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51.
Feedings of [1-13C]- and [1,2-13C2]acetate Aspergillus terreus gave quadrone and terrecyclic acid which were analyzed by 13C NMR. The pattern of 13C-enrichments and couplings is consistent with the formation of 1 and 2 by cyclization of farnesyl pyrophosphate. 相似文献
52.
G.B. Song C.Q. Han J.K. Liang Q.L. Liu F.S. Liu G.H. Rao 《Journal of solid state chemistry》2004,177(7):2394-2403
The subsolidus phase relations of the PrOx-CaO-CuO pseudo-ternary system sintered at 950-1000°C have been investigated by X-ray powder diffraction. In this system, there exist one compound Ca10Pr4Cu24O41, one Ca2Pr2Cu5O10-based solid solution, seven three-phase regions and two two-phase regions. The crystal structures of Ca10Pr4Cu24O41 and Ca2Pr2Cu5O10-based solid solution have been determined. Compound Ca10Pr4Cu24O41 crystallizes in an orthorhombic cell with space group D2h20−Cccm, Z=4. Its lattice parameters are a=11.278(2) Å, b=12.448(3) Å and c=27.486(8) Å. The crystal structure of Ca2Pr2Cu5O10-based solid solution is an incommensurate phase based on the orthorhombic NaCuO2 type subcell. The lattice parameters of the subcell of the Ca2.4Pr1.6Cu5O10 are a0=2.8246(7) Å, b0=6.3693(5) Å, c0=10.679(1) Å, and those of the orthorhombic superstructure are with a=5a0, b=b0, c=5c0. The Ca2.4Pr1.6Cu5O10 structure can also be determined by using a monoclinic supercell with space group C2h5−P21/c, Z=4, a=5a0, b=b0, and β=104.79(1)° or 136.60(1)°, V=5a0b0c0. 相似文献
53.
54.
M. Liang H. Ohm B. De Sutter K. Sistemich 《Zeitschrift für Physik A Hadrons and Nuclei》1992,344(3):357-358
Tie half-lives of 8 low lying levels of103Nb have been determined at the fission-product separator JOSEF. A B-- triple-coincidence method was used which consists in a measurement of the time delay between the feeding of the levels through the B– decay of103Zr and their decay, in coincidence with a tagging ray, with plastic, BaF2 and Ge detectors, respectively. Most of the investigated levels are members of the three known rotational bands based on the ground state and the 164 and 248 keV levels. The deformation Bq=0.31(3) of103Nb could be deduced from the half-life data. The half-lives are well reproduced through calculations in the frame of the Nilsson model.The authors thank Dr. T. Seo for valuable advise in connection with the Nilsson-model calculations. 相似文献
55.
Hydrogen peroxide (HOOH) in ice and snow is an important chemical tracer for the oxidative capacities of past atmospheres. However, photolysis in ice and snow will destroy HOOH and form the hydroxyl radical (*OH), which can react with snowpack trace species. Reactions of *OH in snow and ice will affect the composition of both the overlying atmosphere (e.g., by the release of volatile species such as formaldehyde to the boundary layer) and the snow and ice (e.g., by the *OH-mediated destruction of trace organics). To help understand these impacts, we have measured the quantum yield of *OH from the photolysis of HOOH on ice. Our measured quantum yields (Phi(HOOH --> *OH)) are independent of ionic strength, pH, and wavelength, but are dependent upon temperature. This temperature dependence for both solution and ice data is best described by the relationship ln(Phi(HOOH --> *OH)) = -(684 +/- 17)(1/T) + (2.27 +/- 0.064) (where errors represent 1 standard error). The corresponding activation energy (Ea) for HOOH (5.7 kJ mol(-1)) is much smaller than that for nitrate photolysis, indicating that the photochemistry of HOOH is less affected by changes in temperature. Using our measured quantum yields, we calculate that the photolytic lifetimes of HOOH in surface snow grains under midday, summer solstice sunlight are approximately 140 h at representative sites on the Greenland and Antarctic ice sheets. In addition, our calculations reveal that the majority of *OH radicals formed on polar snow grains are from HOOH photolysis, while nitrate photolysis is only a minor contributor. Similarly, HOOH appears to be much more important than nitrate as a photochemical source of *OH on cirrus ice clouds, where reactions of the photochemically formed hydroxyl radical could lead to the release of oxygenated volatile organic compounds to the upper troposphere. 相似文献
56.
基于TMS320C5409的语音处理系统 总被引:1,自引:0,他引:1
介绍了一个基于DSP(TMS320C5409)的语音采集、编码、回放系统实例,对于DSP与CODEC芯片如何连接和配合工作提出了较为详细的解决方案,并从硬件、软件两个方面做出了说明. 相似文献
57.
鄂尔多斯盆地北部(简称鄂北)工区钻井技术已配套成龙,优选的井身结构经济效益明显;3KP钾基聚合物钻井液、TG无固相完井液可保证井内安全;低密度水泥浆技术已成功应用。 相似文献
58.
以腈纶纤维为起始原料,经乙二胺预交联后,以DMF作溶剂与硫化钠反应,合成了一种硫代酰胺功能基可达5.6mmol/g千纤维的含硫螯合功能纤维,利用红外光谱、硫含量测定等手段对这种功能纤维的结构进行了初步确定并探讨了溶剂、摩尔比以及时间、pH等对反应产物的影响. 相似文献
59.
The various patterns formed in Rayleigh-Bénard convection under different conditions are numerically simulated with a coupled-map-lattice
model. In the case of a lower aspect ratio (L/d=5), the simulations vividly depicted the main features of the transition process from a laminar state to a soft turbulence
and then to a hard turbulence. In this case, the cellular structure in a horizontal section is also reproduced. In the case
of a larger aspect ratio (L/d=30), the simulations successfully reproduced the spiral-defect chaos and target chaos in the initial stage of the pattern
evolution which were recently found in experiments. In this case, for a fluid ofPr=1, it is verified in simulations that both the ideal straight rolls and spiral-defect chaos are stable attractors in the
same parameter regime, and that the initial condition is a decisive factor for which one of the two is formed. In the same
case, for a fluid ofPr=4, the target patterns are dominant instead of the spirals, the sizes and distributions of the target are also notably dependent
on the initial condition. 相似文献
60.