若丹明B荧光增强二硫化碳高阶受激喇曼散射

 利用若丹明B乙醇溶液的荧光改变了二硫化碳的一至三阶Stokes喇曼谱线的强度分布,选择性地增强了三阶Stokes喇曼谱线。在泵浦功率密度为~560MW^.cm^-2时,对染料摩尔浓度分别为~10^-5、cm^-5散射池和~10^-4、1cm散射池进行实验,观察到二硫化碳的三阶Stokes喇曼谱线与染料激光形成的共振增强现象及、二阶Stokes喇曼谱线的部分或完全耗尽。     

Optimization and Comparative Study of Different Extraction Methods of Sixteen Fatty Acids of Potentilla anserina L. from Twelve Different Producing Areas of the Qinghai-Tibetan Plateau

In this study, supercritical fluid extraction (SFE), ultrasonic-assisted extraction (UAE), and microwave-assisted extraction (MAE) were applied to explore the most suitable extraction method for fatty acids of Potentilla anseris L. from 12 different producing areas of the Qinghai-Tibetan Plateau. Meanwhile, the important experimental parameters that influence the extraction process were investigated and optimized via a Box-Behnken design (BBD) for response surface methodology (RSM). Under optimal extraction conditions, 16 fatty acids of Potentilla anserina L. were analyzed via high-performance liquid chromatography (HPLC) with fluorescence detection, using 2-(4-amino)-phenyl-1-hydrogen-phenanthrene [9,10-d] imidazole as the fluorescence reagent. The results showed that the amounts of total fatty acids in sample 6 by applying SFE, UAE, and MAE were, respectively, 16.58 ± 0.14 mg/g, 18.11 ± 0.13 mg/g, and 15.09 ± 0.11 mg/g. As an environmental protection technology, SFE removed higher amounts of fatty acids than did MAE, but lower amounts of fatty acids than did UAE. In addition, the contents of the 16 fatty acids of Potentilla anserina L. from the 12 different producing areas Qinghai-Tibetan Plateau were significantly different. The differences were closely related to local altitudes and to climatic factors that corresponded to different altitudes (e.g., annual mean temperature, annual mean precipitation, annual evaporation, annual sunshine duration, annual solar radiation.). The temperature indices, photosynthetic radiation, ultraviolet radiation, soil factors, and other factors were different due to the different altitudes in the growing areas of Potentilla anserina L., which resulted in different nutrient contents.     

无催化剂条件下微波辐射一步法合成2-氨基-4-芳基-5-氧代-5,6,7,8-四氢-4H-苯并吡喃-3-腈

以芳醛、丙二腈、1,3-环己二酮为原料在无催化剂条件下,分别用微波辐射和传统加热法合成了一系列2-氨基-4-芳基-5-氧代-5,6,7,8-四氢-4H-苯并吡喃-3-腈(4a～4g)衍生物.与常规加热方法相比,微波辐射法具有反应时间短、产率高、后处理方便、环境友好等优点,所有化合物均经IR,1H MMR和元素分析确定.     

新型Sr（NO3）2的水热合成及其晶体结构

本文以Sr（NO₃）₂和水为原料,采用水热法合成了一种新型的Sr（NO₃）₂结构。利用X-射线单晶衍射对其结构进行了测定,结果表明:该晶体属于立方晶系,Pa-3空间群,α=b=c=0.77402（7）nm,α=β=γ=90.00°,V=0.46372（7）nm³,Z=4,Dc=3.031g/cm³,F（000）=400,R_gt（F）=0.0287,wR_ref（F²）=0.0888。     

改进的溶胶-凝胶法制备超细铜粉

对溶胶－凝胶法进行了改进，由溶胶直接制备出超细铜粉，找到了制备超细铜的Ｇ分散剂及最佳制备条件，并获得了平均粒径为１０ｎｍ的铜粉。     

Large-aperture double-focus laser collimator for PAT performance testing of inter-satellite laser communication terminal

A laser collimator is necessary for testing and verification of the pointing, acquisition and tracking (PAT) performance of inter-satellite laser communication terminals on the ground. The laser collimator must have a large clear aperture to fit the PAT performance testing system. The PAT subsystem has a large field of view for the acquisition and a high angular accuracy for the fine tracking. To resolve the conflict between large field of view and fine angular resolution, a large-aperture double-focus laser collimator is proposed and its optical design and mechanical structure are described. The collimator mainly consists of a primary lens, a reflector, a beam-splitting plate, a secondary lens, two compensating lenses, two imaging sensors and a laser. The primary lens directly forms the long focal length arm of the collimator. The combination of the primary lens and the secondary lens form the short focal length arm of the collimator. The collimator has an angular resolution <0.75 μrad and a 10 mrad field of view. For the collimator, the incident beam is focused on the two imaging sensors by its two arms, and the beam emitted from the laser is collimated and transmitted. The collimator is combined with an optical scanner and a fine beam deflector to test and verify the PAT performance of the inter-satellite laser communication terminal in a full physical manner.     

杨桦林普通大,中径材用材林定向培育技术的研究

采用固定标准地定位观测和临时标准地调查点面结合的方法，在立地分类的基础上＾「１」，研究了天然杨桦林林分的经营密度，确定杨桦林最佳经营密度为０．７０。根据各立地级林分平均胸径的生长进程规律、林分的经营密度模型以及林分胸径与小头直径的相关关系，提出了杨桦林大、中径材用材林定向培育技术。结果表明，采用该项技术，山杨林和白桦林林分单位面积生长量分别可提高９．５０％～２４．５２％，２７．６３％。     

次接触过程

提出一类新的粒子系统——次接触过程。它是近邻粒子系统,并以接触过程为自己的特例。讨论了它的一些性质和临界现象,指出它既不吸引也不可逆,并且求得该过程存活时,其参数的范围。这一结果是接触过程相应结论的推广。     

诱导性练习方法在纵箱支撑跳越教学中的运用

根据人类跳越障碍自然活动能力，设计了一套纵箱支撑跳越教学步骤，经实验证明，这不仅能够预防教学中学生不良心理、生理状态的产生，还有效地提高了教学效果。     

Application of chromatography technology in the separation of active alkaloids from Hypecoum leptocarpum and their inhibitory effect on fatty acid synthase

A method that involved the combination of pH‐zone‐refining counter‐current chromatography and semipreparative reversed‐phase liquid chromatography has been established for the preparative separation of alkaloids from Hypecoum leptocarpum. From 1.2 g of crude sample, 31 mg N‐feruloyltyramine, 27 mg oxohydrastinine, 47 mg hydroprotopine, 25 mg leptopidine, and 18 mg hypecocarpine have been obtained. The structure of the new compound, hypecocarpine, is confirmed based on the analysis of spectroscopic data, including NMR, UV, and IR spectroscopy and positive electrospray ionization mass spectrometry. The known chemical structures were characterized on the basis of ¹H and ¹³C NMR spectroscopy. The purities of the five alkaloids are all over 92.7% as determined by high‐performance liquid chromatography. The alkaloids’ cytotoxicity in breast cancer cells is assessed by using a Cell Counting Kit assay and their inhibitory effect on fatty acid synthase expression is assessed by a Western blot assay. These results suggest that leptopidine could suppress growth and induce cytotoxicity in breast cancer cells and that the cytotoxicity of leptopidine may be related to its inhibitory effect on fatty acid synthase expression.