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31.
An essentially binormal operator on Hilbert space is an operator which is unitarily equivalent to a 2 × 2 matrix of essentially commuting, essentially normal operators. A natural invariant of essentially binormal operators up to unitary equivalence in the Calkin Algebra is the reducing essential 2 × 2 matricial spectrum. A nonempty compact subset X of the set of 2 × 2 matrices is called hypoconvex, if it is the reducing essential 2 × 2 matricial spectrum of an operator on Hilbert space. The set EN2(X) is then defined to be the set of all equivalence classes (up to unitary equivalence in the Calkin algebra) of essentially binormal operators whose reducing essential 2 × 2 matricial spectrum coincides with X. The aim of this paper is to prove a result that enables one to compute EN2(X) in terms of the topological structure of the space X? of unitary orbits of X. Indeed, it is shown that for every hypoconvex subset X of the set of 2 × 2 matrices, there exists a natural homomorphism from Ext(X?) onto EN2(X). Also, a six term cyclic exact sequence is obtained, which produces a characterization of the kernel of the above-mentioned homomorphism.  相似文献   
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A wide variety of complex oligosaccharides has now been made accessible as a result of methodological improvements in the sphere of chemical synthesis, which can be used for the study of conformations and interactions with protein-receptor molecules. Such work is of particular importance because the oligosaccharide chains of glycoproteins and glycolipids anchored to the plasma membrane are important in cell-cell interactions and are receptors for enzymes, hormones, proteins, and viruses; furthermore, they determine the antigen properties of cells. The methods of synthesis available for the production of selective linkages in oligosaccharides are dealt with, particular attention being paid to conversion of saccharides into oligosaccharides, which are important from the biological point of view.  相似文献   
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Zusammenfassung An sterisch fixierten N-Acylpiperidin-Derivaten wurde gezeigt, daß die magnetische Wirkung der Amidgruppe die Protonen von N-Alkylresten im wesentlichen nur bei cis-ständiger Carbonylgruppe beeinflußt, wobei Verschiebung der NMR-Signale zu niedrigerem und höherem Feld erfolgen kann. Ein allgemeines Modell gibt die Bereiche an. Äquatoriale Protonen der-Methylgruppen von N-Acetylpiperidinen befinden sich im Entschirmungsbereich, entsprechende axiale Protonen im Abschirmungsbereich. Bei frei rotierenden N-Methylgruppen durchlaufen die Protonen abwechselnd beide Bereiche. Die dabei erfolgende Mittelwertbildung zeigt, daß die Abschirmung überwiegt. Die Kenntnis der magnetischen Anisotropie ermöglicht eine Konformationsanalyse des N-Acetyl-2-methyl-piperidins, das eine Konformation mit axialer CH3-Gruppe bevorzugt. Für 2-Methyl-N-trifluoractyl-pyrrolidin sowie N-Isopropylisochinuclidon wurde eine Stellung der Methinprotonen in der Amidebene gefunden.
Summary It has been demonstrated that the magnetic effect of the amide group of sterically fixed N-acyl-piperidines affects essentially the protons of N-alkyl groups, provided the carbonyl group is in cis-position. The magnetic field acts shielding or deshielding. The corresponding regions are shown in a general model. Equatorial protons of-methylene groups in N-acyl-piperidines are in the deshielding region, corresponding axial protons are in the shielding region. The protons of freely rotating N-methyl groups pass in turn both regions. The resulting mean shows, that shielding predominates. The knowledge of the magnetic anisotropy enables the assignment of the conformation of N-acetyl-2-methyl-piperidine which prefers a conformation with an axial methyl group. In 2-methyl-N-trifluoracetyl-pyrrolidine and N-isopropyl-isoquinuclidone the methine protons are situated in the amide plane.
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We construct a counterexample to Solel's [B. Solel, Contractive projections onto bimodules of von Neumann algebras, J. London Math. Soc. 45 (2) (1992) 169–179] conjecture that the range of any contractive, idempotent, MASA bimodule map on is necessarily a ternary subalgebra. Our construction reduces this problem to an analogous problem about the ranges of idempotent maps that are equivariant with respect to a group action. Such maps are important to understand Hamana's theory [M. Hamana, Injective envelopes of C*-dynamical systems, Tohoku Math. J. 37 (1985) 463–487] of G-injective operator spaces and G-injective envelopes.  相似文献   
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HARUN REŞIT YAZAR 《Pramana》2013,81(4):579-585
The sd-interacting boson approximation (sd-IBA) and the df-interacting boson approximation (df-IBA) can be related to each other and the states of the interacting boson approximation model can be identified with the fully symmetric states in the sdf interacting boson approximation model. A systematic study of the sdf-IBA model showed that the constructed Hamiltonian can successfully describe the strong octupole correlations in the deformed nuclei. We showed that the interacting boson approximation may account for many of these K π ?=?0+ states. It was found that the calculated energy spectra of the gadolinium isotopes agree quite well with the experimental data. The observed B(E2) values were also calculated and compared with the experimental data.  相似文献   
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