EFFECTS OF CHAIN STRUCTURE OF POLYPYRROLONES ON THE ELECTRICAL PROPERTIES OF PYROLYZED POLYPYRROLONES

Three kinds of polypyrrolones (PMDA-DAB, PMDA-TADPE and DEDA-DAB) werepyrolyzed at high temperature in order to study the effect of the chain structure of polypyrro-lones on the electrical properties of the pyrolyzed polymers. Results show that the num-ber of fusing rings in the main chain of polymers has a little effect on the pyrolysis pro-cess, whereas, the ether bond in the main chain plays an important role during pyrolysis.Structure characterizations by elemental analyis, XPS spectra, X-ray diffraction and SEMimages indicate that because the ether bond is easy to break, it is difficult to form largearea planar network. This hampers the formation of the graphite-like structure in thepolypyrrolones containing ether bond even after being pyrolyzed at 1200℃.     

Interactions between polymers and carbon nanotubes: a molecular dynamics study

We used force-field-based molecular dynamics to study the interaction between polymers and carbon nanotubes (CNTs). The intermolecular interaction energy between single-walled carbon nanotubes and polymers was computed, and the morphology of polymers adsorbed to the surface of nanotubes was investigated. Furthermore, the "wrapping" of nanotubes by polymer chains was examined. It was found that the specific monomer structure plays a very important role in determining the strength of interaction between nanotubes and polymers. The results of our study suggest that polymers with a backbone containing aromatic rings are promising candidates for the noncovalent binding of carbon nanotubes into composite structures. Such polymers can be used as building blocks in amphiphilic copolymers to promote increased interfacial binding between the CNT and a polymeric matrix.     

岩体非线性随机反分析优化算法的研究

运用最优化理论 ,通过构造公差准则函数序列 ,在近似可行概念和非线性加速单纯形法的基础上 ,得出了三维非线性位移随机反分析的伸缩保养法 岩体的性态采用弹塑性 开裂模型描述 ,考虑工程中实测位移的随机波动性 ,应用随机反分析的目标函数 非线性迭代采用收敛稳定的子增量变Kp 法 工程实例表明该方法是有效和可行的     

Characterization of refractive index distribution of polymer optical fiber

A focusing method is developed to characterize the refractive index profile of polymer optical fiber (POF). Based on the refractive index profile the theoretical bandwidth and the core index exponentα (α > 0) of POF are calculated. The results show that the value of theoretical bandwidth agrees well with the experimental data.     

基于改进IMK恢复力模型的填充墙RC框架结构地震易损性分析

为了对填充墙RC框架结构在设防大震下的抗震能力进行评估,采用OpenSees有限元软件,建立了填充墙RC框架结构的数值模型,其中,梁柱构件采用基于改进IMK恢复力模型的集中塑性铰单元进行建模,填充墙用双对角斜撑受压杆模拟,并采用基于Clough模型的桁架单元建模。以填充墙的不同布置方式作为参数,设计了4种模型,对模型进行了44条地震波下的增量动力时程分析和倒塌易损性分析。结果表明,底层不布置填充墙的模型和底部两层各有一跨布置填充墙的模型不满足我国规范中"大震不倒"的性能要求,在实际工程中应尽量避免运用此类型的框架结构,需要对已有的此类结构进行加固处理。     

Water-soluble dendrimer–poly(ethylene glycol) starlike conjugates as potential drug carriers

The design and synthesis of a new dendrimer–poly(ethylene glycol) (PEG) conjugate that may be used as a model drug carrier are described. The starting material is a polyether dendrimer with two different types of chain end functionalities. The dendritic assembly is made water soluble through attachment of short PEG chains to the dendrimer via one type of functionality. The remaining chain end functionalities then were used to incorporate model drug molecules of varying polarity into the modified dendrimer. Cholesterol and two amino acid derivatives were selected as model drugs for attachment through their respective hydroxyl, carboxylic acid, and amino functional groups to the dendrimer via carbonate, ester, and carbamate linkages. The resulting water-soluble dendrimer-model drug conjugates were characterized by matrix-assisted laser desorption ionization time of flight (MALDI-TOF) mass spectrometry. © 1999 John Wiley & Sons, Inc. J Polym Sci A: Polym Chem 37: 3492–3503, 1999     

Mechanism of enhancement of conductivity for pyrolyzed polypyrrolone film at high temperature

The effects of the pyrolytic temperature on the structure of the pyrolyzed polypyrrolone (PMDA-DAB) films were investigated. The structure of pyrolyzed PMDA-DAB film was characterized by elemental analysis, XPS spectra, x-ray diffraction, and SEM images. It suggests that the pyrolysis process of PMDA-DAB films consists of carbonization and graphitization processes, and the transitional temperature is at ca. 800°C. During carbonization process (T_p < 800°C), most oxygen is removed and the enhancement of conductivity with the pyrolytic temperature may be due to an extended conjugation of π-electron orbitals resulting in an increase of the number of charge carriers. During graphitization (T_p > 800°C), both oxygen and hydrogen are removed completely, and an increase in the mobility of charge carriers may increase conductivity with pyrolytic temperature. A graphite-like structure with heterocyclic rings containing nitrogen atoms is proposed for the PMDA-DAB film pyrolyzed at 1200°C. © 1996 John Wiley & Sons, Inc.     

基于混合型WENO格式数值模拟四类Riemann问题

本文基于三阶WENO格式和三阶WENO-Z格式,利用有限体积法研究了同一格式在不同方向使用不同的求解器,以及在不同方向采用相同精度的不同格式数值模拟4类Riemann问题,分析各向异性对数值计算结果的影响．数值结果表明,无论是使用不同的格式,还是使用不同的求解器进行数值模拟,都会导致数值结果不同程度地失去图像对称性．     

常温常湿条件下Au/Fe2O3催化剂上CO氧化反应的稳定性

用共沉淀法制备了Ａｕ／Ｆｅ２Ｏ３催化剂,考察了焙烧温度及金含量对Ａｕ／Ｆｅ２Ｏ３催化剂上ＣＯ氧化反应的影响,结果表明,焙烧温度及金含量对催化剂的稳定性均有较大影响,金含量为３％,３００℃焙烧制得的样品具有较好的稳定性和抗水性,在常温湿条件下可连续反应４３０ｈ保持ＣＯ完全转化;催化剂的稳定性与单质金及α－Ｆｅ２Ｏ３的粒径成反比,并与金及铁的化学状态有关,金粒子聚集、氧化态金含量的减少及催化剂表面碳酸根物种的累积可能是导致催化剂活性衰减的主要原因。