考虑地质分层约束的长短期记忆循环神经网络测井曲线重构

延长油田东部裸眼井区早期测井资料普遍只有自然电位（SP）、自然伽马（GR）及梯度电阻率(R2.5)三条曲线,因缺失声波（AC）、地层电阻率（RT）等测井曲线,难以满足精细油藏地质研究需求。东部裸眼井区开发时间长、单井产量低,重新测井缺乏可行性及经济性。采用长短期记忆循环神经网络(Long Short-Term Memory,LSTM)进行缺失测井曲线重构是一种经济有效方法,适用于地层测井序列数据。然而延长油田东部浅层油藏上覆黄土层段测井数据信号干扰大,直接应用模型精度较差。针对此问题,本文采用考虑地质分层约束的LSTM模型进行缺失测井曲线的重构,通过分层数据截取每口井长6层段测井数据作为样本数据,既保留了LSTM模型处理序列数据的优势,同时又避免了上覆黄土层测井数据对模型的干扰。利用裸眼井区完整测井数据进行模型训练优化和验证,讨论了考虑地质分层约束的LSTM测井曲线重构精度,结果表明通过引入地质分层约束,模型重构测井曲线精度更高。应用优化后模型实现裸眼井区50口仅有GR、SP、R2.5三条曲线数据井的AC、RT曲线重构,对50口井的142个射孔段进行二次解释,对比试油解释结论符合率达到89.4%,验证了该方法对测井曲线重构的实用性和有效性。     

基于卷积神经网络的新奇检测技术在结构损伤识别中的应用

针对新奇检测难以同时识别结构损伤时刻和损伤位置的问题,提出在新奇检测中引入卷积神经网络以实现损伤时刻和损伤位置的一次性确定。首先,采用小波包技术处理结构响应得到小波包能量,并将相邻测点对应频带的能量比作为新奇检测模型的特征向量;然后,以结构健康时的特征向量作为训练数据,建立健康模式下的基于卷积神经网络的新奇检测模型;接着,将结构实时输出的特征向量输入到新奇检测模型,所得输出与健康状态的输出进行对比,并将输出和输入的欧氏距离作为新奇指标;最后,根据新奇指标的变化识别结构损伤时刻和损伤位置。数值模拟和实验室试验验证了该方法的有效性。     

基于改进粒子滤波算法的车速估计

针对基于粒子滤波算法设计的车速估计器因提议分布与实际分布不一致导致粒子退化使估计误差变大的问题,提出了一种通过修正提议分布减弱粒子退化影响的改进粒子滤波车速估计器。首先,基于车辆运动学模型和传感器特性建立系统的状态转移方程和观测方程。然后,利用传感器测量值与粒子状态值的差值设计提议分布修正项对状态转移方程进行修正,并对过程噪声做自适应处理。最后,利用CarSim-Simulink联合仿真平台在双移线工况和正弦转角输入工况下进行仿真验证。与自适应粒子滤波器相比,双移线工况下改进粒子滤波估计器产生的纵向速度估计值和侧向速度估计值的平均绝对误差分别减小了40.25%和55.71%;正弦转角输入工况下,改进粒子滤波估计器产生的纵向速度估计值和侧向速度估计值的平均绝对误差分别减小了47.00%和41.21%。     

响应面结合模糊数学感官评价法优化槐花蜜饯配方及品质测定

以新鲜槐花为原料,辅以麦芽糖醇、柠檬酸、鸡蛋清和黄果槲寄生果实多糖等食品添加剂开发低糖槐花蜜饯。通过单因素试验,对鸡蛋清、麦芽糖醇、蜂蜜和黄果槲寄生果实多糖添加量进行筛选,采用响应面结合模糊数学感官评价法优化配方,对其重金属和微生物指标和抗氧化性进行了检验。结果表明,蜜饯最优化参数为鸡蛋清添加量为15%,麦芽糖醇添加量为30%,蜂蜜添加量为10%,黄果槲寄生果实多糖添加量为0.35%,柠檬酸量添加为0.18%、氯化钙添加量和D-异抗坏血酸钠添加量分别为0.01%为0.05%,得到了质地良好的槐花蜜饯产品,颜色均一微黄色,组织状态良好,薄厚均匀、口感细腻、咀嚼性好,槐花风味突出,气味协调。重金属含量低于国家标准限量（＜ 0.05 mg/kg）,未检出沙门氏菌和金黄色葡萄球菌,大肠杆菌和霉菌数量等卫生指标符合国家标准。蜜饯具有较强的总抗氧化能力（FRAP）和较好的清除 1,1-二苯基-2-三硝基苯肼（DPPH）的作用。研究结果表明,研制的低糖槐花蜜饯感官指标好,其质量符合国家标准,具有很好的营养价值和抗氧化功能。     

Unexpectedly ligand-free copper-catalyzed C–S cross-coupling of benzothiazole with aryl iodides in aqueous solution

A novel synthetic protocol for 2-aminophenyl sulfide derivatives via the reactions of benzothiazole with aryl iodides was reported for the first time. The reactions were catalyzed by CuCl with tetrabutylammonium hydroxide as the base and water as the solvent without ligand at 50 °C or room temperature. A variety of aryl iodides underwent the C–S cross-coupling reaction with benzothiazole to afford smoothly the corresponding products in excellent yield.     

Organophosphine/phosphite‐stabilized silver(I) complexes bearing N‐acetylbenzamide ligand: synthesis,characterization and potential application in metal organic chemical vapor deposition

New N‐silver(I) acetylbenzamide complexes of type L_n?AgNC₉H₈O₂ (L = PPh₃; n = 1, 2a; n = 2, 2b; n = 3, 2c; L = P(OEt)₃; n = 1, 2d; n = 2, 2e; n = 3, 2f) were prepared. These complexes were obtained in high yields and characterized by elemental analysis, ¹H NMR, ¹³C{H} NMR, ³¹P{H} NMR and IR spectroscopy, respectively. The molecular structure of 2b has been determined by X‐ray single‐crystal analysis in which the silver atom is in a distorted tetrahedral geometry and crystallizes as cis–trans. New N‐silver(I) acetylbenzamide complexes have a four‐membered ring, which could influence their chemical and physical properties and modulate volatility. Metal organic chemical vapor deposition experiments were carried out successfully at 400°C and 450°C using 2e as precursor for the deposition of silver films, respectively. The high‐purity silver film obtained at 400°C is dense and homogeneous. Copyright © 2012 John Wiley & Sons, Ltd.     

Novel ether-functional spiro-tetronic acid derivatives: molecule design, convenient synthesis and biological evaluation

A novel series of ether functionalization of spiro-tetronic acid derivatives have been designed and conveniently synthesized via three steps, including esterification, one-pot heterocyclization, and etherification reactions. The target molecules have been identified on the basis of analytical spectra data. All newly synthesized compounds have been screened for their potential insecticidal activity against Heliothis armigera and Plutella xylostella compared with spirodiclofen by standard method.     

The millimeter-wave spectrum of acetaldehyde in its two lowest torsional states

A large number of new millimeter-wave spectral lines of gaseous acetaldehyde have been measured at frequencies up to 250 GHz. These lines arise from rotational transitions of acetaldehyde in its two lowest (v_t = 0,1) torsional states and involve angular momentum quantum numbers J ≤ 12 and K ≤ 10. A global data set consisting of 562 lines has been obtained by combining the millimeter-wave lines with previously measured lower frequency data involving the two lowest torsional states. This data set has been analyzed via an internal axis method previously used to study the spectra of CH₃OH and CH₃SH. The root-mean-square deviation of the fit is only 685 kHz. An analogous least-squares fit to 335v_t = 0 lines yields a root-mean-square deviation of 269 kHz.