Confinement and passivation of perovskite quantum dots in porous natural palygorskite toward an efficient and ultrastable light-harvesting system in water

Perovskite quantum dots (QDs) are promising as representative candidates to construct next-generation superior artificial light-harvesting systems (ALHSs). However, their high sensitivity to external environments, especially to water, imposes a stringent limitation for their actual implementation. Herein, by interface engineering and encapsulation with natural palygorskite (PAL), a water-resistant light-harvesting CsPbBr₃@PAL antenna was prepared. Molecular dynamics simulations further confirm a significant shielding protection of the PAL matrix to CsPbBr₃, facilitating exceptional stability of the CsPbBr₃@PAL antenna when exposed to air for 10 months, to 150 °C thermal stress, and even to water for more than 30 days, respectively. Furthermore, as a result of in situ encapsulation of the PAL matrix and defect passivation caused by H-bonding and coordination-bonding interaction, the CsPbBr₃@PAL antenna in water shows a substantially enhanced photoluminescence quantum yield (36.2%) and longer lifetime. After sequentially assembling Eosin Y and Rose Bengal in the pores of the PAL matrix, RB-ESY-CsPbBr₃@PAL with a sequential two-step efficient Förster resonance energy transfer process exhibited extremely enhanced photocatalytic activity toward Friedel–Crafts alkylation reactions in aqueous solution, 2.5-fold higher than that of corresponding ESY/RB. Our work provides a feasible strategy for the exploitation of ultra-stable halide perovskite-based ALHSs in aqueous media for solar-energy conversion.

A water-resistant light-harvesting antenna was prepared via encapsulating and in situ passivating perovskite quantum dots in PAL matrix. The ESY-RB-CsPbBr₃@PAL system with high sequential FRET exhibited enhanced photocatalysis in aqueous solution.     

芪3在铅-锡-氟磷酸盐玻璃中的聚集及光谱特性

采用低温熔融法制备了有机染料芪3掺杂的不同浓度的铅-锡-氟磷酸盐玻璃,通过对掺杂玻璃激发光谱、发射光谱和吸收光谱的测试,研究了芪3在无机玻璃中的聚集状态和光谱性能。 结果表明,有机染料芪3以单体和二聚物的形式共存于无机玻璃中,和芪3单体分子的激发峰相比,二聚物的激发峰位于短波段,随掺杂浓度的增加,掺杂玻璃的发射峰发生红移,同时在荧光光谱中观察到浓度猝灭现象;芪3分子与无机玻璃通过亲水作用发生了键合,从而导致芪3在无机玻璃中的吸收光谱和发射光谱比在乙醇溶液中出现较大红移;与芪3在乙醇溶液中的荧光强度相比,芪3分子受无机玻璃的“笼”化作用有效的提高了其荧光强度。     

重力梯度力矩近似公式适用条件的探讨

教材中重力梯度力矩经典近似公式是基于常规尺寸空间结构推导的,如果直接应用于超大尺寸结构可能会导致精度不够、甚至错误的结果.以超大空间哑铃结构为研究对象,对比了基于重力梯度力矩非近似公式与经典近似公式得到的姿态动力学响应,指出了经典近似公式的局限性.通过提高重力梯度力矩中近似项的保留精度,提出了修正公式,并验证了该公式的适用性.所得结论是对重力梯度力矩教学内容的有益扩展,对工程应用也有帮助.     

聚龙一号装置上首次铝套筒Z箍缩X射线背光照相实验

在聚龙一号脉冲功率装置上首次完成了对带正弦扰动铝套筒Z箍缩的X射线背光照相实验。实验采用千焦耳激光器（1053 nm, 1 kJ, 1 ns）驱动固体靶材产生X射线, 然后利用基于球面晶体的单色背光照相技术以及直接点投影背光照相技术, 成功观测到约7.5 MA电流驱动条件下, Z箍缩铝套筒的外边界不稳定性发展情况。该实验验证了在聚龙一号装置上联合千焦耳激光器开展X射线背光照相实验的能力, 为后续精密Z箍缩物理研究奠定了基础。     

中国散裂中子源直线射频功率源系统的研制

中国散裂中子源加速器质子束流加速能量为1.6 GeV,重复频率为25 Hz,撞击固体金属靶产生散射中子,一期工程的打靶束流功率为100 kW。直线加速器的设计束流流强为15 mA,输出能量为81 MeV。射频加速和聚束系统包括一台射频四极场加速器、中能束流传输线的两个聚束器、四节漂移管直线加速器加速腔和直线-环束流传输线的一个散束器,与之相对应,共有8个单元在线运行的射频功率源为其提供所需的射频功率。目前,直线射频功率源系统预研项目已全部完成,各项性能参数均已达到设计指标,当前正处在批产安装调试阶段。151013     

高功率微波介质窗表面矩形槽抑制二次电子倍增

为深入研究高功率微波(HPM)作用下介质窗沿面击穿破坏的物理机制,探索提高闪络场强阈值的方法和途径,开展了介质窗表面矩形刻槽抑制电子倍增的理论与试验研究。首先根据动力学方程建立了介质窗表面电子倍增模型并分析了介质窗槽内电子运动轨迹,考虑了矩形槽结构对表面微波电场的影响,理论分析表明在闪络击穿的起始和发展阶段矩形槽可有效抑制电子倍增。在S波段(2.86 GHz,脉宽1 s)下开展了介质窗表面矩形刻槽的击穿破坏试验,试验结果发现表面矩形刻槽可大幅度提高微波传输功率,在槽深(1.0 mm)一定时不同的刻槽宽度(0.5 mm和1.0 mm)对应的微波功率抑制范围不同。采用PIC-MC仿真模拟槽内倍增电子的时空演化,仿真结果很好地验证了试验现象。     

基于Simulink大功率电子管放大器仿真

选用4616V4型四极电子管,单管输出350 kW,采用两路并行放大链路,设计了一套输出功率350 kW2的大功率电子管功率源系统。基于四极电子管的恒流特性曲线及实验数据,拟合输出功率与阳极电压、输入功率的关系曲线,利用Origin软件拟合函数,建立数学模型,并利用闭环比例-积分(PI)反馈控制,稳定输出电压,通过Simulink仿真探寻最佳工作点,较低的阳极电压以及近饱和的输入功率既能有效增大工作频率,又能满足高功率输出的要求,仿真结果与实际联机调试数据对比,误差低于5%,根据仿真数据得到的结论与13点分析法一致,可以有效指导探寻最佳工作点。     

Investigation Driven by Network Pharmacology on Potential Components and Mechanism of DGS,a Natural Vasoprotective Combination,for the Phytotherapy of Coronary Artery Disease

Phytotherapy offers obvious advantages in the intervention of Coronary Artery Disease (CAD), but it is difficult to clarify the working mechanisms of the medicinal materials it uses. DGS is a natural vasoprotective combination that was screened out in our previous research, yet its potential components and mechanisms are unknown. Therefore, in this study, HPLC-MS and network pharmacology were employed to identify the active components and key signaling pathways of DGS. Transgenic zebrafish and HUVECs cell assays were used to evaluate the effectiveness of DGS. A total of 37 potentially active compounds were identified that interacted with 112 potential targets of CAD. Furthermore, PI3K-Akt, MAPK, relaxin, VEGF, and other signal pathways were determined to be the most promising DGS-mediated pathways. NO kit, ELISA, and Western blot results showed that DGS significantly promoted NO and VEGFA secretion via the upregulation of VEGFR2 expression and the phosphorylation of Akt, Erk1/2, and eNOS to cause angiogenesis and vasodilation. The result of dynamics molecular docking indicated that Salvianolic acid C may be a key active component of DGS in the treatment of CAD. In conclusion, this study has shed light on the network molecular mechanism of DGS for the intervention of CAD using a network pharmacology-driven strategy for the first time to aid in the intervention of CAD.     

求解反应扩散问题的Wavelet-Galerkin方法

提出了一种求解反应扩散问题的小波有限元方法。一般的反应扩散问题都存在着快反应慢扩散的特点,通过渐近分析知道这类问题一般都存在着各种各样的边界层。为了克服由此带来的计算上的困难,结合小波函数的特性,提出了一种自适应的小波有限元算法,不仅可以得到高精度的近似解,与通常的有限元或有限差分方法相比也大大降低了计算复杂度,可以从O(-ε2)降为O1εln1的两个数值例子表明,该方法对于几乎静止和运动的内边界层情形都是非常有效的。