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51.
IntroductionRecently ,thecompoundscontaining 1H 1,2 ,4 tria zolegrouphaveattractedmuchinterestbecausetheyex hibitsomefungicidalactivity ,plantgrowthregulatingac tivity ,1antibacterialactivityagainstPucciniareconditeandrootsgrowthregulationforcucumber .2 Also ,suchcom poundsareincreasinglybeingstudiedbecauseofthecoor dinationchemistryoftriazolesactingasligandsintransi tionmetalcompounds .Asamatteroffact ,thetriazolederivativeshavebeenextensivelyusedasterminalandbridgingligands ,andtheyleadto… 相似文献
52.
AnOscillationConditionforanElectrode-separatedPiezoelectricSensorinNon-electrolyteLiquidSHENDa-zhong,HUANGMing-shan,LINSong,N... 相似文献
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HanMingDING LiPingWANG YongKuiSHAN MingYuanHE 《中国化学快报》2003,14(8):852-855
Deposition of inorganic-organic nano-hybrid ultrathin films onto mesoporous silicate materials has been proven possible by using layer-by-layer assembly method. In combination with sol-gel method, titania, subsequently dye molecules (or polymer) were successfully fabricated onto the inner wall of SBA-15. Their structures were preliminarily characterized by FTIR and solid-state UV-Vis spectroscopy, thermal analysis, and BET surface area measurements,respectively. 相似文献
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Li J Hong X Li D Zhao K Wang L Wang H Du Z Li J Bai Y Li T 《Chemical communications (Cambridge, England)》2004,(15):1740-1741
Highly luminescent water-soluble CdTe nanorods were prepared with the assistance of the mixed ligand system of cysteine and thioglycolic acid; the aspect ratio and photoluminescence of the CdTe nanorods could be controlled by the refluxing time. 相似文献
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Several novel N′-[(1-ferrocenylethylidene)amino]-N′-β-D-glycopyranosylthioureas have been efficiently synthesized via a six-step procedure, utilizing three monosaccharides (D-glucose, D-galactose and D-xylose) as starting materials, respectively. They have been preliminarily determined to display biological activity against certain fungi. The target compounds have been unambiguously characterized by spectroscopic method and elemental analysis. An initially alternative synthetic route, which was seemingly reasonable, has been excluded due to its inefficiency. 相似文献
58.
Developing low-cost but efficient hydrogen evolution reaction(HER)electrocatalysts over whole pH values is a significant but daunting task for the large-scale application of electrochemical hydrogen production.Herein,we develop,for the first time,a scalable MOF-assisted strategy for the fabrication and microstructural optimization of multi-shelled hollow N-doped carbon nanosheet arrays with confined Co/CoP heterostructures on carbon cloth(Co/CoP@NC/CC)for boosting HER performances.The key to this strategy is the step-by-step epitaxial growth of unprecedented multilayer ZIF-L arrays on carbon cloth,which are subsequently pyrolyzed and controllably phosphorized to achieve the precise control over the shell number and nanoarchitectures of the Co/CoP@NC/CC.Impressively,the HER performances can be significantly enhanced by increasing hollow shell number,and the optimal triple-shelled hollow Co/CoP@NC/CC exhibits low overpotentials of 86,78 and 145 mV in acidic,alkaline and neutral media to deliver a current density of 10 mA cm-2,respectively,ranking as one of the best Co-based HER electrocatalysts over whole pH values.Further DFT calculations suggest that the Co/CoP heterostructures can effectively boost the cleavage of H–OH to generate protons and optimize the adsorption energy of hydrogen(ΔGH*),which,together with the large electrode/electrolyte interface and accelerated charge/mass transfer of multi-shelled hollow array structure as well as the good conductivity and dispersity,are responsible for the remarkably improved HER performances.This study not only provides a new toolbox for enriching the family of multi-shelled nanoarchitecture materials,but also points out a general and effective route to develop highly efficient self-supported electrode materials for energy-related applications and beyond. 相似文献
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New Criteria for Polynomial Stability 总被引:3,自引:0,他引:3
New criteria for real-polynomial stability, developed during19571978, are introduced. The real polynomial an is called stable if every one of its roots hasnegative real part. We define determining coefficients
for the positive-coefficient polynomial f(x). Thestability of f(x) is completely determined by the n 2 determining coefficients. Several simple necessary or sufficientconditions for a stable polynomial are presented in terms ofinequalities involving the determining coefficients. For example,a necessary condition is
, and a sufficientcondition is
. 相似文献