Crystal and molecular structure of crenatine carbonate

The crystal and molecular structure of 1-ethyl-4-methoxy-9H-pyrido[3,4b]indole (crenatine) carbonate C₁₄H₁₄N₂O·H₂CO₃, (MS, m/z 226)M _R 288.3, a-carboline alkaloid, has been determined from X-ray diffraction data. The compound crystallizes in the space group Pbca with cell parameters:a=11.616(4),b=18.450(8),c=12.992(5)Å,V=2784(2)ų,Z=8,D _calc=1.375 g cm^–3, (MoK)=0.71069Å,(Mo K)=0.94 cm^–1,F(000)=1216,R/R _w =8.2/10.3% for 1099 reflections. The ring system of the-carboline nucleus is planar. The title compound shows a two center hydrogen bond between the indole N-H group and the oxygen atom of a carbonate group. The structure does not display hydrogen bonding between-carboline groups but rather a bonding network involving the carbonate group.     

Behavior on the real line of entire functions represented by Dirichlet series with complex exponents

It is shown, in particular, that if _{n k} when n k, Re _n > 0, and , then an entire function F that is bounded on the real line and represented by a Dirichlet series d_n exp (_nz) that is uniformly and absolutely convergent on each compactum in is identically zero.Translated from Ukrainskii Matematicheskii Zhurnal, Vol. 42, No. 7, pp. 882–888, July, 1990.     

A numerical analysis of chaotic behaviour in Bianchi IX models

In this paper we investigate the chaotic behaviour of the Bianchi IX cosmological models using techniques developed in the study of dynamical systems and chaotic behaviour. We numerically calculate the Lyapunov exponent, , and show that instead of converging to a constant value, it decreases steadily. We study this effect further by studying the Lyapunov exponent using short-time averages. We show that the usual method of calculating is invalid in the case of a cosmological model.     

Random fields and quantum effects in proton glasses

The effects of quantum fluctuations on the proton glass phase in mixed hydrogen-bonded ferro-antiferroelectric systems are considered. The system is described in terms of the infinite-ranged Ising pseudospin glass model in a transverse tunneling field in the presence of random parallel fields. The stability limit of the high-temperature proton glass phase is determined within the thermofield dynamic approach, and the behavior or linear and nonlinear susceptibility is evaluated.     

Disordered charge distributions and dielectric loss in extra dense flint glasses

The complex permittivities of some extra dense flint glasses (EDF glasses) have been studied. The dielectric features of the samples are dominated by their PbO content. Both refractive indices and dielectric losses exhibit a close relation to the concentration of Pb ions. The latter are located either at sites of the network atoms or filling the potential minima interstitially. They can be identified by their different relaxation mechanisms. The dispersion in the submillimeter wave and FIR area is characterized by a very broad distribution of comparably sharp resonant states. Thermal lens — or hysteresis effects can be excluded.     

Non-characteristic mixed problems for non-linear symmetric hyperbolic systems

In this paper the existence and uniqueness of solutions of the following initial boundary value problem for non-linear symmetric hyperbolic equations of the first order are shown, where M = I ⁺ ? S , has the same from as the Kreiss' condition, but S must be sufficiently small ( I ⁺ is the unit matrix in the space generated by eigenvectors of the matrix ? A · n? , corresponding to positive eigenvalues) and n? is a unit outward vector normal to the boundary. The main result of the paper is obtaining an a priori estimate for non-linear equations. This estimate is obtained for sufficiently small time and norms of given data functions. The existence of solutions is proved by the method of successive approximations, which can be used because at each step such properties as symmetry of matrices and the numbers of positive and negative eigenvalues of the matrix ? A · n? are assured. This can be done because we restrict our attention to such systems of equations for which these properties are satisfied for solutions from some neighbourhood of initial data u ₀. Therefore, using the fact that solutions in the class of continuous functions are sought, these properties can be satisfied for sufficiently small time. Moreover, some examples of initial boundary value problems for equations of hydrodynamics and magnetohydrodynamics are considered.     

Upper-Branch Instability of Flow in Pipes of Large Aspect Ratio with Three-Dimensional Nonlinear Viscous Critical Layers

We consider the upper-branch neutral stability of flow in pipesof large aspect ratio, basically extending the work of F. T.Smith to the nonlinear regime. The inclusion of weak nonlinearityleads to an eigenproblem whose solution depends on the propertiesof three-dimensional nonlinear critical layers. Two specialcases are considered. The first is for very small amplitude perturbations, where R is a Reynolds numberbased on the height of the tube and which is assumed large.Then a fully analytical solution of the three-dimensional criticallayers is possible, from which the linear results of Smith maybe deduced. The second case studied is that of flow in a rectangularpipe, where a solution of the nonlinear critical layer problemcan be obtained. Further analysis of neutral modes in this lattercase suggests the possible existence, inter alia, of neutralmodes for finite aspect ratio tubes. These modes depend on thescaled amplitude and have O(1) wavespeeds.     

On the dynamics of cosmological particle production

The time evolution of the particle number density and spectrum of massive scalar particles, coupled conformally to a classical Friedman-Robertson-Walker gravitational field is followed numerically. Not only for a pure radiation cosmos, but also for one with an inflationary interlude, the density of particles produced remains constant in time. This results in a constant equivalent temperature scale up to the Compton time of the massive particles, and opens the possibility that during a sufficiently long inflation the energy density of the particles produced can exceed that of the radiation background.     

Crystal structures of dimethylsuccinate and dimethyloxalate: Carbonyl group orientation for C13 chemical shielding tensor studies

The crystal structures of dimethylsuccinate (DMS) and dimethyloxalate (DMO) have been determined to facilitate the determination of the C-13 chemical shielding tensors of the carbonyl carbon in esters. Crystals of DMS are monoclinic, space groupC2/c,Z=4,a=13.154(4),b=6.156(1),c=9.363(4)Å,=98.53(3)°. The structure was solved by direct methods and refined by leastsquares procedures to giveR=0.071 for 932 observed data. Crystals of DMO are monoclinic space group,P2₁/n,Z=2, witha=3.891(1),b=11.879(2),c=6.213(2) Å,=103.32(2)°. The structure is the same (within experimental error) as that reported by Dougill and Jeffrey (1953) and refined to giveR=0.074 for 395 observed data.