微波消解-ICP-AES 法测定彝药野巴子中元素质量比

采用微波消解电感耦合等离子发射光谱法（IC P‐A ES ）,对攀枝花、昆明两地的野巴子所含铜、铁、锰、锌、铝、镉、铅、钛和砷等元素质量比进行测定．检出限为0.0029～0.079 m g／L ,相对标准偏差均低于2％,回收率为96.00％～109.09％．结果表明不同地区的野巴子含有丰富的元素,其中铁和铝的质量比最高,锰、锌和钛质量比中等,铜、镉和铅质量比最低,但不同地区野巴子的元素质量比是不同的,这可能与生长环境有关系．     

基于GCRN的矿岩可爆性分级模型及其应用

为了准确反映岩体可爆性等级,构建了由弹性波阻抗、坚固性系数、平均裂隙距和标准爆破漏斗炸药单耗4个因素组成的评价体系,采用改进的灰色关联分析法对传统的岩体可爆性等级划分标准进行优化。利用灰色关联相对贴近度(GCRN)来反映各可爆性等级之间的差别,确定各可爆性等级对应的灰色关联相对贴近度区间,以此划分新的岩体可爆性等级。采用基于GCRN的矿岩可爆性分级模型对武钢资源集团公司程潮矿业有限公司东、西区矿体的可爆性级别进行评价,评价结果与实际情况基本一致,表明利用灰色关联相对贴近度来划分矿岩可爆性等级的方法是可行的。     

基于Bayesian方法的参数估计和异常值检测

异常值检测是当前数据分析研究中的一个重要研究领域。模型中的异常值会直接影响建模、参数的估计、预测等问题。基于模型的异常值检测,传统的做法是先对模型参数进行估计,再进行异常值检测。而异常值的存在会影响参数估计,从而导致下一步异常值检测的不可靠;反之异常值检测也会影响参数估计。针对这些不足之处,提出了基于 Bayesian 方法的参数估计和异常值检测,此方法可以将参数估计和异常值检测同时实现,具体做法是在线性回归模型中引入识别变量,基于 Gibbs 抽样算法,给出识别变量后验概率的计算方法,通过比较这些识别变量的后验概率进行异常值定位,同时给出参数的估算方法。通过大量的模拟实验,结果表明,与传统方法相比,提出的方法对异常值更灵敏。     

Study of tin amalgam mirrors by 119Sn Mössbauer spectroscopy and other analytical methods

From the beginning of the 16 ^th until the end of the 19 ^th century the most widely used mirrors consisted of a pane of glass backed with a reflecting layer of tin-mercury amalgam. They were made by sliding the glass pane over a tin foil covered with liquid mercury. After removal of the superfluous mercury, tin amalgam formed slowly at ambient temperature and yielded a reflecting layer adhering to the surface of the glass. Such mirrors often deteriorate in the course of time by oxidation of the tin in the amalgam to stannous or stannic oxide. ¹¹⁹Sn Mössbauer spectroscopy, scanning electron microscopy, micro-XRF and X-ray diffraction have been used to study this deterioration process. The studied specimens were a modern mirror made for the reconstruction of the Green Vault in Dresden in the early 2000s, two rather well preserved German mirrors from the 17 ^th and 19 ^th centuries and several strongly deteriorated specimens of Baroque mirrors from the south of Spain. The modern mirror consists mainly of a Sn_0.9Hg_0.1 amalgam with only 2 % of SnO₂. The older German mirrors showed more pronounced oxidation, containing 12 and 15 % of SnO₂, which did not noticeably impair their reflectivity. In the samples from the Spanish mirrors at best a few percent of metallic phase was left. The majority of the tin had oxidised to SnO₂, but between 8 and 20 % of the tin was present as SnO. X-ray diffraction yielded similar results and micro-XRF mapping using synchrotron radiation for excitation gave information on the distribution of Sn and Hg in the reflecting layer of the mirrors.     

图的k部划分的一个注记

设k≥2是一个整数。本文证明了任意有m条边的图都存在一个顶点的划分V_1,V_2…,V_k,使得e(V_1,V_2…,V_k)≥k-1/k m+k-1/2k((2m+1/4)~1/2-1/2)-(k-2)~2/8k,且max{e(V_i):1≤i≤k}≤m/k~2+(k-1)/2k~2((2m+1/4)~1/2-1/2+3/8-7k-4/8k~2.我们的结果改进了[Fan G.,Hou J.,Zeng Q.,A bound for judicious k-partitions of graphs,Discrete Appl.Math.,2014,179:86—99]的主要结论.     

Structure of Pro4H+ investigated by infrared photodissociation（IRPD） spectroscopy and theoretical calculations

Combining with electrospray ionization(ESI)mass spectrometry,infrared photodissociation(IRPD)spectroscopy is a powerful method to study structures of cluster ions in the gas phase.In this paper,infrared photodissociation spectrum of Pro_4H~+in the range of 2700–3600 cm 1was obtained experimentally.Both theoretically predicted spectra of the two most stable isomers of Pro4~(-1) and Pro4~(-2) obtained at the level of M062X/6-31+G(d,p)are in good consistent with the experimental results.The two isomers have similar structures and close energies.Both of them only consist of zwitterionic units,indicating the strong salt-bridged interactions inside the clusters.And the calculated collision cross section(ccs)of Pro4-1 is found to be very close to the experimental result previously reported.     

求解广义鞍点问题的一个新的类SOR算法

本文提出了求解广义鞍点问题的一个新的类SOR迭代算法,并分析了新算法的收敛性.数值实验结果表明新算法是十分有效的.     

Electrochemical Oxidation of Astaxanthin on Glassy‐carbon Electrode and its Amperometric Determination Using Batch Injection Analysis (BIA)

This work presents the electrochemical oxidation of the antioxidant astaxanthin on a glassy‐carbon electrode (GCE) and its amperometric determination in salmon samples using a batch‐injection analysis (BIA) system. The proposed BIA method consisted of 80‐µL a fast microliter injection of sample at 193 µL s^?1 on the GCE immersed in the electrolyte, a mixture of acetone, dichloromethane, and water (80 : 10 : 10 v/v), containing 0.1 mol L^?1 HClO₄. Advantages include high precision (RSD of 2.4 %), sample throughput of 240 h^?1, and low detection limit (0.3 µmol L^?1 that corresponds to 0.1 µg g^?1) for the analysis of acetone extracts of salmon samples. Recovery values between 83 and 97 % attested the accuracy of the method.     

Lack of exponential stability to Timoshenko system with viscoelastic Kelvin–Voigt type

We study the Timoshenko systems with a viscoelastic dissipative mechanism of Kelvin–Voigt type. We prove that the model is analytical if and only if the viscoelastic damping is present in both the shear stress and the bending moment. Otherwise, the corresponding semigroup is not exponentially stable no matter the choice of the coefficients. This result is different to all others related to Timoshenko model with partial dissipation, which establish that the system is exponentially stable if and only if the wave speeds are equal. Finally, we show that the solution decays polynomially to zero as \({t^{-1/2}}\) , no matter where the viscoelastic mechanism is effective and that the rate is optimal whenever the initial data are taken on the domain of the infinitesimal operator.     

Organocatalytic Enantioselective Synthesis of Pyrazoles Bearing a Quaternary Stereocenter

An efficient one‐pot asymmetric synthesis of pyrazoles bearing a chiral quaternary stereocenter has been developed. Quinine‐derived thiourea catalyzed the enantioselective addition of pyrazolones to isatin‐derived ketimines, providing the corresponding acetylated pyrazoles after in situ treatment with Ac₂O/Et₃N. The corresponding pyrazoles were afforded in high yields and excellent enantioselectivities.