The influence of hard‐segments on two‐phase structure and shape memory properties of PCL‐based segmented polyurethanes

Poly(ε‐caprolactone)‐based segmented polyurethanes (PCLUs) were prepared from poly(ε‐caprolactone) diol, diisocyanates (DI), and 1,4‐butanediol. The DIs used were 4,4′‐diphenylmethane diisocyanate (MDI), 2,4‐toluenediisocyanate (TDI), isophorone diisocyanate (IPDI), and hexamethylene diisocyanate (HDI). Differential scanning calorimetry, small‐angle X‐ray scattering, and dynamic mechanical analysis were employed to characterize the two‐phase structures of all PCLUs. It was found that HDI‐ and MDI‐based PCLUs had higher degree of microphase separation than did IPDI‐ and TDI‐based PCLUs, which was primarily due to the crystallization of HDI‐ and MDI‐based hard‐segments. As a result, the HDI‐based PCLU exhibited the highest recovery force up to 6 MPa and slowest stress relaxation with increasing temperature. Besides, it was found that the partial damage in hard‐segment domains during the sample deformation was responsible for the incomplete shape‐recovery of PCLUs after the first deformation, but the damage did not develop during the subsequent deformation. © 2007 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 45: 557–570, 2007     

南宋新喻籍高僧德光禅师生平

德光不仅是一位佛教思想家和实践家,同时又是一位教育家。他是历代新喻籍僧人中最出色的一位。他天姿聪颖,少壮出家,参悟佛法,观机逗教,为临济宗的发展做出了自己的贡献。他法嗣遍布海内,甚至远播东瀛。他名满当时,广结善缘,与皇帝文臣有着广泛的交往,并留下了一些佳话。     

浅谈幼儿基本体操对幼儿发育的促进作用

幼儿基本体操是以幼儿为对象,以增强体质为目的的大众健身体操。从幼儿基本体操的概念上、幼儿生理上、心理上、智力发展方面介绍和论述幼儿基本体操对幼儿发育的促进作用。     

学年学分制模式下的高校学生工作探索

我国目前大多数高校采用学年学分制,与学年制和完全学分制不同,它以学分为计量单位,按学年或学期作为结算时段确定学生的降级和退学标准,有相对固定的修业年限。文章对该模式下的学生工作进行初步探讨,提出了进一步完善辅导员制度、加强班集体建设等系列措施。     

等截面垂直管道中气粉流的临界管长

考虑重力和摩擦力的影响，建立了描述垂直管道中气粉流行为的数学模型，采用马赫数检验法，确定了产生摩擦壅塞时的临界管长，计算表明，当气粉流以不同方式喷入相同的冶金熔池时，底吹垂直管道比顶吹垂直管道需要更大的临界管长。     

油溶性银漂染料的合成及性能研究

合成并鉴定了黄色、品红色及青色共１１个油溶性偶氮染料，研究了染普在溶剂中的光谱性质和油溶性，结果表明，各染料色光纯正、有害吸收少，分子支链度大的染料Ｙ－２、Ｙ－６等具有良好的油溶性，可望用于银漂感光材料。     

一种基于一元插值的网格化方法

针对地质数据点的空间分布特点，提出了一种一元网格化方法，探讨了几种常用一元插值方法的应用，并与Ｎ－Ｐ法进行了对比，说明了一元网格化方法的特点．     

Erratum: Preparation of size‐controlled In2O3 nanoparticles

The article referenced above was first published online on 7 August 2007 with incorrect pagination; the pagination has now been corrected online and in print. Copyright © 2007 John Wiley & Sons, Ltd.     

基于B/S模式的网络考试系统的研究

主要介绍基于B/S模式的网络考试系统的设计原理和体系结构,并且根据研究的结果开发出了一个通用的考试系统工具.本文首先介绍了软件开发的基础,其次分析了该系统的功能,然后详细介绍了该系统中的主要模块的设计与实现.     

Synthesis of grafted poly(p‐phenyleneethynylene) with energy donor–acceptor architecture via atom transfer radical polymerization: Towards nonaggregating and hole‐facilitating light‐emitting material

In this contribution, we demonstrate a new effective methodology for constructing highly efficient and durable poly(p‐phenyleneethynylene) (PPE) containing emissive material with nonaggregating and hole‐facilitating properties through the introduction of hole‐transporting blocks into the PPE system as the grafting coils as well as building the energy donor–acceptor architecture between the grafting coils and the PPE backbone. Poly(2‐(carbazol‐9‐yl)ethyl methacrylate) (PCzEMA), herein, is chosen as the hole‐transporting blocks, and incorporated into the PPE system as the grafting coils via atom transfer radical polymerization. The chemical structure of the resultant copolymer, PPE‐g‐PCzEMA, was characterized by NMR and gel permeation chromatography, showing that the desirable copolymer was obtained with the narrow polydispersity. The increased thermal stability of PPE‐g‐PCzEMA was confirmed by thermogravimetric analysis and differential scanning calorimetry along with its macroinitiator. The optoelectronic properties of this copolymer were studied in detail by ultraviolet‐visible absorption, photoluminescence emission and excitation spectra, and cyclic voltammogram (CV). The results indicate that PPE‐g‐PCzEMA exhibits the solid‐state luminescent property dominated by individual lumophores, and also the energy transfer process from the PCzEMA blocks to the PPE backbone with a relatively higher energy transfer efficiency in the solid‐state compared to that of the solution state. Additionally, the hole‐injection property is greatly facilitated due to the presence of PCzEMA, as confirmed by CV profiles. All these data indicate that PPE‐g‐PCzEMA is a good candidate for use in optoelectronic devices. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 3776–3787, 2007