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941.
A new synthetic protocol for the synthesis of large diameter (2.5 to 5 μm), temperature-, and pH-responsive microgels via
aqueous surfactant-free radical precipitation copolymerization is presented. We have found that in this size range, which
is not typically attainable using traditional dispersion polymerization approaches, excellent monodispersity and size control
are achieved when the synthesis employs a programmed temperature ramp from 45 to 65 °C during the nucleation stage of the
polymerization. A combined kinetic and thermodynamic hypothesis for large particle formation under these conditions is described.
Particle sizes, volume phase transition temperatures, and pH responsivity were characterized by particle tracking and photon
correlation spectroscopy to illustrate their similar behavior to particles made via more traditional routes. These particles
have been enabling for various studies in our group where microscopic visualization of the particles is required. 相似文献
942.
Lap Mou Tam Juhn Horng Chen Hsien Keng Chen Wai Meng Si Tou 《Chaos, solitons, and fractals》2008,38(3):826-839
A system with more than one positive Lyapunov exponent can be classified as a hyperchaotic system. In this study, a sinusoidal perturbation was designed for generating hyperchaos from the Chen–Lee chaotic system. The hyperchaos was identified by the existence of two positive Lyapunov exponents and bifurcation diagrams. The system is hyperchaotic in several different regions of the parameters c, ε, and ω. It was found that this method not only can enhance or suppress chaotic behavior, but also induces chaos in non-chaotic parameter ranges. In addition, two interesting dynamical behaviors, Hopf bifurcation and intermittency, were also found in this study. 相似文献
943.
944.
In this article, electrochemistry of mitochondria is achieved. Cyclic voltammograms of freshly prepared mitochondria were obtained by immobilizing mitochondria together with glutaraldehyde and bovine serum albumin on the surface of a pyrolytic graphite electrode. Two pairs of redox peaks could be observed which were ascribed to the electron transfer reactions of cytochrome c and FAD/FADH2. Study of submitochondrial particles was also conducted, which could confirm the results of the study of the entire mitochondria. The redox wave of NADH could be obtained due to the destruction of the membrane of mitochondria. We have also checked the function of succinate in mitochondria by employing the electrochemical method. This work is not only the first to be able to obtain the direct electrochemistry of mitochondria, but is also beneficial to the further understanding of the structure and function of mitochondria in vitro. 相似文献
945.
Joann Huber Robert G.K. Donald Sang Ho Lee Lisa Wang Jarantow Michael J. Salvatore Xin Meng Ronald Painter Russell H. Onishi James Occi Karen Dorso Katherine Young Young Whan Park Stephen Skwish Michael J. Szymonifka Tim S. Waddell Lynn Miesel John W. Phillips Terry Roemer 《Chemistry & biology》2009,16(8):837-848
946.
给出了种利用单片机微机8031和集成实时时钟芯片MC146818控制的巨型石英钟的电路结构图以及部分程序流图。 相似文献
947.
孟宪林 《河南师范大学学报(自然科学版)》1990,(2):72-78
为保持竞技体操的领先地位,我国从1988年开始执行新的《体操教学训练大纲》。本文以河南省第一届青少年运动会体操比赛为资料,对如何根据具体情况,更好地实施《大纲》等问题作了综合研究,希望能对我国培养优秀后备选手,攀登技术高峰起促进作用。 相似文献
948.
作者引入了非齐型空间上的弱Herz空间,并建立了一类次线性算子在这些空间中的弱型估计. 作为应用, 证明了由Calder\'on-Zygmund算子和$\os$函数生成的交换子在弱Herz空间中的弱型估计,其中$r\ge1$. 并且Orlicz空间$\os$当$r=1$时即为$\rb$空间;当$r>1$时为$\rb$的子空间. 相似文献
949.
Xinzhu Meng Jianjun Jiao Lansun Chen 《Nonlinear Analysis: Theory, Methods & Applications》2008,68(12):3633-3645
A nonautonomous Lotka–Volterra dispersal system with continuous delays and discrete delays is considered. By using a comparison theorem and delay differential equation basic theory, we obtain sufficient conditions for the permanence of the population in every patch. By constructing a suitable Lyapunov functional, we prove that the system is globally asymptotically stable under some appropriate conditions. Using almost periodic functional hull theory, we get sufficient conditions for the existence, uniqueness and globally asymptotical stability for an almost periodic solution. This implies that the population in every patch exhibits stable almost periodic fluctuation. Furthermore, the results show that the permanence and global stability of system, and the existence and uniqueness of a positive almost periodic solution, depend on the delay; then we call it “profitless”. 相似文献
950.
Meng Yuan Wenlong Xu Ying Yang Suying Li Haiyan Yang Jun Gao Heqing Jiang Menglong Yang 《Chemphyschem》2023,24(24):e202300587
Studying the characteristics and molecular mechanisms of liquid self-diffusion coefficient and viscosity changes is of great significance for, e. g., chemical and petroleum processing. As examples of highly complex liquid,an asphaltene-free high-acid and high-viscosity crude oil and its extracted fractions were studied by comparing their 1H DOSY diffusion maps. The crude oil exhibited a polydisperse diffusion distribution, including multiple diffusion portions with diffusion coefficients much smaller than that of any single fraction in independent diffusion. The main mechanism that leads to the decreases in the diffusion coefficients of crude oil is attributed to diffusion resistance enhanced by Dynamical Molecular-Interaction Networks (DMINs), rather than by enlargement of the diffusion species caused by molecular aggregation. Constructed through the synergistic interactions of various polar molecules in crude oil, DMINs dynamically bind polar molecules, trap polarizable molecules, and spatially hinder the free motion of non-polar molecules. Overall, this reduces the mobility of all molecular species, as illustrated by the decreased diffusion coefficients. This study demonstrates that DOSY is a powerful NMR method to investigate molecular motion abilities also in complex mixtures. In addition, the insights in the influence of the interaction matrix on the molecular mobility also help to understand the contribution of “structural viscosity” to the viscosity of heavy oil. 相似文献