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71.
A novel compound, [Co(phen)3][V10O26]·H2O, was hydrothermally synthesized and characterized by single-crystal X-ray diffraction. This compound crystallizes in the orthorhombic space group Ccca with a=13.447(3), b=29.936(6), c=23.252(5) Å, V=9360(3) Å3, Z=8 and R=0.0285. Data were collected on a Rigaku R-AXIS RAPID IP diffractometer at 293 K in the range of 1.36<θ<24.99°. The structure of the compound consists of vanadium oxide layers, which are built up from the infinite VO4 chains by corners and edges sharing. The [Co(phen)3]2+ complexes occupy the interlayer space and contact each other via π−π stacking interactions of the phen groups to form infinite one-dimensional chains. 相似文献
72.
The stimulatory effect of heavy metal cations on proliferation of aortic smooth muscle cells 总被引:1,自引:0,他引:1
K P Lu S H Zhao D S Wang 《Science in China. Series B, Chemistry, life sciences & earth sciences》1990,33(3):303-310
Heavy metal cations Cd2+, Pb2+, and Hg2+ were added to substitute for Ca2+ in culture media to study their effect on the relationship between CaM and the proliferation of cultured rabbit aortic smooth muscle cells (ASMC). It was found that all the heavy metal cations studied stimulated the proliferation of ASMC in varying degrees, increased the CaM content in cells at late G1 stage and decreased the activity of cAMP PDE. These results suggest that the adverse effect of heavy metals may be related to the pathogenesis of atherosclerosis and hypertensive disease. 相似文献
73.
Separation of the phenolic fraction of Corydalis ochotensis afforded a new spirobenzylisoquinoline alkaloid, isoochotensine ( 1 ) and three known alkaloids, ochotensine ( 3 ), cheilanthifoline ( 7 ), and lienkonine ( 9 ) as their acetyl derivatives together with a known nonphenolic alkaloid, ochotensimine ( 5 ). Their structures were elucidated by the spectral data. 相似文献
74.
75.
Simple heteroarenes such as pyrroles and indoles undergo addition reactions to C-C triple bonds in the presence of a catalytic amount of Pd(OAc)(2) under very mild conditions, affording cis-heteroarylalkenes in most cases. The cleavage of aromatic C-H bonds is the possible rate-determining step in CH(2)Cl(2), and the addition of heteroaromatic C-H bonds to C-C triple bonds is in a trans-fashion. 相似文献
76.
Recent breakthrough in synthesizing arbitrary vertical heterostructures of Ruddlesden–Popper (RP) perovskites opens doors to myriad quantum optoelectronic applications. However, it is not clear whether moiré excitons and flat bands can be formed in such heterostructures. Here, we predict from first principles that twisted homobilayers of RP perovskite, MA2PbI4, can host moiré excitons and yield flat energy bands. The moiré excitons exhibit unique and hybridized characteristics with electrons confined in a single layer of a striped distribution while holes localized in both layers. Nearly flat valence bands can be formed in the bilayers with relatively large twist angles, thanks to the presence of hydrogen bonds that strengthen the interlayer coupling. External pressures can further increase the interlayer coupling, yielding more localized moiré excitons and flatter valence bands. Finally, electrostatic gating is predicted to tune the degree of hybridization, energy, position and localization of moiré excitons in twisted MA2PbI4 bilayers.Excitonic states in twisted MA2PbI4 bilayers were calculated by first-principles calculations. 相似文献
77.
Czechoslovak Mathematical Journal - During the last decade, several research groups have published results on sufficient conditions for the hamiltonicity of graphs by using some topological... 相似文献
78.
Annals of the Institute of Statistical Mathematics - The research is about a systematic investigation on the following issues. First, we construct different outcome regression-based estimators for... 相似文献
79.
Numerical Algorithms - Iterative algorithms based on thresholding, feedback, and null space tuning (NST+HT+FB) for sparse signal recovery are exceedingly effective and efficient, particularly for... 相似文献
80.
睡莲科植物酯酶同功酶的数量分类研究 总被引:3,自引:0,他引:3
采用垂直平板聚丙烯酰胺凝胶盘状电泳技术,对国内睡莲科植物(包括6个属的6个代表种及3个品种)的叶片进行了酯酶同功酶的测定,初步结果表明被测植物均有各自稳定的酯酶酶谱.运用数量分类学方法对被测植物进行聚类,其中白睡莲与其派生的红睡莲和黄睡莲2品种聚为一类,南芡与北芡亦聚为一类,而此2类与萍蓬草、莲、莼菜和王莲的亲缘关系较远,且后4种植物之间亲缘关系亦远.该结果与由过氧化物同功酶酶谱的分析结果基本相似. 相似文献