CO-laser photoacoustic detection of phosgene (COCl2)

Detection of COCl₂, a highly toxic gas in chemical industry, using laser photoacoustic spectroscopy is presented. The spectrophone system used has a broad band LN₂ cooled CW CO laser as a source of radiation, which operates from 4.8–8.4 um in the mid-infrared. Using an extracavity open longitudinal resonant cell, absorption signals to about 30 CO laser lines in the 5.45 um region could be observed. detection sensitivity has been estimated to be ppb order.This work has been supported by the NSFC     

Lattice Boltzmann Model for the Incompressible Navier–Stokes Equation

In this paper a lattice Boltzmann (LB) model to simulate incompressible flow is developed. The main idea is to explicitly eliminate the terms of o(M ²), where M is the Mach number, due to the density fluctuation in the existing LB models. In the proposed incompressible LB model, the pressure p instead of the mass density ρ is the independent dynamic variable. The incompressible Navier–Stokes equations are derived from the incompressible LB model via Chapman–Enskog procedure. Numerical results of simulations of the plane Poiseuille flow driven either by pressure gradient or a fixed velocity profile at entrance as well as of the 2D Womersley flow are presented. The numerical results are found to be in excellent agreement with theory.     

整系数多项式是否存在有理根的几种判别法及应用

本文给出一类整系数多项式最多存在ｉ（ｉ＝０，１，２，…，ｎ－２）个有理根的判别法。并将文［３，４］中的主要结果作了进一步的推广。     

素质教育评价"建模"构想

构建素质教育评价模式，对素质教育的实施和评价有直接的推进和指导作用。构建素质教育评价模式，应当遵循导向性、科学性、系统性、有效性原则。在构建素质教育评价模式时，有多种方法可供我们选择；但在此过程中，要注意研究模式，防止“模式化”。     

Combinatorial computational chemistry approach of tight-binding quantum chemical molecular dynamics method to the design of the automotive catalysts

Recently, we have developed a new tight-binding quantum chemical molecular dynamics program “Colors” for combinatorial computational chemistry approach. This methodology is based on our original tight-binding approximation and realized over 5000 times acceleration compared to the conventional first-principles molecular dynamics method. In the present study, we applied our new program to the simulations on various realistic large-scale models of the automotive three-way catalysts, ultrafine Pt particle/CeO₂(111) support. Significant electron transfer from the Pt particle to the CeO₂(111) surface was observed and it was found to strongly depend on the size of the Pt particle. Furthermore, our simulation results suggest that the reduction of the Ce atom due to the electron transfer from the Pt particle to the CeO₂ surface is a main reason for the strong interaction of the Pt particle and CeO₂(111) support.     

正负系数中立型差分方程的正解的存在性

In this paper the sufficient conditions for the existence of positive solutions of the neutral difference equations with positive and negative coefficients are established. The results improve some known conclusions in the literature     

C~k连续的保形分段2k次多项式插值

1．引言在每个子区间上，通过插入至多一个内结点，Brodlie和Butt［1］给出了分段三次多项式保形插值算法，Randal［2］等讨论了分段五次多项式插值，作者［31讨论了一般分段奇次多项式的保形插值，并且给1了内结点的位置范围公式．这种插值方法完全解决了一般的分段奇次多项式的保形插值问题．关于分段偶次多项式的保形插值，大多数文献只讨论分段二次保形插值，这里要特别指出的是Shumake［4j导出了二次样条保凸的充要条件，并且给出了一个二次样条保形插值的方法．在每一个子区间上至多插入一个内结点，则一个二次插值样条就可得到．作…     

Reversible addition–fragmentation transfer (RAFT) copolymerization of methyl methacrylate and styrene in miniemulsion

In the reversible addition–fragmentation transfer (RAFT) copolymerization of two monomers, even with the simple terminal model, there are two kinds of macroradical and two kinds of polymeric RAFT agent with different R groups. Because the structure of the R group could exert a significant influence on the RAFT process, RAFT copolymerization may behave differently from RAFT homopolymerization. The RAFT copolymerization of methyl methacrylate (MMA) and styrene (St) in miniemulsion was investigated. The performance of the RAFT copolymerization of MMA/St in miniemulsion was found to be dependent on the feed monomer compositions. When St is dominant in the feed monomer composition, RAFT copolymerization is well controlled in the whole range of monomer conversion. However, when MMA is dominant, RAFT copolymerization may be, in some cases, out of control in the late stage of copolymerization, and characterized by a fast increase in the polydispersity index (PDI). The RAFT process was found to have little influence on composition evolution during copolymerization. The synthesis of the well‐defined gradient copolymers and poly[St‐b‐(St‐co‐MMA)] block copolymer by RAFT miniemulsion copolymerization was also demonstrated. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 6248–6258, 2004     

疼痛评估量表在体温单上的临床应用

目的探讨疼痛量化记录方法。方法对疼痛评估用数字分级法((NRS)为基础,将评估强度设计绘制在体温单上,并试用于296例术后患者疼痛评估。结果在体温单上获得了准确、系统的疼痛量化曲线图,提高了整体护理意识,并为有效开展疼痛管理工作打下了基础。结论将疼痛量化曲线图绘制在体温单上能直观、明了、动态地反映病人疼痛变化过程及护理干预镇痛或药物镇痛效果。     

GENERALIZED SIMULTANEOUS CHEBYSHEV APPROXIMATION

In this note,we develop,without assuming the Haar condition,a generalized simultaneousChebyshev approximation theory which is similar to the classical Chebyshev theory and con-rains it as a special case.Our results also contain those in[1]and[3]as a special case,and thetwo conjectures proposed by C.B.Dunham in[2]are proved to be true in the case of simulta-neous approximation.