A recording phase lag between ocean and continent climate changes: Constrained by the Matuyama/Brunhes polarity boundary

The Matuyama/Brunhes polarity boundary (MBPB) is recorded in Chinese loess L8, which is associated with the glacial period. It is proved that loess L8 is capable of recording earth’s secular variation, and the lock-in depth in Chinese loess is no more than that of marine sediments. Comparison with the location of MBPB in Chinese loess and marine sediments, it is put forward that there is a recording phase lag between ocean and continent climate changes.     

区域自然灾害系统基本单元研究(Ⅲ)──湖南省农业自然灾害灾情综合区划

在区域自然灾害系统基本单元概念体系的指导下,以灾害系统基本单元为最小空间单位,选取对湖南省农业生产影响较大的水灾、旱灾、低温冷害、风雹灾及病虫害5种自然灾害,以民政部1978～1993年农业灾情统计数据为标准,并以综合农业灾情强度（16年年平均状况）为指标,在地理信息系统支持下,“自下而上”逐级综合,提出了湖南省农业自然灾害灾情综合区划方案,将全省划分为东西分异的3个一级区及18个二级亚区．通过检验,分区方案合理,较前人在此方面的研究工作有较大的进展     

土堤下非均质粘土层的承载力分析

用滑移线法分析了土堤下软弱土层的极限荷载,并以设计图表的形式给出了分析结果和通过算例提出了加劲和非加劲土提极限高度的计算方法。     

神经网络在橡胶硫化温度预测中的应用

本文针对难以通过在线测温实现等效硫化控制的情况,在确定硫化条件的直接测温实验基础上,提出了用神经网络模型预测实际生产过程中硫化制品内部温度的方法．在该方法中将所测温度值作为样本提供给神经网络学习,温度采集时刻及易测外部温度作为网络输入,输出值则是在硫化时制品难测温点处不同时刻的内温．神经网络通过学习取得了良好的效果,网络输出的温度值将成为等效硫化计算和硫化质量智能控制的有价值的依据．     

用动力学方法研究8,9-苯并-2-亚甲基-1,4,6-三氧螺[4,4]壬烷的聚合反应机理

根据在自由基引发剂存在下,8,9-苯并-2-亚甲基-1,4,6-三氧螺(4,4)壬烷(Ⅰ)可能存在的竞争反应,推导了动力学方程式。用红外光谱法测定了单体的消失速率和苯酞的生成速率。实验结果与推导动力学方程式相符。进一步证明了单体(Ⅰ)的增长反应由加成聚合和开环—异构化—加成这两个反应组成。这两个反应对总速率的相对贡献与单体浓度有关。得到了共聚物的结构。     

Thermodynamic Studies of Bi-Univalent Electrolytes. VI. Thermodynamics of Cadmium Acetate from E. M. F. and Calorimetric Measurements

E. M. F. of the Cell, Cd-Hg (2-phase)/CdAc₂(m), Hg₂Ac₂(s)/Hg was measured at 20°, 25°, 30° and 40°C. The standard e. m. f. of the cell, Cd/CdAc₃(m), Hg₂Ac₂(c)/Hg was evaluated as E°=1.1500?11.09×10^?4T+1.06×10^?8T² The thermodynamic data of the reaction, Cd(c) + Hg₂Ac₂(c)=2Hg(l)+Cd⁺⁺(aq)+2Ac^?(aq) at 25°C were estimated as ΔF°=?42,139, ΔH°=?48,698 cal mole^?1 and ΔS°=?22.0 cal deg^?1 mole^?1 at 25°C. The thermodynamic data for the formation of Hg₂Ac₂(s) were evaluated as ΔF_f°=?202.3, ΔH_f°=?154.5 Kcal mole^?1 and S°=72.9 cal deg^?1 mole^?1. From measurements of the heats of solution of CdAc₂·2H₂O in aqueous solution, the relative partial molal enthalpies of cadmium acetate in aqueous solution were estimated.     

Palladium-catalyzed ring expansion reaction of 1-alkynylcyclobutanols with aryl iodides: an efficient route to 2-disubstituted methylenecyclopentanones

The reaction of 1-alkynylcyclobutanols with aryl iodides in the presence of Pd(OAc)₂ and Et₃N in acetonitrile at 80°C for 24 h gives 2-disubstituted methylenecyclopentan-1-ones in modest to good yields. The tandem insertion-ring expansion process proceeds via the formation of an alkynyl π-complex, followed by migration of a carbon-carbon bond of the tert-alkanol to form the cyclopentanones stereoselectively.