Hyperbranched block copolymer from AB2 macromonomer: Synthesis and its reaction‐induced microphase separation in epoxy thermosets

In this contribution, we reported the synthesis of a hyperbranched block copolymer composed of poly(ε‐caprolactone) (PCL) and polystyrene (PS) subchains. Toward this end, we first synthesized an α‐alkynyl‐ and ω,ω′‐diazido‐terminated PCL‐b‐(PS)₂ macromonomer via the combination of ring‐opening polymerization and atom transfer radical polymerization. By the use of this AB₂ macromonomer, the hyperbranched block copolymer (h‐[PCL‐b‐(PS)₂]) was synthesized via a copper‐catalyzed Huisgen 1,3‐dipolar cycloaddition (i.e., click reaction) polymerization. The hyperbranched block copolymer was characterized by means of ¹H nuclear magnetic resonance spectroscopy and gel permeation chromatography. Both differential scanning calorimetry and atomic force microscopy showed that the hyperbranched block copolymer was microphase‐separated in bulk. While this hyperbranched block copolymer was incorporated into epoxy, the nanostructured thermosets were successfully obtained; the formation of the nanophases in epoxy followed reaction‐induced microphase separation mechanism as evidenced by atomic force microscopy, small angle X‐ray scattering, and dynamic mechanical thermal analysis. © 2015 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2016 , 54, 368–380     

Gold‐Catalyzed Fluorination–Hydration: Synthesis of α‐Fluorobenzofuranones from 2‐Alkynylphenol Derivatives

The Au^I‐catalyzed fluorination–hydration of 2‐alkynylphenol derivatives in the presence of Selectfluor [1‐chloromethyl‐4‐fluoro‐1,4‐diazoniabicyclo‐[2.2.2]octane bis(tetrafluoroborate)] has been developed. This method provides straightforward access to α‐fluorobenzofuranones with the construction of C?O, C=O, and C?F bonds in a single step on the basis of an Au^I/Au^III redox catalytic cycle. Several control experiments, including the asymmetric variant of this reaction, were also conducted to gain insight into the reaction mechanism.     

The roles of cysteines in the heme domain of human soluble guanylate cyclase

Soluble guanylate cyclase(sGC) is a critical heme-containing enzyme involved in NO signaling.The dimerization of sGC subunits is necessary for its bioactivity and its mechanism is a striking and an indistinct issue.The roles of heme domain cysteines of the sGC on the dimerization and heme binding were investigated herein.The site-directed mutations of three conserved cysteines(C78A,C122A and C174S) were studied systematically and the three mutants were characterized by gel filtration analysis,UV-vis spectroscopy and heme transfer examination.Cys78 was involved in heme binding but not referred to the dimerization,while Cys174 was demonstrated to be involved in the homodimerization.These results provide new insights into the cysteine-related dimerization regulation of sGC.     

旅游规划制图研究

文章阐述了旅游规划制图的理论基础,梳理了旅游规划制图的详细内容,突破对单个软件的独立应用进行介绍和对多个软件进行并列介绍的传统研究模式,按照旅游规划制图的流程体系提出了旅游规划制图组合使用多种软件的方法,并选取AutoCAD、3dsMax和Photoshop的软件组合,设计了旅游规划制图完整、详细的流程.     

基于AutoCAD的静力学图解方法

以空间汇交力系和桁架为研究对象,根据力的矢量性质,结合工程制图的基本视图原理,在AutoCAD中以平移变换为基本操作,提出了静力学图解计算方法.研究表明,所提方法能直观、方便地求解静力学问题,且在满足精度要求的同时提高了解题效率,实现了计算机辅助设计在静力学问题求解方面的实际应用.     

基于规范文本的特征词提取技术研究

文本特征词提取是一种提炼文本重要信息的实用技术,同时也为文本聚类、自动分类、信息抽取等相关课题提供了技术支持。在规范文本上,利用文本篇章结构的特征,以此为基础设计了一个特征词的加权函数,综合考虑了词频、词长和位置因子,并对比分析了各种位置因子对系统的贡献度。     

高压微雾在蒸发冷却空调机组中的应用

为了得到填料-高压微雾对组合式空调机组的降温效果,测试1台55 000m3/h风量的填料-高压微雾组合式空调机组.采用对比方法,将5种不同的测试的降温效果进行对比.实验数据表明,高压微雾和填料上采用三维布水相结合对空调机组的降温最为显著.从研究结果上看,高压微雾不仅是人们传统认识上的加湿器,还是一台良好的冷却器,能够对空气进行降温,满足一些场所降温的需要,具有广泛的应用范围.     

LTI系统时域分析初始条件应用研究

在LTI系统时域分析中,为确定响应中的待定系数,我们会使用一组初始条件,正确地确定和使用初始条件是系统分析的关键,本文对初始条件的确定及应用进行了研究和探讨。     

发达地区老年人舞蹈锻炼对身心健康的研究与分析

对昆山市区的老年人舞蹈锻炼情况及他们的身心健康状况进行调查,从而了解并分析日常生活方式、社会经济因素、观念意识等对发达地区老年人身心健康的影响.方法:主要通过问卷调查法和调查询问法,采集有关老年人身心健康和舞蹈锻炼的信息,进行统计.结果表明:舞蹈锻炼对老年人身心健康具有明显的促进作用,并且地区的发达程度决定着老年人的体育观念和意识.