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951.
Maryam Mirza‐Aghayan Mahboubeh Khoshkameh Langrodi Mahshid Rahimifard Rabah Boukherroub 《应用有机金属化学》2009,23(7):267-271
An efficient synthesis of 1,4‐dihydropyridine derivatives has been achieved by the one‐pot cyclocondensation reaction of methyl 3‐aminocrotonate and a range of aldehydes in the presence of chlorotrimethylsilane as a promoter under solvent‐free conditions. The cyclocondenstion reaction requires a very short time and takes place in good to excellent yields. Furthermore iodotriethylsilane, generated in situ by the reaction of triethylsilane and methyl iodide in the presence of palladium chloride, has been investigated for the synthesis of 1,4‐dihydropyridine derivatives. This facile and efficient method affords high yields for the preparation of 1,4‐dihydropyridines at room temperature and short reaction times. Copyright © 2009 John Wiley & Sons, Ltd. 相似文献
952.
RuIII(OTf)SalophenCH2–NHSiO2–Fe: an efficient and magnetically recoverable catalyst for trimethylsilylation of alcohols and phenols with hexamethyldisilazane
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Maryam Torki Shahram Tangestaninejad Valiollah Mirkhani Majid Moghadam Iraj Mohammadpoor‐Baltork 《应用有机金属化学》2014,28(4):304-309
Efficient trimethylsilylation of alcohols and phenols with hexamethyldisilazane (HMDS) catalyzed by ruthenium(III) complex of chloromethylated Salophen supported on nanomagnetic materials is reported. First, the iron nanomagnets were silica coated, functionalized with amine and then ruthenium CM‐Salophen was successfully bonded to their surface. The catalyst, RuIII(OTf)SalophenCH2–NHSiO2–Fe, was characterized by elemental analysis, FT‐IR and UV–visible spectroscopic techniques, transmission electron microscopy and inductively coupled plasma (ICP). The RuIII(OTf)SalophenCH2–NHSiO2–Fe catalyzed trimethylsilylation of primary and secondary alcohols as well as phenols, and the corresponding TMS ethers were obtained in high yields and short reaction times at room temperature. This new heterogenized trimethylsilylation catalyst is easily recovered with a magnet and showed no appreciable loss of activity even after five consecutive runs. Copyright © 2014 John Wiley & Sons, Ltd. 相似文献
953.
Homayoon Bahrami Mehdi D. Davari Maryam Keshavari Mansour Zahedi Ayoob Bazgir Ali A. Moosavi‐Movahedi 《国际化学动力学杂志》2009,41(11):689-703
The influence of substitution on the amine functional group of glycine in the permanganic oxidation of such an α‐amino acid in moderately concentrated sulfuric acid medium has been investigated. Reaction products analysis has revealed that contrary to the usual α‐amino acid oxidation product, which is an aldehyde species, a valuable compound, namely 1,4‐dimethylpiperazine‐2,5‐dione, has been obtained as the main product via a cheap, simple, efficient, and novel method. Sarcosine has been chosen as a substituted derivative of glycine, and the kinetics and mechanism of its permanganic oxidation have been investigated using a spectrophotometric technique. Conclusive evidence has proven delayed autocatalytic activity for Mn(II) in this reaction, analogous to some α‐amino acids. It has been revealed that such activity can show up when a certain concentration ratio of Mn(II) to sarcosine is built up in the medium, which we call the “critical ratio.” The magnitude of the latter ratio depends on the sulfuric acid concentration. Considering the “delayed autocatalytic behavior” of Mn(II) ions, rate equations satisfying observations for both catalytic and noncatalytic routes have been presented. The reaction shows first‐order dependence on permanganate ions and sarcosine concentrations in both catalytic and noncatalytic pathways, and apparent first‐order dependence on Mn2+ ions in catalytic pathways. The correspondence of pseudo‐order rate constants of the catalytic and noncatalytic pathways to Arrhenius and Eyring laws has verified “critical ratio” as well as “delayed autocatalytic behavior” concepts. The activation parameters associated with both pathways have been computed and discussed. Mechanisms for both catalytic and noncatalytic routes involving radical intermediates as well as a product having a diketopiperazine skeleton have been reported for the first time. © 2009 Wiley Periodicals, Inc. Int J Chem Kinet 41: 689–703, 2009 相似文献
954.
Mohammad Mazloum Ardakani Hossein Dehghani Maryam Jalayer Hamid R Zare 《Analytical sciences》2004,20(12):1667-1672
The performance of silver metal complexes with meso-tetraphenylporphyrin ([H2T(4-CH3)]PP) as ionophores for ion-selective electrodes was studied. The electrode exhibited linear response with Nernstian slope of 59.2 +/- 1.0 mV per decade within the concentration range of 1.0 x 10(-7)-1.0 x 10(-1) M silver ions. The limit of detection as determined from the intersection of the extrapolated linear segments of the calibration plot, was 1.0 x 10(-7) M. The response time of the electrode was < 10 s over the entire concentration range. The silver-selective electrode exhibited good selectivity for Ag(I) with respect to alkali, alkaline earth and heavy metal ions. The electrodes could be used at least three months without a considerable divergence in their potential. The electrodes are suitable for use in aqueous solutions in a wide pH range of 3.0-9.0. They were used as indicator electrodes in titration of Ag(I) with sodium iodide solution and were successfully applied to direct determination of silver in real samples. 相似文献
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An efficient one-pot method has been developed for the synthesis of α-oxycarbanilinophosphonates via a one-pot reaction of an aldehyde with diethyl phosphite in the presence of magnesium oxide followed by reaction with an isocyanate under solvent-free conditions using ultrasonic irradiation. This method is simple, rapid and good yielding. 相似文献
958.
Maryam Mirza‐Aghayan Rabah Boukherroub Mahshid Rahimifard Mohammad Bolourtchian 《应用有机金属化学》2010,24(6):477-480
Reduction of a variety of nitroaromatic compounds with triethylsilane in the presence of catalytic amounts of palladium chloride in ethanol resulted in the formation of the corresponding anilines in excellent yields. Copyright © 2010 John Wiley & Sons, Ltd. 相似文献
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