Synthesis,characterization, and electrical properties of polypyrrole/multiwalled carbon nanotube composites

Size‐controllable polypyrrole (PPy)/multiwalled carbon nanotube (MWCNT) composites have been synthesized by in situ chemical oxidation polymerization directed by various concentrations of cationic surfactant cetyltrimethylammonium bromide (CTAB). Raman spectra, FTIR, SEM, and TEM were used to characterize their structure and morphology. These results showed that the composites are core (MWCNT)–shell (PPy) tubular structures with the thickness of the PPy layer in the range of 20–40 nm, depending on the concentration of CTAB. Raman and FTIR spectra of the composites are almost identical to those of PPy alone. The electrical conductivities of these composites are 1–2 orders of magnitude higher than those of PPy without MWCNTs. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 6449–6457, 2006     

Synthesis and characterization of polyimides derived from (3‐amino‐2,4,6‐trimethylphenyl)‐(3′‐aminophenyl)methanone and aromatic dianhydrides

A series of new polyimides were prepared via the polycondensation of (3‐amino‐2,4,6‐trimethylphenyl)‐(3′‐aminophenyl)methanone and aromatic dianhydrides, that is, 3,3′,4,4′‐biphenyltetracarboxylic dianhydride (BPDA), 4,4′‐oxydiphthalic anhydride, 3,3′,4,4′‐benzophenone tetracarboxylic dianhydride, and 2,2′‐bis(3,4‐dicarboxyphenyl) hexafluoropropane dianhydride. The structures of the polyimides were characterized by Fourier transform infrared and NMR measurements. The properties were evaluated by solubility tests, ultraviolet–visible analysis, differential scanning calorimetry, and thermogravimetric analysis. The two different meta‐position‐located amino groups with respect to the carbonyl bridge in the diamine monomer provided it with an unsymmetrical structure. This led to a restriction on the close packing of the resulting polymer chains and reduced interchain interactions, which contributed to the solubility increase. All the polyimides except that derived from BPDA had good solubility in strong aprotic solvents, such as N‐methyl‐2‐pyrrolidinone, N,N′‐dimethylacetamide, N,N‐dimethylformamide, and dimethyl sulfone, and in common organic solvents, such as cyclohexanone and chloroform. In addition, these polyimides exhibited high glass‐transition values and excellent thermal properties, with an initial thermal decomposition temperature above 470 °C and glass‐transition temperatures in the range of 280–320 °C. The polyimide films also exhibited good transparency in the visible‐light region, with transmittance higher than 80% at 450 nm and a cutoff wavelength lower than 370 nm. © 2005 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 1291–1298, 2006     

Characterization and electrical properties of polypyrrole/multiwalled carbon nanotube composites synthesized by in situ chemical oxidative polymerization

This study describes the preparation of polypyrrole (PPy)/multiwalled carbon nanotube (MWNT) composites by in situ chemical oxidative polymerization. Various ratios of MWNTs, which served as hard templates, were first dispersed in aqueous solutions with the surfactant cetyltrimethylammonium bromide to form micelle/MWNT templates and overcome the difficulty of MWNTs dispersing into insoluble solutions of pyrrole monomer, and PPy was then synthesized via in situ chemical oxidative polymerization on the surface of the templates. Raman spectroscopy, Fourier transform infrared (FTIR), field‐emission scanning electron microscopy (FESEM), and high‐resolution transmission electron microscopy (HRTEM) were used to characterize the structure and morphology of the fabricated composites. Structural analysis using FESEM and HRTEM showed that the PPy/MWNT composites were core (MWNT)–shell (PPy) tubular structures. Raman and FTIR spectra of the composites were almost identical to those of PPy, supporting the idea that MWNTs served as the core in the formation of a coaxial nanostructure for the composites. The conductivities of these PPy/MWNT composites were about 150% higher than those of PPy without MWNTs. © 2006 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 44: 1413–1418, 2006     

剃齿时齿形中凹现象的形成机理

本文综合啮合原理、微分几何和弹性力学的基础理论,对剃齿过程中刀具齿面和被剃齿轮齿面间的失配进行了分析。最后利用径向力求出了齿面间的压切量,从而解释并验证了剃齿过程中产生的齿形中凹现象。这对提高剃齿精度、降低噪音有着重要意义。     

一类拟线性耦合方程组的初边值问题

引用带权的Sobolev模和牛顿迭代格式,讨论了拟线性对称双曲抛物耦合方程组的初边值问题,得到了可微解的存在和唯一性定理。     

高效有机吸附膜吸附数学模型的建立

本文建立了高效有机吸附膜吸附数学模型，并与实验数据进行了比较，发现模型的数值计算结果与实验值基本相符，本模型具有较高的实用价值。     

培养学生数学解题能力的教学途径

从认知结构、认知规律、策略模式及非智力因素四个方面阐述了数学教学中如何有效地培养学生解题能力的问题.     

关于双语课程《数字电子技术》学习状况的调查与思考

以问卷调查的形式,通过描述性统计和定量分析,对我校双语课程《数字电子技术》学习状况进行了调查和分析,在此基础上,对双语教学提出了一些建议.     

从日昇昌看旅行社管理

日昇昌票号自创立以来,凭借其非同寻常的经营管理办法,推动了当时社会经济的迅猛发展,并且对我们今天的企业发展,尤其是对旅行社的发展有着重大的启迪作用.其先进的股份制和严格的用人制度是值得我们借鉴的.     

发动机的曲轴转速方程及其近似解

从活塞发动机的动力分析中得到本文中的微分一积分方程(4),其中α为曲轴转角,θ为角速度的平方,而ε<<1为总等效转动惯量的倒数。本文利用压缩映象原理和摄动方法证明了所得方程解的存在性和唯一性,并给出了这个解的渐近展开。