将SVRT模型应用到单原子多原子反应F+CH2D2→CH2D/CHD2+DF/HF中

由于含时波包方法具有经典的直观又不乏量子力学的准确 ,选择含时波包方法来处理F +CH2 D2 →CH2 D/CHD2 +DF/HF反应 .把半刚性振转子 (SVRT)模型应用到该反应体系中 ,研究了两个通道中该反应从基态反应物开始在修正过的J1(MJ1)势能面上计算出来了反应几率、积分截面、速率常数 .反应几率随能量变化的图的数值结果给出了振荡结构 ,这些振荡结构是可以和动力学振荡联系起来的 .而这些振荡结构在积分截面随着能量变化的图中就被反应几率求和后的平均结果所掩盖了 .速率常数和实验结果的比较也得到了较好的结果 .     

Weight measurement using image-based pose analysis

Image-based gait analysis as a means of biometric identification has attracted much research attention. Most of the existing methods focus on human identification, posture analysis and movement tracking. There have been few investigations on measuring the carried load based on the carrier＇s gait characteristics by automatic image processing. Nevertheless, this measurement is very useful in a number of applications, such as the study of the carried load on the postural development of children and adolescence. In this paper, we investigate how to automatically estimate the carried weight from a sequence of images. We present a method to extract human gait silhouette based on an observation that humans tend to minimize the energy during motion. We compute several angles of body leaning and determine the relationship of the carried weight, the leaning angles and the centroid location according to a human kinetic study. Our weight determination method has been verified successfully by experiments.     

砼强度准则在井壁结构中的应用研究

本文根据井壁结构模型试验结果,对目前具有代表性的复杂应力状态下的砼强度准则进行了分析和对比,找到了一种比较适合于井壁结构的砼强度准则,从而为井壁结构承载能力的合理计算提供了理论基础.     

论微观辨证

探讨了在中、西医理论不同的前提下，如何合理选择应用现代检测项目作为辩证的指标，并提出微观辩证的新概念。     

一类下级有穷的拟素整函数

证明了对有穷级整函数,若Julia方向总数有穷,且有一个有穷亏值,则能找到一个角形域,使该函数在此角形域内有界。并以此结论证明了该函数是拟素的。     

Preparation of new mixed ligand complexes of lanthanide acetylacetonate with dibenzo-18-crown-6 and their IR spectra

Fourteen new mixed ligand complexes of lanthanide acetylacetonate and dibenzo-18- crown-6 (DB18C6) were prepared by three different methods. The composition of the complexes was shown to be Ln(acac)· DB18C6 by elemental analysis and X-ray powder diffraction. Infrared spectra of the complexes were investigated, and the results indicate that their absorption bands in the region of 400—4000 cm^?1 are complicated and without much difference from each other, but in the far infrared region various absorption bands of Ln—O can be observed and they changes regularly with the atomic number of lanthanides.     

抗坏血酸同顺磁离子Mn~(2+)、Gd~(3+)络会的~(13)C NMR研究

该文用顺磁离子对其近邻~(13)C核的NMR吸收增宽效应,系统地研究了抗坏血酸在不同溶剂中对金属离子Mn~(2+)、Gd~(3+)的配合行为.在水溶液中,抗坏血酸可通过两种配合方式与Mn~(2+)作用,但与Gd~(3+)的作用只有一种稳定的结构.在水中抗坏血酸对金属的配位活性部位分别是1位羟基氧,3位离解的羟基氧和6位羟基氧.在DMSO中,3位羟基由于H~+对该基团的静电遮蔽而变得对金属离子Mn~(2+)表现为配位惰性,同时6位羟基配位活性较大增强.对Gd~(3+)来说,此时没有优势配位活性部位存在.文章还讨论了抗坏血酸在H_2O-DMSO混合溶剂中的~(13)C NMR谱及在DMSO中NaOH对其~(13)C NMR谱及其与金属络合结构的影响.