液相色谱-四极杆-静电轨道阱高分辨质谱法测定保健食品中11种磷酸二酯酶抑制剂

保健食品样品用50%(体积分数)甲醇溶液超声提取15 min,提取液用水定容至50.0mL,离心,取上清液,经0.22μm微孔滤膜过滤,采用液相色谱-四极杆-静电轨道阱高分辨质谱法测定滤液中11种磷酸二酯酶抑制剂的含量。以Waters HSS T3色谱柱为固定相,以不同体积比的0.1%(体积分数)甲酸溶液和乙腈的混合液为流动相进行梯度洗脱,质谱分析中采用电喷雾离子源正离子模式和全扫描模式。11种磷酸二酯酶抑制剂的质量浓度均在2~100μg·L^-1内与其对应的峰面积呈线性关系,测定下限(10S/N)为0.02~0.5μg·L^-1。以空白样品为基体进行加标回收试验,所得回收率为75.7%~98.9%,测定值的相对标准偏差(n=6)为5.9%~14%。     

不同部位灵芝及子实体提取物中总三萜酸含量测定

建立不同部位灵芝及子实体提取物中总三萜酸含量测定方法.灵芝样品用乙醇提取,依次经氯仿、5%碳酸氢钠萃取,酸化后再用氯仿萃取、浓缩至干,称重,即得灵芝总三萜酸量.结果:灵芝子实体总三萜酸为(8.58±0.25)mg/g,孢子粉为(3.48±0.03)mg/g,菌丝体仅为(1.75±0.09)mg/g;菌盖总三萜酸含量为(12.62±0.22)mg/g,菌柄为(7.66±0.08)mg/g.10批次灵芝子实体的总三萜酸含量范围为4.3416.39 mg/g.灵芝子实体提取物中的总三萜酸含量以醇-水提取物的最高为(208.70±5.54)mg/g;碱水提取物的最低,仅为(123.07±4.99)mg/g.HPLC初步分析子实体和孢子及子实体提取物间三萜酸成分大部分相同.本法适用于灵芝子实体及其提取物、灵芝孢子和菌丝体总三萜酸的含量测定,结果可靠,可为灵芝产品质量指标提供依据.     

1Cr18Ni9Ti不锈钢薄板等离子电弧加热弯曲成形的温度场

为获得等离子电弧加热工艺参数和薄板几何尺寸对薄板温度场分布的影响规律,应用有限元方法对1Cr18Ni9Ti不锈钢薄板等离子电弧加热弯曲成形的三维瞬态温度场进行了数值模拟,分析了等离子电弧功率、扫描速度、薄板厚度以及冷却条件等对等离子电弧成形温度场的影响特性.结果表明:1Cr18Ni9Ti不锈钢薄板的弯曲角度随着等离子电弧功率的增加而增加,最佳扫描速度下薄板厚度方向温度梯度达到最大.改变温度梯度可以达到控制变形的目的.     

太赫兹波在雾中的多重散射特性

太赫兹(THz)波作为微波和毫米波的延伸,它所提供的通信带宽和容量远大于毫米波。在随机介质中传播时,不但会发生时域和空域的形变,介质中的粒子还会对入射波发生散射,这些都会使得脉冲信号发生衰减。根据Mie理论与随机离散分布粒子的波传播与散射理论,计算了THz波信号入射下雾滴粒子的消光系数。结合雾滴粒子谱分布,得到了雾媒质的平均体系散射特性,采用蒙特卡罗法得到了平流雾对THz信号的多重散射特性,计算了THz波段信号对平流雾的透过率与反射率,分析了THz波段信号的前向、后向散射特性随散射角的分布。结果表明,低能见度大气环境中,雾对THz波产生的吸收和衰减不容忽视。相关研究结果对THz在大气传输、通信等方面的应用具有重要意义。     

Decreasing trend of temperature in Princess Elizabeth Land, Antarctica in the past 150 years

A 50-m firn core drilled in Princess Elizabeth Land, Antarctica, during the 1996/1997 Chinese First Antarctic Inland Expedition, has been measured for d 18O and major ions. Based on the high quality of the seasonal variations of major ions, the firn core was dated with errors within ±3 years. The features of the temperature change in the past 150 years in the investigated region have first been studied based on the oxygen isotope in the upper 32.93 m of the firn core. Results show that the temperature decreased nearly by 2℃ in Princess Elizabeth Land in the past 150 years. On the background of the global, especially the Southern Hemispheric warming in the past 150 years, a temperature decline of 2℃ in Princess Elizabeth Land likely reflects the impacts of the unique Southern Hemisphere atmospheric circulation, the Antarctic Circumpolar Wave (ACW) and the special terrain (such as the large drainage basins) on the coastal regions of Antarctica.     

一类连续函数模拟退火算法及其收敛性分析

高维连续函数的全局优化问题普遍存在于计算生物学、计算化学等领域．针对这类问题和现有连续函数模拟退火算法的某些不足,本文给出了一类改进的模拟退火算法．采用一种简单的方法证明了算法的全局收敛性．数值结果表明,对于高维连续函数,该算法能够快速有效地收敛到全局最优点,比较了两种新解产生方法的试验结果。     

An efficient and green process for the synthesis of 5-methyl-2-nitrobenzoic acid

Research on Chemical Intermediates - A new and environmental friendly nitration process of methyl 3-methylbenzoate by mixtures of HNO3/Ac2O for the synthesis of 5-methyl-2-nitrobenzoic acid has...     

Equilibrium conditions for CO2 hydrate in porous medium

Experimental phase equilibrium conditions data for carbon dioxide (CO₂) hydrate in porous medium with the presence of sodium chloride (NaCl) solution were investigated in this study. The experimental data were generated using graphic-method in presence of solutions contained (0, 0.2, 0.4, 0.6, and 0.8) mol/L NaCl. The results indicated the increase of NaCl concentration caused the enhancement in the equilibrium pressure of CO₂ hydrate as the pore size and the temperature were kept the same. Effects of NaCl solutions on CO₂ hydrate equilibrium conditions could be neglected when the temperature is lower than ice point. An improved model was used to predict CO₂ hydrate equilibrium conditions, and the predictions showed good agreement with experimental measurements.     

共焦扫描显微成象系统的点扩散函数再商讨

针对共焦扫描显微成象中物体相对于被扫描点的位置矢量是反向移动的特性,探讨了物体移动后的物函数在此基础上,根据成象的理论进行了计算,得到新的系统点扩散函数表达式,最后根据计算结果分析成象的性质,得出了系统成象的相干性.