970年   3篇
  1959年   4篇
  1957年   4篇
排序方式: 共有10000条查询结果,搜索用时 9 毫秒
31.
钱平 《科技信息》2008,(36):291-291
本文按照《大学英语课程教学要求》,简要分析了基于计算机和课堂的英语教学模式,提出了在这种模式下大学英语教师的角色定位,以更好的发挥学生的主体作用和教师的主导作用。  相似文献   
32.
μC/OS-Ⅱ is an open source real-time kernel adopting priority preemptive schedule strategy. Aiming at the problem of μC/OS-Ⅱ failing to support homology priority tasks scheduling, an approach for solution is proposed. The basic idea is adding round-robin scheduling strategy in its original scheduler in order to schedule homology priority tasks through time slice roundrobin. Implementation approach is given in detail. Firstly, the Task Control Block (TCB) is extended. And then, a new priority index table is created, in which each index pointer points to a set of homology priority tasks. Eventually, on the basis of reconstructing μC/OS-Ⅱ real-time kernel, task scheduling module is rewritten. Otherwise, schedulability of homology task supported by modified kernel had been analyzed, and deadline formula of created homology tasks is given. By theoretical analysis and experiment verification, the modified kernel can support homology priority tasks scheduling, meanwhile, it also remains preemptive property of original μC/OS-Ⅱ.  相似文献   
33.
A new family of photonucleases, naphthalimide-thiazoles was synthesized and evaluated. These compounds intercalated into DNA efficiently and damaged DNA photochemically at concentrations as low as 5 μM. Mechanistic experiment suggests that a novel naphthalimide-thiazole radical produced via an excited triple state might be involved in the DNA photodamage. Different activity may arise from the impact of substituents at 2-phenyl ring of thiazole on the electron population of excited triple state according to AM1 semi-empirical calculation.  相似文献   
34.
We have synthesized a blue‐light‐emitting polyfluorene (PF) derivative ( PF‐CBZ‐OXD ) that presents bulky hole‐transporting carbazole and electron‐transporting oxadiazole pendent groups functionalized at the C‐9 positions of alternating fluorene units. The results from photoluminescence and electrochemical measurements indicate that both the side chains and the PF main chain retain their own electronic characteristics in the copolymer. An electroluminescent device incorporating this polymer as the emitting layer was turned on at 4.5 V; it exhibited a stable blue emission with a maximum external quantum efficiency of 1.1%. Moreover, we doped PF‐CBZ‐OXD and its analogue PF‐TPA‐OXD with a red‐light‐emitting iridium phosphor for use as components of phosphorescent red‐light emitters to investigate the effect of the host's HOMO energy level on the degree of charge trapping and on the electrophosphorescent efficiency. We found that spectral overlap and individual energy level matching between the host and guest were both crucial features affecting the performance of the electroluminescence devices. Atomic force microscopy measurements indicated that the dipolar nature of PF‐CBZ‐OXD , in contrast to the general nonpolarity of polydialkylfluorenes, provided a stabilizing environment that allowed homogeneous dispersion of the polar iridium triplet dopant. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 2925–2937, 2007  相似文献   
35.
引入了Laffey自同构的概念,讨论了Laffey自同构的一些性质,所得结果推广了文献中关于交换自同构及中心自同构的相应结论.  相似文献   
36.
一种小波域音频信息隐藏方法   总被引:1,自引:0,他引:1  
提出了一种基于量化的小波域音频隐藏算法,将保密语音隐藏到载体音频中.为提高隐藏重和保密语音传输的安全性,对保密语音进行了小波域压缩编码和m序列的扩频调制,生成待隐藏的比特序列;通过量化方法,将编码和调制后的保密语音隐藏到载体音频的小波系数中;保密语音的恢复过程不需要使用原始音频、仿真结果表明,隐藏有保密语音的载体音频听觉质量没有明显下降,提取的保密语音感知质量较好;该算法对重量化、加噪、低通滤波等攻击均有良好的鲁棒性.  相似文献   
37.
We succeeded in developing the acyl chloride‐facilitated condensation polymerization method for the synthesis of new poly(anhydride‐ester)s with aromatic side groups, which cannot be polymerized by the classic melt condensation polymerization method. Using chlorinated and acylated carboxylic acids as the intermediates, the polymerization was carried out at low temperatures of 120 or 135 °C to yield pure poly(anhydride‐ester)s of molecular weights as high as 1.55 × 105 with minimal side‐reactions. A homogeneous route of preparation was developed and optimized, using butyric anhydride as the acylating reagent and oxalyl chloride as the chlorinating reagent. A comparison of the mechanisms of the classic method and the new method indicates that the effects of transacylation—cyclization and oligomer formation—were greatly reduced due to the high reactivity of carboxylic acid chloride and the steric effect of bulky acyl groups. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 5899–5915, 2007  相似文献   
38.
Glasses in SiO2–ZnO–BaO system with the different ZnO/BaO ratio were studied. In some cases, BaF2 was introduced to substitute for BaO on the equal base. Photoluminescent spectra showed that ZnO in glass matrices behaved somewhat differently from ZnO crystals. Especially, the introduction of fluorine ions led to dramatic shift of UV emission band of glasses closer to that of ZnO crystals. Raman spectral analysis provided consistent results. In particular, Raman bands in the high frequency region are sensitive to effects of different ZnO/BaO or BaF2/BaO ratio on structure of glasses.  相似文献   
39.
Structural hierarchy of rock masses and the mechanisms of its formation   总被引:1,自引:0,他引:1  
The formation mechanisms for the structural hierarchy in geological media are discussed. It is shown that the formation of such a hierarchy is caused by certain external and internal circumstances. The first ones consist in the fact that, because of external actions, the Earth’s poles continuously execute the translational and rotational motions responsible for a regular structure of rock fracture and for the appearance of the scale factor √2. The second ones consist in the fact that, under the action of many random factors and because of external actions, during the formation of geological media there appear dissipative structures and, hence, some self-similar fractal structures are formed.  相似文献   
40.
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号