A thermally stable Pt/Y-based metal-organic framework: Exploring the accessibility of the metal centers with spectroscopic methods using H2O, CH3OH, and CH3CN as probes

A metal-organic framework (MOF) based on Pt, Y, and 2,2'-bipyridine-5,5'-dicarboxylate (BPDC), stable up to 400 degrees C, has been synthesized and characterized. In this MOF, the Pt centers are coordinated to Cl and the N atoms of the BPDC unit, giving a local environment similar to that found in a series of Pt-organic complexes with catalytic activity toward C-H bond cleavage of alkanes. This new material is a heterogeneous counterpart to the corresponding metal-organic complex. The structure, determined by single-crystal XRD data, is the repetition of three covalently bonded layers. These layers form a block, which is stacking as an (a)(b)(c) sequence along the crystallographic b-axis. Each layer contains the Pt-organic unit, while Y atoms represent the connection between adjacent layers. No covalent connection is present between layer (a) of a block and layer (c) of an adjacent block. EXAFS (BM29 at the ESRF) analysis supports the XRD data. As this MOF crystallizes under hydrothermal conditions, water acts both as solvent and as a direct ligand of Y. Accessibility to the metal centers is demonstrated by reversible water desorption/readsorption, as determined by TPA/TPD, FTIR, UV-vis, EXAFS, and XANES. Importantly, the results show that the as-synthesized material will not suffer a permanent loss in porosity upon solvent removal. In addition to water, methanol, ethanol, and acetonitrile can also access the internal void of the dehydrated phase.     

Hermitian generalization of the Rarita-Schwinger operators

We introduce two new linear differential operators which are invariant with respect to the unitary group SU（n）. They constitute analogues of the twistor and the Rarita-Schwinger operator in the orthogonal case. The natural setting for doing this is Hermitian Clifford Analysis. Such operators are constructed by twisting the two versions of the Hermitian Dirac operator 6z_ and 6z_ and then projecting on irreducible modules for the unitary group. We then study some properties of their spaces of nullsolutions and we find a formulation of the Hermitian Rarita-Schwinger operators in terms of Hermitian monogenic polynomials.     

Recognizing near-bipartite Pfaffian graphs in polynomial time

A matching covered graph is a non-trivial connected graph in which every edge is in some perfect matching. A non-bipartite matching covered graph G is near-bipartite if there are two edges e₁ and e₂ such that G−e₁−e₂ is bipartite and matching covered. In 2000, Fischer and Little characterized Pfaffian near-bipartite graphs in terms of forbidden subgraphs [I. Fischer, C.H.C. Little, A characterization of Pfaffian near bipartite graphs, J. Combin. Theory Ser. B 82 (2001) 175-222.]. However, their characterization does not imply a polynomial time algorithm to recognize near-bipartite Pfaffian graphs. In this article, we give such an algorithm.We define a more general class of matching covered graphs, which we call weakly near-bipartite graphs. This class includes the near-bipartite graphs. We give a polynomial algorithm for recognizing weakly near-bipartite Pfaffian graphs. We also show that Fischer and Little’s characterization of near-bipartite Pfaffian graphs extends to this wider class.     

EPR Studies of Electron Spin Polarization of Triplet Exciton and its Transfer into Triplet Traps of Naphthalene-TCNQ and Naphthalene-pChloranil Guest Complexes in the Naphthalene-TCNB Host

The EPR spectra of triplet excitons in single crystals of Naphthalene-TCNB (N-TCNB) charge-transfer (CT) complexes show optical electron spin polarization (OEP) which is accounted for by a spin selective populating process from the excited CT singlet into an excited triplet state localized on the acceptor. OEP is also observed for triplet traps in N-TCNB crystals doped with TCNQ and pChloranil. The analysis of the orientation dependence of spin polarization allows one to establish that also selective decay from the trap spin sublevels is important for the onset of the observed OEP features.     

Bulk hot-electron properties of cubic semiconductors

This paper contains a review of charge transport properties at high electric fields in bulk cubic semiconductors. The microscopic theoretical interpretation follows a semi-classical approach and is based on the knowledge of the band structure and scattering mechanism of the material under investigation. For the solution of the Boltzmann equation, the Monte-Carlo simulation technique is considered, which provides an ‘exact’ numerical solution limited only by the simplifying assumptions inherent in the physical model assumed. Experimental techniques for the measurements of the most important transport quantities are briefly surveyed. Comparison between theory and experiment is reported for both electron and hole transport properties in Si, Ge and GaAs. These substances, besides being the best known materials, can in fact be considered as models for any other cubic semiconductor.     

Multi-shot turbo spin-echo for 3D vascular space occupancy imaging

Vascular space occupancy (VASO) is a magnetic resonance imaging technique sensitive to cerebral blood volume, and is a potential alternative to the blood oxygenation level dependent (BOLD) sensitive technique as a basis for functional mapping of the neurovascular response to a task. Many implementations of VASO have made use of echo-planar imaging strategies that allow rapid acquisition, but risk introducing potentially confounding BOLD effects. Recently, multi-slice and 3D VASO techniques have been implemented to increase the imaging volume beyond the single slice of early reports. These techniques usually rely, however, on advanced scanner software or hardware not yet available in many centers. In the present study, we have implemented a short-echo time, multi-shot 3D Turbo Spin-Echo (TSE) VASO sequence that provided 8-slice coverage on a routine clinical scanner. The proposed VASO sequence was tested in assessing the response of the human motor cortex during a block design finger tapping task in 10 healthy subjects. Significant VASO responses, inversely correlated with the task, were found at both individual and group level. The location and extent of VASO responses were in close correspondence to those observed using a conventional BOLD acquisition in the same subjects. Although the spatial coverage and temporal resolution achieved were limited, robust and consistent VASO responses were observed. The use of a susceptibility insensitive volumetric TSE VASO sequence may have advantages in locations where conventional BOLD and echo-planar based VASO imaging is compromised.     

Focal nodular hyperplasia of the liver: diffusion and perfusion MRI characteristics

Purpose

To present diffusion and perfusion magnetic resonance imaging (MRI) characteristics of focal nodular hyperplasia (FNH) of the liver.

Materials and Methods

Thirty-five patients with 52 FNHs (21 were pathologically-confirmed) underwent MRI at 1.5-T device. MR diffusion [diffusion-weighted imaging (DWI)] was performed using a free-breathing single-shot, spin-echo, echo-planar sequence with b gradient factor value of 500 s/mm². MR perfusion [perfusion-weighted imaging (PWI)] consisted of a 3D free-breathing LAVA sequence repeated up to 5 minutes after injection of 7 mL Gd-BOPTA (MultiHance, Bracco, Italy) and 20 mL saline flush at a flow rate of 4 mL/s. Apparent diffusion coefficient (ADC) and time-signal intensity curve (TSIC) were obtained for both normal liver and each FNH by two reviewers in conference; maximum enhancement (ME) percentage, time to peak enhancement (TTP), and maximal slope (MS) were also calculated.

Results

On DWI mean ADC value was 1.624×10^− 3 mm²/s for normal liver and 1.629×10^− 3 mm²/s for FNH. ADC value for each FNH and the normal liver was not statistically different (P= .936). On PWI, TSIC-Type 1 (quick and marked enhancement and quick decay followed by slowly decaying) was observed in all 52 FNHs, and TSIC-Type 2 (fast enhancement followed by slowly decaying plateau) in all normal livers. The mean ME, TTP and MS values were significantly different for FNH and normal liver (P= .005).

Conclusion

FNHs of the liver showed typical diffusion and perfusion MRI characteristics in all cases. On the ADC map, we could get similar value between the FNHs and the background parenchyma. On the perfusion imaging, FNHs showed a different pattern distinguished from the background liver.