Novel,Complex Flavonoids from Mallotus philippensis (Kamala Tree)

One new flavanone, 4′‐hydroxyisorottlerin ( 2 ), and two new chalcone derivatives, kamalachalcones C ( 3 ) and D ( 4 ), were isolated from Mallotus philippensis (kamala tree). The largest compound ( 4 ; M_r 1098 g/mol) was shown to possess a unique, fused‐ring system made of two hydroxy‐chalcone units, giving rise to eight fused benzene/pyran units. From the same plant, the following six known compounds were also isolated: kamalachalcone A ( 5 ) and B ( 6 ), isoallorottlerin ( 7 ), isorottlerin ( 8 ), 5,7‐dihydroxy‐8‐methyl‐6‐prenylflavanone ( 9 ); 6,6‐dimethylpyrano(2″,3″: 7,6)‐5‐hydroxy‐8‐methylflavanone ( 10 ), and rottlerin ( 1 ). The structures of the new compounds were confirmed by in‐depth spectral analyses, including 2D‐NMR techniques, and the full ¹³C‐NMR assignments of the known flavanones 1 and 7 – 10 are published for the first time.     

CO2‐Induced Spin‐State Switching at Room Temperature in a Monomeric Cobalt(II) Complex with the Porous Nature

CO₂‐responsive spin‐state conversion between high‐spin (HS) and low‐spin (LS) states at room temperature was achieved in a monomeric cobalt(II) complex. A neutral cobalt(II) complex, [Co^II(COO‐terpy)₂]?4 H₂O ( 1?4 H₂O ), stably formed cavities generated via π–π stacking motifs and hydrogen bond networks, resulting in the accommodation of four water molecules. Crystalline 1?4 H₂O transformed to solvent‐free 1 without loss of porosity by heating to 420 K. Compound 1 exhibited a selective CO₂ adsorption via a gate‐open type of the structural modification. Furthermore, the HS/LS transition temperature (T_1/2) was able to be tuned by the CO₂ pressure over a wide temperature range. Unlike 1 exhibits the HS state at 290 K, the CO₂‐accomodated form 1?CO₂ (P =110 kPa) was stabilized in the LS state at 290 K, probably caused by a chemical pressure effect by CO₂ accommodation, which provides reversible spin‐state conversion by introducing/evacuating CO₂ gas into/from 1 .     

Inter-lamellar interactions modulated by addition of guest components

We have investigated the effects of a guest component (polymer or spherical colloidal particle) confined between flexible lamellar slits on the inter-lamellar interaction by means of a small-angle X-ray scattering technique and a neutron spin echo technique. The dominant interaction between flexible lamellar membranes without guest components is the Helfrich mechanism. The addition of a neutral polymer into the lamellar phase induces an attractive inter-lamellar interaction and finally destabilizes the lamellar phase. On the other hand, spherical colloidal particles confined between flexible lamellar membranes reduce the undulational fluctuations of lamellae and bring a repulsive inter-lamellar interaction. The behavior of the layer compression modulus of the lamellar membrane containing colloidal particles is well described by the entropical repulsive inter-lamellar interaction driven by steric hindrance.Received: 26 March 2004, Published online: 4 May 2004PACS: 82.70.Uv Surfactants, micellar solutions, vesicles, lamellae, amphiphilic systems, (hydrophilic and hydrophobic interactions) - 61.25.Hq Macromolecular and polymer solutions; polymer melts; swelling - 83.80.Hj Suspensions, dispersions, pastes, slurries, colloids - 89.75.Fb Structures and organization in complex systems     

Measurement of the branching ratio and form factor of K(L)-->mu(+)mu(-)gamma

We report on the analysis of the rare decay K(L)-->mu(+)mu(-)gamma the 1997 data from the KTeV experiment at Fermilab. A total of 9327 candidate events are observed with 2.4% background, representing a factor of 40 increase in statistics over the current world sample. We find that B(K(L)-->mu(+)mu(-)gamma) = (3.62 +/- 0.04(stat) +/- 0.08(syst)) x 10(-7). The form factor parameter alpha(K*) is measured to be alpha(K*) = -0.160(+0.026)(-0.028). In addition, we make the first measurement of the parameter alpha from the D'Ambrosio-Isidori-Portolés form factor, finding alpha = -1.54 +/- 0.10. In that model, this alpha measurement limits the Cabibbo-Kobayashi-Maskawa parameter rho>-0.2.     

Vinylpolymerisation. 311. Mitt. Synthese und Polymerisation von 2-Bromäthoxyphenoxyphosphorylmethacrylat

Ohne Zusammenfassung     

Measurement of the branching ratio and asymmetry of the decay Xi degrees -->Sigma degrees gamma

We have studied the rare weak radiative hyperon decay Xi degrees -->Sigma degrees gamma in the KTeV experiment at Fermilab. We have identified 4045 signal events over a background of 804 events. The dominant Xi degrees -->Lambdapi degrees decay, which was used for normalization, is the only important background source. An analysis of the acceptance of both modes yields a branching ratio of B(Xi degrees -->Sigma degrees gamma)/B(Xi degrees -->Lambdapi degrees ) = (3.34+/-0.05+/-0.09)x10(-3). By analyzing the final state decay distributions, we have also determined that the Sigma degrees emission asymmetry parameter for this decay is alpha(XiSigma) = -0.63+/-0.09.     

Microexplosion of an emulsion droplet during Leidenfrost burning

An experimental study has been made of the microexplosion of an emulsion droplet on a hot surface during Leidenfrost burning. Photographic observation is used to study how the emulsion droplet behaves and what happens inside the droplet and to measure the waiting time for the onset of microexplosion. Weibull analysis was used to obtain the distribution function of the waiting time for the onset of microexplosion and to derive the formula for the rate of microexplosion as a function of water volume and emulsion temperature. The base fuels employed were n-decane, n-dodecane, n-tetradecane, and n-hexadecane. The results show that the increase in emulsion temperature with lapse of time results in the agglomeration and coalescence of microdroplets of base fuel dispersed in the continuous phase of water inside the emulsion droplet, terminated by the complete separation of the two phases. At the end of the phase separation process, an opaque water droplet is formed in the central core and is enveloped by the transparent shell of base fuel. Preferential evaporation of the base fuel occurs after the phase separation. The volume of the base fuel decreases while the water volume remains constant. The onset of the microexplosion of an emulsion droplet burning on the hot surface is classified by the wearout type of the Weibull distribution. The waiting time for the onset of the microexplosion decreases with increases in the normal boiling point of base fuel, initial water content, ambient pressure, and test surface temperature. The rate of microexplosion increases with the lapse of time and with increased normal boiling point of the base fuel. The rate of microexplosion increases linearly with increasing water volume in the emulsion droplet and decreases exponentially with the inverse of emulsion temperature.     

Autoignition and early flame behavior of a spherical cluster of 49 monodispersed droplets

Autoignition and early flame behavior of a spherical cluster of 49 monodispersed droplets in a high-temperature air were examined in microgravity. The monodispersed suspended-droplet cluster (MSDC) model with which both droplet spacing and initial droplet diameter were well-controlled was developed, and the solidified-fuel fiber-suspension technique was utilized for making the MSDC model. The tested 3D MSDC models had the HCP (hexagonal closest packing) structure. Individual flames, which enveloped each droplet, or group flame, which enveloped the whole droplet cluster, were formed immediately after ignition. The flame changed from the group flame to a cluster of the individual flames either with increasing the droplet spacing or decreasing the initial droplet diameter. Each of the individual flames merged into the group flame with the lapse of time. Burning sphere diameter decreased at the beginning, and then increased. The transition from the individual flames to the group flame occurred around the time period at which the burning sphere diameter reached its minimum. The time period at which the burning sphere diameter reached its maximum was delayed and the expansion rate of the burning sphere was enhanced with decreasing the droplet spacing or with increasing the initial droplet diameter.