新型手性近晶C相液晶共聚酯的设计与合成

以对苯二甲酰氯 ,2 ,5 二 [4 ((s) 2 甲基丁氧基 )苯甲酰氧基 ]对苯二酚和乙二醇、一缩乙二醇、二缩三乙二醇、三缩四乙二醇和聚乙二醇为单体 ,采用低温溶液缩聚方法 ,合成了一系列新的手性近晶C相串型液晶共聚酯 .共聚酯通过GPC、DSC、TG、WAXD、偏光显微镜和旋光仪等方法表征 .发现所有的共聚酯加热至各自的熔点以上都能形成液晶态 ,在液晶态可以观察到近晶相的焦锥织构 ,所有的手性化合物和共聚酯都有较高的旋光性 .通过变温X 射线衍射研究结合偏光显微镜观察和旋光分析证明它们为手性近晶C相 .所有共聚酯的熔融温度 (Tm)和各向同性温度 (Ti)随共聚酯中不同柔性链段长度的增加逐渐降低 ,液晶态温度范围变宽     

A Single Component Mutation Evolutionary Programming

In this paper, a novel evolutionary programming is proposed for solving the upper and lower bound optimization problems as well as the linear constrained optimization problems. There are two characteristics of the algorithm: first, only one component of the current solution is mutated in each iteration; second, it can solve the linear constrained optimization problems directly without converting it into unconstrained problems. By solving two kinds of the optimization problems, the algorithm can not only effectively find optimal or close to optimal solutions but also reduce the number of function evolutions compared with the other heuristic algorithms.     

关于“信息熵”分析及其应用的研究

本文用Ｓｈａｎｎｏｎ熵函数的观点及最大离散熵原理，探讨了对随机试验项目的优选问题：即压缩某种“不确定性”试验项目的实施与探索．并通过应用实例的计算，获得了满意的聚类效果．这种方法对于信息资料的数据处理及压缩“不确定性“验项目具有普遍意义．     

一类连续函数模拟退火算法及其收敛性分析

高维连续函数的全局优化问题普遍存在于计算生物学、计算化学等领域．针对这类问题和现有连续函数模拟退火算法的某些不足,本文给出了一类改进的模拟退火算法．采用一种简单的方法证明了算法的全局收敛性．数值结果表明,对于高维连续函数,该算法能够快速有效地收敛到全局最优点,比较了两种新解产生方法的试验结果。     

GLOBAL WEAK SOLUTIONS OF THE RELATIVISTIC VLASOV-KLEIN-GORDON SYSTEM IN TWO DIMENSIONS

In this paper we consider the system of classical particles coupled with a Klein-Gordon field in two dimensions.We establish a-priori-bounds on the solutions of this system with initial data satisfying a size restriction derived from conservation of energy.This result,together with the smoothing of"velocity averaging",yields the existence of global weak solutions to the corresponding restricted initial value problem.The size restriction is necessary since energy of the system is indefinite.Finally,we show that the weak solutions preserve the total mass.     

Decreasing trend of temperature in Princess Elizabeth Land, Antarctica in the past 150 years

A 50-m firn core drilled in Princess Elizabeth Land, Antarctica, during the 1996/1997 Chinese First Antarctic Inland Expedition, has been measured for d 18O and major ions. Based on the high quality of the seasonal variations of major ions, the firn core was dated with errors within ±3 years. The features of the temperature change in the past 150 years in the investigated region have first been studied based on the oxygen isotope in the upper 32.93 m of the firn core. Results show that the temperature decreased nearly by 2℃ in Princess Elizabeth Land in the past 150 years. On the background of the global, especially the Southern Hemispheric warming in the past 150 years, a temperature decline of 2℃ in Princess Elizabeth Land likely reflects the impacts of the unique Southern Hemisphere atmospheric circulation, the Antarctic Circumpolar Wave (ACW) and the special terrain (such as the large drainage basins) on the coastal regions of Antarctica.     

一类描述混沌映射的符号动力系统

本文定义了符号空间上的拟移位映射,并用该类映射描述了Ｃａｎｔｏｒ集及平面Ｃａｎｔｏｒ集上的混沌映射,本文结果可看作Ｓｍａｌｅ马蹄模型的简化。     

苯乙烯本体聚合动力学及链转移反应的研究

本文以新的计算方法对烯烃单体的本体聚合动力学进行了较全面的理论分析,获得了一系列的动力学方程式.使用这些方程式可对聚合实验数据以合理而有效的处理.     

量子能谱的非线性解法

本文建议一个求解量子系统束缚态能量本征值的新方法。通过一个积分变换,Schr(?)dinger方程可转变为非线性的Riccati方程,求解它相当于对位势作带参数(能量)的反Miura变换。借助于节点定理我们可以绕过特殊函数而迅捷得到全部能级,从而使量子能谱的求解过程大为简化。     

岩体动态响应分析程序的微机化及其应用

开发微机化的数值分析程序是推广数值方法在岩体工程中应用的一条有效途径。本文首先介绍一种微机数值分析程序的内存数据处理方法，然后介绍据此对岩体动态响应分析的二维非线性有限元程序ＤＹＮＰＡＫ的微机化改造和应用实例。