全文获取类型
收费全文 | 102049篇 |
免费 | 13474篇 |
国内免费 | 8644篇 |
专业分类
化学 | 50546篇 |
晶体学 | 662篇 |
力学 | 4689篇 |
综合类 | 313篇 |
数学 | 8223篇 |
物理学 | 27787篇 |
综合类 | 31947篇 |
出版年
2024年 | 362篇 |
2023年 | 1993篇 |
2022年 | 2870篇 |
2021年 | 3341篇 |
2020年 | 3443篇 |
2019年 | 3007篇 |
2018年 | 2736篇 |
2017年 | 2610篇 |
2016年 | 3808篇 |
2015年 | 3956篇 |
2014年 | 5002篇 |
2013年 | 6082篇 |
2012年 | 7638篇 |
2011年 | 7772篇 |
2010年 | 5458篇 |
2009年 | 5353篇 |
2008年 | 5767篇 |
2007年 | 5379篇 |
2006年 | 4839篇 |
2005年 | 4298篇 |
2004年 | 3262篇 |
2003年 | 2608篇 |
2002年 | 2413篇 |
2001年 | 2260篇 |
2000年 | 2234篇 |
1999年 | 3313篇 |
1998年 | 2840篇 |
1997年 | 2910篇 |
1996年 | 2783篇 |
1995年 | 2314篇 |
1994年 | 2025篇 |
1993年 | 1740篇 |
1992年 | 1499篇 |
1991年 | 1313篇 |
1990年 | 1162篇 |
1989年 | 973篇 |
1988年 | 816篇 |
1987年 | 569篇 |
1986年 | 408篇 |
1985年 | 261篇 |
1984年 | 152篇 |
1983年 | 105篇 |
1982年 | 82篇 |
1981年 | 70篇 |
1980年 | 66篇 |
1979年 | 34篇 |
1978年 | 31篇 |
1977年 | 40篇 |
1976年 | 30篇 |
1973年 | 29篇 |
排序方式: 共有10000条查询结果,搜索用时 625 毫秒
61.
Dapeng Liu Binod R. Giri Milán Szőri Béla Viskolcz Et-touhami Es-sebbar Aamir Farooq 《Proceedings of the Combustion Institute》2021,38(1):967-976
NOx mitigation is a central focus of combustion technologies with increasingly stringent emission regulations. NOx can also enhance the autoignition of hydrocarbon fuels and can promote soot oxidation. The reaction between allyl radical (C3H5) and NOx plays an important role in the oxidation kinetics of propene. In this work, we measured the absolute rate coefficients for the redox reaction between C3H5 and NOx over the temperature range of 1000–1252 K and pressure range of 1.5–5.0 bar using a shock tube and UV laser absorption technique. We produced C3H5 by shock heating of C3H5I behind reflected shock waves. Using a Ti:Sapphire laser system with frequency quadrupling, we monitored the kinetics of C3H5 at 220 nm. Unlike low-temperature chemistry, the two target reactions, C3H5 + NO → products (R1) and C3H5 + NO2 → products (R2), exhibited a strong positive temperature dependence for this radical-radical type reaction. However, these reactions did not show any pressure dependence over the pressure range of 1.5–5.0 bar, indicating that the measured rate coefficients are close to the high-pressure limit. The measured values of the rate coefficients resulted in the following Arrhenius expressions (in unit of cm3/molecule/s):To our knowledge, these are the first high-temperature measurements of allyl + NOx reactions. The reported data will be highly useful in understanding the interaction of NOx with resonantly stabilized radicals as well as the mutual sensitization effect of NOx on hydrocarbon fuels. 相似文献
62.
63.
刘全礼 《北京联合大学学报(自然科学版)》2018,32(2):67-72
弱智儿童的脑机制是我国特殊教育界尚未探讨的一个领域。从智力、弱智和学习的本质出发,探讨了弱智儿童脑发育的机制和脑活动机制,认为弱智儿童脑发育的正常机制因为先天、后天的遗传异常或损伤遭到了破坏,由此导致了神经系统的传导失能,并表现为神经环路的形成困难、传导的信息堵塞和消失这些主要的神经活动特点。提出了干预或教育弱智儿童的三大措施,包括食物或物质干预、文化给予以及感官训练与文化、言语的结合。 相似文献
64.
Peng-Yan Gui Xiao-Hui Yan Wen-Juan Yuan Yuan-Liang Ma Xiao Ding Shuai Liu 《Natural product research》2019,33(19):2830-2836
A new A, D-seco limonoid, named 12-acetyloxyperforatin (1), along with three known ones, were isolated from the leaves of Harrisonia perforata. Their structures were elucidated on the basis of spectroscopic analysis, including extensive NMR techniques and computational modelling. These compounds showed no inhibitory activity against the 11β-HSD1 enzyme. 相似文献
65.
Jia Tian-Cong Guo Jin-Tao Wang Zhen Zhu Xiao-Shan Zhang Qian-Xin Chen Ping Yao Kun Lv Wen-Ying Liu Guo-Guang 《Journal of Radioanalytical and Nuclear Chemistry》2019,321(3):823-829
Journal of Radioanalytical and Nuclear Chemistry - In the present work the final products of coumarin radiation chemical transformation are investigated by chromatography. During radiolysis of... 相似文献
66.
Luo Dajuan Liu Bingqian Gao Rong Su Lixia Su Yonghuan 《Journal of Solid State Electrochemistry》2022,26(3):749-759
Journal of Solid State Electrochemistry - Cortisol, a steroid hormone, has been confirmed as a kind of biomarker that reflects the stress response of psychobiology and related adverse health... 相似文献
67.
An oriented tetrahedron defined on four vertices is a set of four cyclic triples with the property that any ordered pair of vertices is contained in exactly one of the cyclic triples. A tetrahedral quadruple system of order with index , denoted by , is a pair , where is an ‐set and is a set of oriented tetrahedra (blocks) such that every cyclic triple on is contained in exactly members of . A is pure if there do not exist two blocks with the same vertex set. When , the spectrum of a pure TQS has been completely determined by Ji. In this paper, we show that there exists a pure if and only if and . A corollary is that a simple also exists if and only if and . 相似文献
68.
2018年,中共中央、国务院印发《中国乡村振兴战略规划(2018-2022年)》,全面部署和布局乡村振兴战略.文章基于政府绩效评价的理念和方法,构建乡村振兴绩效评价指标体系,明确评价维度,为实现乡村振兴、城乡融合发展提供价值导向、度量体系和动力工具.该评价维度包涵资源投入、过程监管、目标实现情况和社会满意度四个方面.文章指出,相关单位以绩效评价推进乡村振兴时应注重顶层设计,强化部门协同,构建评价体系,引入第三方评价主体,凸显农民获得感. 相似文献
69.
70.