全文获取类型
收费全文 | 2911篇 |
免费 | 435篇 |
国内免费 | 275篇 |
专业分类
化学 | 1406篇 |
晶体学 | 21篇 |
力学 | 104篇 |
综合类 | 8篇 |
数学 | 286篇 |
物理学 | 760篇 |
综合类 | 1036篇 |
出版年
2024年 | 8篇 |
2023年 | 56篇 |
2022年 | 61篇 |
2021年 | 59篇 |
2020年 | 76篇 |
2019年 | 68篇 |
2018年 | 74篇 |
2017年 | 67篇 |
2016年 | 93篇 |
2015年 | 90篇 |
2014年 | 125篇 |
2013年 | 163篇 |
2012年 | 190篇 |
2011年 | 217篇 |
2010年 | 140篇 |
2009年 | 166篇 |
2008年 | 201篇 |
2007年 | 173篇 |
2006年 | 176篇 |
2005年 | 147篇 |
2004年 | 118篇 |
2003年 | 97篇 |
2002年 | 90篇 |
2001年 | 101篇 |
2000年 | 67篇 |
1999年 | 92篇 |
1998年 | 70篇 |
1997年 | 84篇 |
1996年 | 85篇 |
1995年 | 67篇 |
1994年 | 43篇 |
1993年 | 50篇 |
1992年 | 55篇 |
1991年 | 49篇 |
1990年 | 37篇 |
1989年 | 19篇 |
1988年 | 26篇 |
1987年 | 20篇 |
1986年 | 14篇 |
1985年 | 12篇 |
1984年 | 9篇 |
1983年 | 6篇 |
1982年 | 10篇 |
1981年 | 5篇 |
1980年 | 4篇 |
1979年 | 5篇 |
1978年 | 3篇 |
1976年 | 4篇 |
1974年 | 3篇 |
1973年 | 5篇 |
排序方式: 共有3621条查询结果,搜索用时 835 毫秒
81.
Hong‐Ze Gao Zhong‐Min Su Chun‐Sheng Qin Ri‐Gen Mo Yu‐He Kan 《International journal of quantum chemistry》2004,97(6):992-1001
Bis(2‐methyl‐8‐quinolinolato)aluminum(III) hydroxide complex (AlMq2OH) is used in organic light‐emitting diodes (OLEDs) as an electron transport material and emitting layer. By means of ab initio Hartree–Fock (HF) and density functional theory (DFT) B3LYP methods, the structure of AlMq2OH was optimized. The frontier molecular orbital characteristics and energy levels of AlMq2OH have been analyzed systematically to study the electronic transition mechanism in AlMq2OH. For comparison and calibration, bis(8‐quinolinolato)aluminum(III) hydroxide complex (Alq2OH) has also been examined with these methods using the same basis sets. The lowest singlet excited state (S1) of AlMq2OH has been studied by the singles configuration interaction (CIS) method and time‐dependent DFT (TD‐DFT) using a hybrid functional, B3‐LYP, and the 6‐31G* basis set. The lowest singlet electronic transition (S0 → S1) of AlMq2OH is π → π* electronic transitions and primarily localized on the different quinolate ligands. The emission of AlMq2OH is due to the electron transitions from a phenoxide donor to a pyridyl acceptor from another quinolate ligand including C → C and O → N transference. Two possible electron transfer pathways are presented, one by carbon, oxygen, and nitrogen atoms and the other via metal cation Al3+. The comparison between the CIS‐optimized excited‐state structure with the HF ground‐state structure indicates that the geometric shift is mainly confined to the one quinolate and these changes can be easily understood in terms of the nodal patterns of the highest occupied and lowest unoccupied molecular orbitals. On the basis of the CIS‐optimized structure of the excited state, TD‐B3‐LYP calculations predict an emission wavelength of 499.78 nm. An absorption wavelength at 380.79 nm on the optimized structure of B3LYP/6‐31G* was predicted. They are comparable to AlMq2OH 485 and 390 nm observed experimentally for photoluminescence and UV‐vis absorption spectra of AlMq2OH solid thin film on quartz, respectively. Lending theoretical corroboration to recent experimental observations and supposition, the reasons for the blue‐shift of AlMq2OH were revealed. © 2003 Wiley Periodicals, Inc. Int J Quantum Chem, 2004 相似文献
82.
A method for direct de termination of total in organic arsenic (III+V), arsenic (III) and dimethylarsinate (DMA) in sea water was developed by combining continuous‐flow selective hydride generation and inductively coupled plasma mass spectrometry (ICP‐MS) is presented. The principle underlying selective hydride generation is based on proper control of the reaction conditions for achieving separation of the respective arsenic species. The effects of pH and composition of reaction media on mutual interference between the arsenic species were investigated in detail. The results indicate that the appropriate media for the selective determination of total in organic arsenic, DMA and As(III) are 6 M HNO3, acetate buffer at pH = 4.63 and citrate buffer at pH = 6.54, respectively. The concentrations of total inorganic arsenic species, As(III+V), and As(III) were respectively deter mined and that of As(V) was obtained by the difference between them. As to the concentration of DMA, it was obtained after correction from the interference caused by As(III) and As(V). By following the established procedure, the detection lim its (as based on 3‐sigma criterion) for As(III+V), As(III) and DMA were 0.050, 0.009, and 0.002 ng/mL, respectively. There liability of the pro posed method was evaluated in terms of precision and spike addition. The results indicated that the precision of better than 3% and spike recovery of 95 to 105% for all the arsenic species tested in the natural sea water samples can be obtained. 相似文献
83.
用循环伏安法和电位阶跃法研究了LiCl-KCl-NaCl熔盐体系中碳的阴极还原机理。在钨、铂、不锈钢等微电极上得到的伏安图表明碳的还原是由CO_3~(2-)离子经一步电化学反应实现的,电极反应速度控制步骤为CO_3~(2-)离子向阴极的扩散过程,还原过程具有反应物吸附特征。碳在W、Pt、不锈钢电极上析出电位分别为-2.05V、-1.745V和-1.90V(均相对于Ag/AgCl参比电极)。 相似文献
84.
本文提出平行催化体系的对位叠式循环方波伏安法,并对共作了系统的研究,推导了这一方法的催化电流理论方程,并用验验证这理论的正确性,得到其各脉冲电流皆为同方向,对位叠式循环催化电流相当于将电流叠加4次,而波形不受方波幅度大小的影响,因而灵敏度和分辨率有较大提高,优于其它方波伏安法。 相似文献
85.
近年来亚硝酸甲酯分子(CHa0NO)的光解动力学研究十分活跃{‘5],主要集中在紫外激光的单光子解离的机理,光解过程的矢量相关性质和光解产物的态分布.CH30NO分子的解离能D。(CH30-NO)=174kJ·mol‘,若单从能量上看,人<689。的光就能使其解离,但人>400urn的光解离研究还未见报导.*H30*0分子在人>40onm的强激光场下是充电离还是先解离,是单光子解离还是多光子解离,以及通过哪个电子态解离都不清楚.时间飞行质谱不仅具有质量分辨率高、范围宽,而且响应快,因此适合做光解光电离过程初生态产物的探测.特别是时间飞… 相似文献
86.
Cα-Tetrasubstituted α-amino acids are ubiquitous and unique structural units in bioactive natural products and pharmaceutical compounds. The asymmetric synthesis of these molecules has attracted a lot of attention, but a more efficient method is still greatly desired. Here we describe the first sequential four-step acylation reaction for the efficient synthesis of chiral Cα-tetrasubstituted α-amino acid derivatives from simple N-acylated amino acids via an auto-tandem catalysis using a single nucleophilic catalyst. The synthetic efficiency is improved via a direct enantioselective C-acylation; the methodology affords the corresponding Cα-tetrasubstituted α-amino acid derivatives with excellent enantioselectivities (up to 99% ee). This step-economic, one-pot, and auto-tandem strategy provides facile access to important chiral building blocks, such as peptides, serines, and oxazolines, which are often used in medicinal and synthetic chemistry.The first four-step sequential reaction for the synthesis of Cα-tetrasubstituted chiral α-amino acid derivatives via auto-tandem catalysis has been developed. 相似文献
87.
J. Říkovská A. Machová W. D. Hamilton J. Dupák Chan Chen Mo M. Finger N. A. Lebedev B. S. Neganov V. N. Pavlov A. F. Shchus 《Czechoslovak Journal of Physics》1979,29(6):620-639
The anisotropy of the angular distribution of gamma-rays from the decay of156Tb, oriented in a gadolinium matrix at low temperatures, has been measured at the angles of 0 and π/2 with respect to the applied magnetic field direction in the range of temperatures from 14·6 to 68·4 mK. The temperature dependence of anisotropy was measured for the first time. The parameters of hyperfine magnetic dipole and electric quadrupole splittings have been determined and the values of the magnetic dipole moment ¦Μ156¦=(9·6±1·3)×10?27 J/T and the electric quadrupole momentQ 156=(2·9±0·9)×10?28 m2 of the156Tb ground state have been calculated. Multipole mixing ratios andB(E2) branching ratios of many gamma-ray transitions occurring in156Gd have been found and the results have been discussed in terms of the rotational-vibration and pairing-plus-quadrupole models. 相似文献
88.
莫勇波 《玉林师范学院学报》2005,26(2):1-7
村民自治在实践中取得了较好政治绩效,出现了较高的村民选举参与率,初步建立了以村民为决策主体的民主决策体制,同时出现了多元民主管理主体和多样化的民主管理和民主监督方式。另一方面村民自治实践中仍存在一些问题,影响了村民自治政治绩效的提高。要提升村民自治的政治绩效,必须要加强制度建设,要利用多种渠道,提高村民自治主体的民主、法制意识和文化素质。要加强村民自治组织的建设,提升其管理能力和服务能力。同时要求村民自治营造良好的社会法制环境。本文以广东省为例,对村民自治的政治绩效进行了分析,并提出了作者自己的见解。 相似文献
89.
为了满足数据传输的高速度,低功耗的要求,开发出来了利用低电压差分信号传输技术(简称LVDS)设计混合信号系统,可以确保铜导线能够满足高速数据传输.分析了LVDS驱动器的电路结构,在此基础上提出了具体设计,同时给出了用SPECTRES工具进行模拟验证的结果。 相似文献
90.
U形渡槽水体大幅晃动的ALE有限元模拟 总被引:3,自引:1,他引:3
应用任意拉格朗日-欧拉有限元方法分析大型u形渡槽结构中流体的大幅晃动问题;针对不同的水位,研究渡槽结构在谐波激励和地震作用下的振动反应.数值分析表明,渡槽结构中水体的晃动具有明显的非线性特征,且随着水位的增高,水体晃动的非线性增强;同时存在某一水位使得水体的晃动幅度产生突变增大. 相似文献